Implementation of Solute Transport in the Vadose Zone into the “HYDRUS Package for MODFLOW”

The “HYDRUS package for MODFLOW” is an existing MODFLOW package that allows MODFLOW to simultaneously evaluate transient water flow in both unsaturated and saturated zones. The package is based on incorporating parts of the HYDRUS-1D model (to simulate unsaturated water flow in the vadose zone) into MODFLOW (to simulate saturated groundwater flow). The coupled model is effective in addressing spatially variable saturated-unsaturated hydrological processes at the regional scale. However, one of the major limitations of this coupled model is that it does not have the capability to simulate solute transport along with water flow and therefore, the model cannot be employed for evaluating groundwater contamination. In this work, a modified unsaturated flow and transport package (modified HYDRUS package for MODFLOW and MT3DMS) has been developed and linked to the three-dimensional (3D) groundwater flow model MODFLOW and the 3D groundwater solute transport model MT3DMS. The new package can simulate, in addition to water flow in the vadose zone, also solute transport involving many biogeochemical processes and reactions, including first-order degradation, volatilization, linear or nonlinear sorption, one-site kinetic sorption, two-site sorption, and two-kinetic sites sorption. Due to complex interactions at the groundwater table, certain modifications of the pressure head (compared to the original coupling) and solute concentration profiles were incorporated into the modified HYDRUS package. The performance of the newly developed model is evaluated using HYDRUS (2D/3D), and the results indicate that the new model is effective in simulating the movement of water and contaminants in the saturated-unsaturated flow domains.     

P–T–t–d evolution of orogenic middle crust of the Roc de Frausa Massif (Eastern Pyrenees): a result of horizontal crustal flow and Carboniferous doming?

Structural, petrological and textural studies are combined with phase equilibria modelling of metapelites from different structural levels of the Roc de Frausa Massif in the Eastern Pyrenees. The pre‐Variscan lithological succession is divided into the Upper, Intermediate and Lower series by two orthogneiss sheets and intruded by Variscan igneous rocks. Structural analysis reveals two phases of Variscan deformation. D1 is marked by tight to isoclinal small‐scale folds and an associated flat‐lying foliation (S1) that affects the whole crustal section. D2 structures are characterized by tight upright folds facing to the NW with steep NE–SW axial planes. D2 heterogeneously reworks the D1 fabrics, leading to an almost complete transposition into a sub‐vertical foliation (S2) in the high‐grade metamorphic domain. All structures are affected by late open to tight, steeply inclined south‐verging NW–SE folds (F3) compatible with steep greenschist facies dextral shear zones of probable Alpine age. In the micaschists of the Upper series, andalusite and sillimanite grew during the formation of the S1 foliation indicating heating from 580 to 640 °C associated with an increase in pressure. Subsequent static growth of cordierite points to post‐D1 decompression. In the Intermediate series, a sillimanite–biotite–muscovite‐bearing assemblage that is parallel to the S1 fabric is statically overgrown by cordierite and K‐feldspar. This sequence points to ~1 kbar of post‐D1 decompression at 630–650 °C. The Intermediate series is intruded by a gabbro–diorite stock that has an aureole marked by widespread migmatization. In the aureole, the migmatitic S1 foliation is defined by the assemblage biotite–sillimanite–K‐feldspar–garnet. The microstructural relationships and garnet zoning are compatible with the D1 pressure peak at ~7.5 kbar and ~750 °C. Late‐ to post‐S2 cordierite growth implies that F2 folds and the associated S2 axial planar leucosomes developed during nearly isothermal decompression to <5 kbar. The Lower series migmatites form a composite S1–S2 fabric; the garnet‐bearing assemblage suggests peak P–T conditions of >5 kbar at suprasolidus conditions. Almost complete consumption of garnet and late cordierite growth points to post‐D2 equilibration at <4 kbar and <750 °C. The early metamorphic history associated with the S1 fabric is interpreted as a result of horizontal middle crustal flow associated with progressive heating and possible burial. The upright F2 folding and S2 foliation are associated with a pressure decrease coeval with the intrusion of mafic magma at mid‐crustal levels. The D2 tectono‐metamorphic evolution may be explained by a crustal‐scale doming associated with emplacement of mafic magmas into the core of the dome.     

Dynamics of Saxothuringian subduction channel/wedge constrained by phase‐equilibria modelling and micro‐fabric analysis

Subduction and exhumation dynamics can be investigated through analysis of metamorphic and deformational evolution of associated high‐grade rocks. The Erzgebirge anticline, which forms at the boundary between the Saxothuringian and Teplá‐Barrandian domains of the Bohemian Massif, provides a useful study area for these processes owing to the occurrence of numerous meta‐basites preserving eclogite facies assemblages, and coesite and diamond bearing quartzofeldspathic lithologies indicating subduction to deep mantle depths. The prograde and retrograde evolution of meta‐basite from the Czech portion of the Erzgebirge anticline has been constrained through a combination of thermodynamic modelling and conventional thermobarometry. Garnet growth zoning indicates that the rocks underwent burial and heating to peak conditions of 2.6 GPa and at least 615 °C. Initial exhumation occurred with concurrent cooling and decompression resulting in the growth of amphibole and zoisite poikiloblasts overgrowing and including the eclogite facies assemblage. The development of clinopyroxene–plagioclase–amphibole symplectites after omphacite and Al‐rich rims on matrix amphibole indicate later heating at the base of the lower crust. Omphacite microstructures, in particular grain size analysis and lattice‐preferred orientations, indicate that the prograde evolution was characterized by a constrictional strain geometry transitioning into plane strain and oblate fabrics during exhumation. The initial constrictional strain pattern is interpreted as being controlled by competing slab pull and crustal buoyancy forces leading to necking of the subducting slab. The transition to plane strain and flattening geometries represents transfer of material from the subducting lithosphere into a subduction channel, break‐off of the dense slab and rebound of the buoyant crustal material.     

Assess hydrological responses to a warming climate at the Lysina Critical Zone Observatory in Central Europe

Climate warming is having profound effects on the hydrological cycle by increasing atmospheric demand, changing water availability, and snow seasonality. Europe suffered three distinct heat waves in 2019, and 11 of the 12 hottest years ever recorded took place in the past two decades, which will potentially change seasonal streamflow patterns and long-term trends. Central Europe exhibited six dry years in a row since 2014. This study uses data from a well-documented headwater catchment in Central Europe (Lysina) to explore hydrological responses to a warming climate. We applied a lumped parameter hydrologic model Brook90 and a distributed model Penn State Integrated Hydrologic Model (PIHM) to simulate long-term hydrological change under future climate scenarios. Both models performed well on historic streamflow and in agreement with each other according to the catchment water budget. In addition, PIHM was able to simulate lateral groundwater redistribution within the catchment validated by the groundwater table dynamics. The long-term trends in runoff and low flow were captured by PIHM only. We applied different EURO-CORDEX models with two emission scenarios (Representative Concentration Pathways RCP 4.5, 8.5) and found significant impacts on runoff and evapotranspiration (ET) for the period of 2071–2100. Results from both models suggested reduced runoff and increased ET, while the monthly distribution of runoff was different. We used this catchment study to understand the importance of subsurface processes in projection of hydrologic response to a warming climate.     

Marine mammals from northeast Atlantic: relationship between their trophic status as determined by delta13C and delta15N measurements and their trace metal concentrations

The relationship between trophic position through delta13C and delta15N and trace metal concentrations (Zn, Cd, Cu and Hg) was investigated in the tissues of six marine mammal species from the Northeast Atlantic: striped dolphin Stenella coeruleoalba, common dolphin, Delphinus delphis, Atlantic white-sided dolphin Lagenorhynchus acutus, harbour porpoise Phocoena phocoena, white beaked-dolphin Lagenorhynchus albirostris, grey seal Halichoerus grypus stranded on French Channel and Irish coasts. White-beaked dolphins, harbour porpoises, white-sided dolphins, common and striped dolphins display the same relative and decreasing trophic position, as measured by delta15N values, along both the Irish and French channel coasts, reflecting conservative trophic habits between these two places. Hepatic and renal Cd concentrations were significantly correlated to muscle delta13C and delta15N values while Hg, Zn and Cu did not. These results suggest that Cd accumulation is partly linked to the diet while other factors such as age or body condition might explain Hg, Zn or Cu variability in marine mammals. Combined stable isotope and trace metal analyses appear to be useful tools for the study of marine mammal ecology.