Early solar system aqueous activity: K isotope evidence from Allende

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.     

柱顶层间隔震体系增量动力响应研究

针对悬臂柱顶有拉梁和无拉梁层间隔震体系的抗震性能问题,运用增量动力分析(IDA)方法进行弹塑性分析,模拟结构从弹性到弹塑性直至最后倒塌的全过程。通过调幅地震动得到相应的层间位移角及峰值加速度,分别绘制单条与多条IDA曲线分析拉梁对隔震结构动力响应的影响,研究两种结构的抗震性能。结果表明:在相同性能点,有拉梁和无拉梁对纤维铰弯矩值和曲率值基本无影响,而在不同性能点,纤维铰状态明显不同;两种体系从正常使用阶段到防止倒塌阶段所需的加速度峰值的差距慢慢增大;在极罕遇地震下,柱顶有拉梁层间隔震体系的下部结构抗震性能要高于柱顶无拉梁层间隔震体系。     

万维望远镜平台下基于ASSURE模式的天文教学研究

随着教学手段和教学方法的现代化,信息技术与课程整合正成为教育改革的研究热点。文章以万维望远镜(WWT)平台为教学媒体,以ASSURE模式为教学设计的理论依据,设计并构建用以指导天文教学准备、实施与评价的教学模式,并将该模式应用于“四季星空”的教学案例中,使用基于信息技术的互动分析编码系统和学生课程反馈调查对教学效果进行分析和评价。研究表明,万维望远镜的使用可以降低教师言语比率,改变传统天文教学中以讲授式为主的教学方式。它适合起点能力较高、对新知识和新技能掌握能力较强的学生,能提高其学习兴趣和积极性,激发其探索宇宙的兴趣,有助于培养学生的科学素养。     

两株南极枝孢霉属真菌Cladosporium sp.NJF4和NJF6的次级代谢产物研究

南极因其独特的自然环境成为潜在、重要的微生物资源库,是产生新型生物活性物质和先导化合物菌株的潜在种源地,南极微生物正在成为创新药物研究新的重要资源。虽然近年来对南极微生物次级代谢产物的研究逐渐增加,但与温带和热带微生物研究相比仍处于初级阶段。对从南极普里兹湾海洋沉积物中获得的两株枝孢霉属真菌Cladosporium sp. NJF4和NJF6进行次级代谢产物分离及结构鉴定,获得20个化合物。化合物结构类型包括甾醇(1)、倍半萜类(7—8)、生物碱类(9—14)、二酮哌嗪(2—5、15—17)、芳香酸(6、18—19)等,其中倍半萜类(7—8)为首次从枝孢霉属真菌中分离得到,以上研究将为丰富南极微生物次级代谢产物库奠定一定的研究基础。     

Characteristics of Permeability Changes in Bituminous Coal Under Conditions of Stress Variation Due to Repeated Mining Activities

The factors affecting permeability change under repeated mining of coal seams are important study aspects that need to be explored. This study combined various stress variation characteristics of protective seam mining and simplified the stress path of repeated mining in protective seam mines. Based on the results from the bespoke gas flow and displacement testing apparatus, seepage tests for simulated repetitive mining were carried out. The results simulated the actual behavior very well. With any drastic increase in the mining influence, the axial deviation stress in the stress path increased, and the greater the difference in coal permeability during the unloading and stress recovery stage, the more substantial the increase in permeability. The change in coal permeability was significantly influenced by the severity of simulated repeated mining cycles. When the mining stress exceeded a critical value, the permeability of the coal sample increased with the increase in the number of loading and unloading cycles, but the reverse was true when the mining stress was lower than the critical value. The effective sensitivity of seepage to the applied stress decreased with an increase in the number of stress cycles. With a decrease in the deviation stress, that is, with lower severity of mining influence, the effective sensitivity of coal seepage to stress gradually decreased.

     

Seismic prediction method of multiscale fractured reservoir

Common prestack fracture prediction methods cannot clearly distinguish multiplescale fractures. In this study, we propose a prediction method for macro- and mesoscale fractures based on fracture density distribution in reservoirs. First, we detect the macroscale fractures (larger than 1/4 wavelength) using the multidirectional coherence technique that is based on the curvelet transform and the mesoscale fractures (1/4–1/100 wavelength) using the seismic azimuthal anisotropy technique and prestack attenuation attributes, e.g., frequency attenuation gradient. Then, we combine the obtained fracture density distributions into a map and evaluate the variably scaled fractures. Application of the method to a seismic physical model of a fractured reservoir shows that the method overcomes the problem of discontinuous fracture density distribution generated by the prestack seismic azimuthal anisotropy method, distinguishes the fracture scales, and identifies the fractured zones accurately.     

Jason-2高度计电离层GIM误差分析及修正研究

基于Jason-2高度计2015年地球物理数据集(GDR)38个周期太平洋海域的全球电离层图(GIM)电离层校正值和双频校正值的数据，分不同季度和不同纬度区域比较二者的差异，结果表明:GIM值与双频校正值之间存在明显的差异，GIM校正值普遍高于双频校正值，说明GIM高估了电离层路径延迟，GIM校正值与双频校正值的差异与季节和纬度区间有关。用梯度下降法得到GIM值的修正方程，将修正方程应用于2016年Jason-2的全年数据，修正后的GIM值与双频校正值十分接近，在各年份中均具有良好的适用性。在单频高度计不能使用电离层双频校正算法的情况下，可以利用不同季度和不同纬度区域的修正方程对同等高度的高度计GIM值进行修正以达到双频校正值的精度水平。     

N油田A油组钙质隔夹层地质特征及成因分析

在油田开发过程中,隔夹层控制油气水运动规律,对于寻找剩余油具有重要控制作用。本文以N油田TF组2段A油组为研究对象,通过薄片、岩心测试、测井、碳氧同位素等资料综合分析,研究其钙质隔夹层的分布特征、岩石学特征、物性特征、测井识别特征,并从沉积环境、物质来源、成岩作用相结合的角度分析钙质隔夹层的成因。研究表明,A油组纵向上发育的三套钙质隔夹层主要发育在前滨滩坝沉积微相,顶钙与底钙的岩性以砂质生屑质灰岩为主,中钙为钙质砂岩;三套钙质隔夹层中生物碎屑主要以腕足、腹足、有孔虫为主,含少量棘皮、瓣鳃、红藻、介形虫、苔藓虫等;成岩作用主要为胶结作用,胶结物类型包含早期方解石胶结物、中期铁方解石胶结物、晚期铁白云石胶结物;碳氧同位素分析表明,隔夹层中碳主要来自于沉积过程中的海水,同时有少量来自于大气淡水和有机酸,Ca~(2+)主要来源于生物碎屑,其次为钙长石溶解、铝硅酸盐矿物的水化作用。     

敞开酸溶和偏硼酸锂碱熔ICP-MS法测定多金属矿中的稀土元素及铌钽锆铪

用电感耦合等离子体质谱法(ICP-MS)测定地质样品中的稀土及难熔元素,混合酸敞开酸溶法和碱熔融法是两种主要的溶样方法。但地质样品组分复杂,元素之间存在相互共生的现象,对于特殊元素、特殊样品用传统酸溶法会造成部分元素消解不完全,使测定结果不准确;而碱熔法的操作过程繁琐,且溶液盐度高,易产生基体干扰和堵塞仪器进样系统。本文改进了传统四酸和五酸体系,采用氢氟酸-硝酸-硫酸敞开酸溶体系,用国家一级标准物质制作标准曲线测定15种稀土元素,方法准确度(ΔlgC)为0.001～0.027。同时改进了偏硼酸锂碱熔法,样品用偏硼酸锂碱熔提取,加入氢氧化钠调节溶液至碱性条件,所测元素与偏硼酸锂共沉淀后过滤分离熔剂,再用硝酸复溶测定15种稀土元素及铌钽锆铪。两种溶样方法的测定值与认定值的相对误差为1.09%～9.30%。将混合酸敞开酸溶法测定稀土元素、偏硼酸锂碱熔法测定铌钽锆铪的结果与其他实验室密闭酸溶法相比,两组数据的相对偏差为0.13%～15.32%。本实验表明,混合酸敞开酸溶法适用于测定地质样品中的稀土元素,偏硼酸锂碱熔法不仅适用于测定地质样品中的稀土元素及铌钽锆铪,也适用于测定如古老高压变质岩石及铝含量高的样品中的铌钽锆铪。     

大兴安岭中南段构造岩浆岩带深部地质成矿作用

大兴安岭中南段位于索伦—西拉木伦断裂带与嫩江—白城断裂带交汇域，区内大规模岩浆活动、成矿作用与深部地质活动密切相关。深部地球物理研究成果显示：该区域上地幔存在埋藏较浅的低速、低阻、高热异常体，推断应是深部软流体局部上涌的显示；下地壳存在低密度、低速、高导层，推断是因软流体上涌，诱发下地壳重熔，形成所谓下地壳热流体引起。总之该区域软流层厚度大，热活动性强是引起大规模的岩浆活动及多金属矿床集中分布的深部地质因素。而古生代古亚洲洋洋壳俯冲消减，华北板块、西伯利亚板块陆—陆碰撞拼接及至中生代晚期太平洋板块俯冲作用是引起软流层上涌、下地壳重熔等强烈的壳幔相互作用之源动力。