Instant Cyclohexene Epoxidation Over Ni-TUD-1 Under Ambient Conditions

Catalysis Letters - To avoid the aggregation problem and activity loss of nickel oxide (NiO) nanoparticles (NPs) in organic reactions, NiO NPs were incorporated into TUD-1 mesoporous material....     

Integrative and multi-disciplinary framework for the 3D rehabilitation of large mandibular defects

The International Journal of Advanced Manufacturing Technology - The restoration of mandibular defects, especially large deformities is regarded as the most challenging surgical procedure owing to...     

A Channel Borrowing Approach for Cluster-based Hierarchical Wireless Sensor Networks

Mobile Networks and Applications - In Wireless Sensor Networks (WSNs), energy-efficient routing is required to conserve the scarce resources of these networks. Various energy-efficient routing...     

P水电站一管三机机组功率波动的分析与消除

针对P电站一管三机水电机组功率波动现象,发现水力不稳定是引起机组功率波动的主要原因,建立了一管三机引水系统的数值计算模型,计算结果表明球形分岔处的不稳定漩涡是导致水轮机蜗壳压力大幅波动的原因。在实际工程中加装导流板后,机组功率平稳,球形分岔处的漩涡消失,解决了水力不稳定的问题。     

C38+N2非调质钢曲轴法兰开裂原因分析

某厂的C38+N2非调质钢曲轴,在装机测试压力时法兰部位开裂。通过化学成分分析、金相检验、断口检验、能谱分析及硫印试验等研究了曲轴开裂的原因。分析结果如下:①材料化学成分和法兰部位淬硬层深度均符合要求;②断口上部为准解理断裂,下部为“朽木状”撕裂;③在锻造分模面有硫化物聚集,甚至有长达1mm的以MnS为主的超长硫化物。硫化物聚集割裂基体材料是曲轴开裂的主要原因,曲轴锻后晶粒粗大,法兰的螺孔部位厚度较薄,是其开裂的次要原因。     

基于稳定固溶体团簇模型的无扩散阻挡Cu合金薄膜的成分设计

随着超大规模集成电路的发展,器件特征尺寸不断缩小,必然会出现Cu互连扩散阻挡层厚度无法进一步减小等瓶颈问题。因此,开发新型无扩散阻挡层Cu合金薄膜(Cu种籽层)势在必行。该新型互连结构在长时间的中高温(400~500℃)后续工艺实施过程中,需同时具备高的稳定性(不发生互扩散反应)和低的电阻率。基于此,首先综述了目前无扩散阻挡层结构的研究现状及问题,然后对基于稳定固溶体团簇模型设计制备的无扩散阻挡Cu-Ni-M薄膜的研究工作进行了梳理,通过多系列薄膜微观结构、电阻率及稳定性的对比,深入探讨了第三组元M的选择原则及其对薄膜热稳定性的影响。为进一步验证稳定固溶体团簇模型的有效性,对第二组元的变化进行了相关讨论。结果证实,选取原子半径略大于Cu、难扩散且难溶的元素作为第三组元M,薄膜表现出良好的扩散阻挡能力;当M/Ni=1/12,即合金元素完全以团簇形式固溶于Cu基体时,薄膜综合性能达到最优,能够满足微电子行业的要求。所有研究表明,稳定固溶体团簇模型在无扩散阻挡层Cu合金薄膜的成分设计方面十分有效,该模型也有望在耐高温Cu合金及抗辐照材料成分设计方面推广使用。     

Medium-entropy (Ti,Zr, Hf)2SC MAX phase

Medium- and high-entropy alloys or ceramics for tuning the physicochemical properties of materials by the combination of multiple principal elements have received much interest. Herein, a medium-entropy (Ti, Zr, Hf)₂SC phase was synthesized attributing to the structural and chemical diversity of MAX phases. The crystal structure of (Ti, Zr, Hf)₂SC was determined by the Rietveld refinement of XRD, SEM, and atom-resolved TEM along with EDS elemental analysis. Phase evolution of X-ray diffraction patterns and TG/DSC curves were employed to reveal the synthesis mechanism of (Ti, Zr, Hf)₂SC from 2TiC–Zr–ZrC-2HfH₂-3.2FeS reactant system. The Vicker's hardness and the electrical resistivity of (Ti, Zr, Hf)₂SC were found higher than those of Ti₂SC, but the thermal conductivity of (Ti, Zr, Hf)₂SC was lower.     

Simultaneously achievement of high recoverable energy density and efficiency in sodium niobate-based ceramics

Journal of Materials Science: Materials in Electronics - Single lead-free Na0.73Bi0.09(Nb1???xTax)O3 (x?=?0, 0.10, 0.20, 0.30, and 0.40) ceramic phases were processed...