Tektite research 1936–1990*

Abstract— Fifty-odd years of tektite research are reviewed, proceeding from the discovery of the first North American tektites in 1936. This included the early recognition that tektites were terrestrial objects rather than meteorites and that the glassy particles in tektites were fused quartz (lechatelierite). Later, during National Science Foundation-supported research, it was found that some tektites appeared to have formed as puddles of melt, that the content and character of bubbles in lechatelierite can be used as a relative temperature scale, that rayed bubbles in tektites formed from hydrous minerals, that bubbles in tektites formed chiefly from water which was absorbed into the walls of the bubbles leaving vacuums, and that “fingers” in the surficial part of some tektites may have formed by differential volatilization. Some unpublished observations and adventures are briefly reported.     

X-ray and ultraviolet observations of the dwarf nova VW Hyi in quiescence

We present an analysis of X-ray and ultraviolet (UV) data of the dwarf nova VW Hyi that were obtained with XMM–Newton during the quiescent state. The X-ray spectrum indicates the presence of an optically thin plasma in the boundary layer that cools as it settles on to the white dwarf. The plasma has a continuous temperature distribution that is well described by a power law or a cooling flow model with a maximum temperature of 6–8 keV. We estimate from the X-ray spectrum a boundary layer luminosity of  8 × 10³⁰ erg s^-1  , which is only 20 per cent of the disc luminosity. The rate of accretion on to the white dwarf is  5 × 10⁻¹² M_⊙ yr⁻¹  , about half of the rate in the disc. From the high-resolution X-ray spectra, we estimate that the X-ray emitting part of the boundary layer is rotating with a velocity of 540 km s⁻¹, which is close to the rotation velocity of the white dwarf but is significantly smaller than the Keplerian velocity. We detect a 60-s quasi-periodic oscillation of the X-ray flux, which is likely to be due to the rotation of the boundary layer. The X-ray and the UV flux show strong variability on a time-scale of ∼1500 s. We find that the variability in the two bands is correlated and that the X-ray fluctuations are delayed by ∼100 s. The correlation indicates that the variable UV flux is emitted near the transition region between the disc and the boundary layer and that accretion rate fluctuations in this region are propagated to the X-ray emitting part of the boundary layer within ∼100 s. An orbital modulation of the X-ray flux suggests that the inner accretion disc is tilted with respect to the orbital plane. The elemental abundances in the boundary layer are close to their solar values.     

Response of earth and venus ionospheres to corotating solar wind stream of 3 July 1979

Corotating solar wind streams emanating from stable coronal structures provide an unique opportunity to compare the response of planetary ionospheres to the energy conveyed in the streams. For recurrent solar conditions the signal propagating outward along spiral paths in interplanetary space can at times exhibit rather similar content at quite different downstream locations in the ecliptic plane. Using solar wind measurements from plasma detectors on ISEE-3, Pioneer Venus Orbiter (PVO) and Helios-A, as well as in-situ ion composition measurements from Bennett Ion Mass Spectrometers on the Atmosphere Explorer-E and PVO spacecraft, corotating stream interactions are examined at Earth and Venus. During May–July 1979 a sequence of distinct, recurrent coronal regions developed at the Sun. Analysis of these regions and the associated solar wind characteristics indicates a corrresponding sequence of corotating streams, identifiable over wide distances. The time series of solar wind velocity variations observed at Earth, Venus, and the Helios-A positions during June–July attests to intervals of corotating stream propagation. The characteristics of the stream which passed Earth on July 3, are observed at Helios-A and at Venus (PVO) about 8 days later, consistent with the spiral path propagation delay times between the locations in the ecliptic plane. On July 3, Earth and Venus have a wide azimuthal separation of about 142 . Although the planetary environments are distinctly different, pronounced and somewhat analagous ionospheric responses to the stream passage are observed at both Earth and Venus. The response to the intercepted stream is consistent with independent investigations which have shown that the variability of the solar wind momentum flux is an important factor in the solar wind-ionosphere interaction at both planets.     

The Mordor Alkaline Igneous Complex,Central Australia: PGE-enriched disseminated sulfide layers in cumulates from a lamprophyric magma

The Mordor Alkaline Igneous Complex (MAIC) is a composite intrusion comprising a body of syenite and a funnel-shaped layered mafic–ultramafic intrusion of lamprophyric parentage, the Mordor Mafic–Ultramafic Intrusion or MMUI. The MMUI is highly unusual among intrusions of lamprophyric or potassic parentage in containing primary magmatic platinum-group element (PGE)-enriched sulfides. The MMUI sequence consists largely of phlogopite-rich pyroxenitic cumulates, with an inward dipping conformable layer of olivine-bearing cumulates divisible into a number of cyclic units. Stratiform-disseminated sulfide accumulations are of two types: disseminated layers at the base of cyclic units, with relatively high PGE tenors; and patchy PGE-poor disseminations within magnetite-bearing upper parts of cyclic units. Sulfide-enriched layers at cycle bases contain anomalous platinum group element contents with grades up to 1.5 g/t Pt+Pd+Au over 1-m intervals, returning to background values of low parts per billion (ppb) on a meter scale. They correspond to reversals in normal fractionation trends and are interpreted as the result of new magma influxes into a continuously replenished magma chamber. Basal layers have decoupled Cu and PGE peaks reflecting increasing PGE tenors up-section, due to increasing R factors during the replenishment episode, or progressive mixing of between resident PGE-poor magma and more PGE-enriched replenishing magma. The presence of PGE enriched sulfides in cumulates from a lamprophyric magma implies that low-degree partial melts do not necessarily leave sulfides and PGEs in the mantle restite during partial melting. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Supercritical gas sorption on moist coals

The effect of moisture on the CO₂ and CH₄ sorption capacity of three bituminous coals from Australia and China was investigated at 55 °C and at pressures up to 20 MPa. A gravimetric apparatus was used to measure the gas adsorption isotherms of coal with moisture contents ranging from 0 to about 8%. A modified Dubinin–Radushkevich (DR) adsorption model was found to fit the experimental data under all conditions. Moisture adsorption isotherms of these coals were measured at 21 °C. The Guggenheim–Anderson–de Boer (GAB) model was capable of accurately representing the moisture isotherms over the full range of relative pressures.Moist coal had a significantly lower maximum sorption capacity for both CO₂ and CH₄ than dry coal. However, the extent to which the capacity was reduced was dependent upon the rank of the coal. Higher rank coals were less affected by the presence of moisture than low rank coals. All coals exhibited a certain moisture content beyond which further moisture did not affect the sorption capacity. This limiting moisture content was dependent on the rank of the coal and the sorbate gas and, for these coals, corresponded approximately to the equilibrium moisture content that would be attained by exposing the coal to about 40–80% relative humidity. The experimental results indicate that the loss of sorption capacity by the coal in the presence of water can be simply explained by volumetric displacement of the CO₂ and CH₄ by the water. Below the limiting moisture content, the CO₂ sorption capacity reduced by about 7.3 kg t^− 1 for each 1% increase in moisture. For CH₄, sorption capacity was reduced by about 1.8 kg t^− 1 for each 1% increase in moisture.The heat of sorption calculated from the DR model decreased slightly on addition of moisture. One explanation is that water is preferentially attracted to high energy adsorption sites (that have high energy by virtue of their electrostatic nature), expelling CO₂ and CH₄ molecules.     

The Dynamics of Covering Behaviour in Dominant Echinoid Populations from American and European West Coasts

Abstract.  The so-called 'covering behaviour' of echinoids is known to vary with habitat according to the types of covering items available, but the full extent of the role played by habitat characteristics in this behaviour is not known. Moreover, whether or not different species inhabiting similar environmental conditions and habitats also show similar patterns of this particular behaviour has yet to be investigated. In this study, two prominent west coast echinoid species, Paracentrotus lividus and Strongylocentrotus purpuratus , were examined with respect to covering behaviour and spatial organisation. Populations of both species are found in exposed intertidal zones, occupying boreholes within tidepools. Important similarities were found in the spatial organisation of both species' populations, with lowest densities in upper shore pools. However, the size distributions of the two populations differed significantly; P. lividus within upper shore pools were significantly larger than those in mid or lower shore pools, whereas S. purpuratus on the lower shore were significantly larger than those at other shore heights. We found significant between-species variability in covering item use, although the number of covering items available at both sites was not significantly different. For example, greater densities of covering items were used by P. lividus than by S. purpuratus . We also found that the percent of echinoid surface area covered varied significantly in space for both species. These data emphasise the complex and multifaceted nature of covering behaviour, but most importantly, they also strongly suggest that habitat characteristics can only partly explain the extent of this behavioural variability amongst echinoid species.     

Manganese and iron distributions off central California influenced by upwelling and shelf width

In July 2002, a combination of underway mapping and discrete profiles revealed significant along-shore variability in the concentrations of manganese and iron in the vicinity of Monterey Bay, California. Both metals had lower concentrations in surface waters south of Monterey Bay, where the shelf is about 2.5 km wide, than north of Monterey Bay, where the shelf is about 10 km wide. During non-upwelling conditions over the northern broad shelf, dissolvable iron concentrations measured underway in surface waters reached 3.5 nmol L⁻¹ and dissolved manganese reached 25 nmol L⁻¹. In contrast, during non-upwelling conditions over the southern narrow shelf, dissolvable iron concentrations in surface waters were less than 1 nmol L⁻¹ and dissolved manganese concentrations were less than 5 nmol L⁻¹. A pair of vertical profiles at 1000 m water depth collected during an upwelling event showed dissolved manganese concentrations of 10 decreasing to 2 nmol L⁻¹, and dissolvable iron concentrations of 12–20 nmol L⁻¹ in the upper 100 m in the north, compared to 3.5–2 nmol L⁻¹ Mn and 0.6 nmol L⁻¹ Fe in the upper 100 m in the south, suggesting the effect of shelf width influences the chemistry of waters beyond the shelf.These observations are consistent with current understanding of the mechanism of iron supply to coastal upwelling systems: Iron from shelf sediments, predominantly associated with particles greater than 20 μm, is brought to the surface during upwelling conditions. We hypothesize that manganese oxides are brought to the surface with upwelling and are then reduced to dissolved manganese, perhaps by photoreduction, following a lag after upwelling.Greater phytoplankton biomass, primary productivity, and nutrient drawdown were observed over the broad shelf, consistent with the greater supply of iron. Incubation experiments conducted 20 km offshore in both regions, during a period of wind relaxation, confirm the potential of these sites to become limited by iron. There was no additional growth response when copper, manganese or cobalt was added in addition to iron. The growth response of surface water incubated with bottom sediment (4 nmol L⁻¹ dissolvable Fe) was slightly greater than in control incubations, but less than in the presence of 4 nmol L⁻¹ dissolved iron. This may indicate that dissolvable iron is not as bioavailable as dissolved iron, although the influence of additional inhibitory elements in the sediment cannot be ruled out.