金伯利岩型金刚石矿床研究及其成矿模式探讨——以辽宁瓦房店地区金刚石原生矿矿床为例

辽宁南部瓦房店金刚石矿是国内最大的金刚石矿产区，现已发现4处金刚石成矿带、120个岩体。其中金伯利岩岩管24个、岩脉89个、可疑岩体7个，累计提交1221万克拉储量，占全国金刚石储量52%。本文主要对该矿床的金刚石母岩—金伯利岩的岩石地球化学特征进行了全面系统分析，发现金伯利岩中MgO、NiO、Cr 2O 3的含量与TiO 2、Al 2O 3、Na 2O、K 2O、CaO、P 2O 5等偏碱性组分呈正相关关系；Ni、Cr、Co含量与金刚石含量呈正相关，而Ti、Zr、Ba元素含量与金刚石含量呈负相关。通过对瓦房店矿区金刚石中石榴石及单斜辉石包裹体、橄榄石- 石榴石矿物对、石榴石微量元素、尖晶石- 橄榄石等多种地质温、压计归纳得出金刚石矿的来源深度为150~210 km,压力5~7 GPa，温度1083~1261℃，在上述温、压条件下，结合岩浆化学组成，估算金伯利岩具有低氧逸度(fO 2=2. 913×1. 01325×10-6Pa)的特点。结合野外勘查工作，总结了该矿床的地质特征、控矿构造、矿体空间分布规律等要素，认为NEE向和NE向断裂控制着金伯利岩体的展布方向和矿体形态。脉状金伯利岩体一般呈NEE 70°~80°方向展布，严格受NEE至近EW向的密集节理或裂隙控制。提出了金刚石母岩—金伯利岩是由源于上地幔岩浆，在一定的封闭条件下，受构造与岩性双重控制，多期性的爆发与侵入交替作用所形成，并建立了具有较高氧逸度和较高密度的流变性软流圈，通过渗滤熔体浸蚀岩石圈形成金刚石的理想成因模式，希望为下一步找矿工作提供参考。     

微生物勘探技术在潮汕坳陷油气勘探中的应用初探

东沙海域潮汕坳陷中生界研究程度相对较低,油气分布规律不明,为了加强对该区油气分布和富集规律的研究,针对潮汕坳陷西部地质目标首次应用微生物地球化学勘探技术(MGCE),探讨其含油气性。MGCE技术以轻烃微渗漏理论为基础,采用地质微生物学方法和地球化学方法检测研究区海底表层的微生物异常和吸附烃异常,预测研究区下伏地层中油气的富集区及其油气性质。检测结果显示研究区西部凹陷的斜坡区微生物异常呈块状发育,轻烃微渗漏强度变化大,可能为潜在油气富集区,酸解吸附烃成果显示可能的油气性质为干气和凝析油气。     

Microstructure Evolution of Organic Matter and Clay Minerals in Shales with Increasing Thermal Maturity

As the two important components of shale, organic matter(OM) and clay minerals are usually thought to strongly influence the hydrocarbon generation, enrichment and exploitation. The evolution process of OM and clay minerals as well as their interrelationship over a wide range of thermal maturities are not completely clear. Taking Yanchang(T_3y), Longmaxi(S_1l) and Niutitang(?_1n) shales as examples, we have studied the microstructure characteristics of OM and clay minerals in shales with different thermal maturities. The effects of clay minerals and OM on pores were reinforced through sedimentation experiments. Using a combination of field emission scanning electron microscopy(FESEM) and low-pressure N_2 adsorption, we investigated the microstructure differences among the three shales. The results showed that both OM and clay minerals have strong effects on pores, and small mesopore(2–20 nm) is the dominant pore component for all three samples. However, the differences between the three samples are embodied in the distribution of pore size and the location. For the T_3y shale, clay minerals are loosely arranged and develop large amounts of pores, and fine OM grains often fill in intergranular minerals or fractures. Widespread OM pores distribute irregularly in S_1l shale, and most of the pores are elliptical and nondirectional. The ?_1n shale is characterized by the preferred orientational OM-clay aggregates, and lots of pores in the composites are in the mesopore range, suggesting that over maturity lead to the collapse and compaction of pores under huge pressure of strata. The results of the current research imply that with increasing thermal maturity, OM pores are absent at low maturity(T_3y), are maximized at high maturity(S_1l) and are destroyed or compacted at over-mature stage(?_1n). Meanwhile, clay minerals have gone through mineral transformation and orientational evolution. The interaction of the two processes makes a significant difference to the microstructure evolution of OM and clay minerals in shale, and the findings provide scientific foundation in better understanding diagenetic evolution and hydrocarbon generation of shale.     

浑河断裂地球物理场特征及地震活动性

浑河断裂是辽宁省内一条重要的北东向地震构造带,断裂两侧的地球物理重磁场存在差异。通过浑河断裂的区域重力场与磁场研究,认为浑河断裂既控制了深、浅部岩石地层的发育,同时浑河断裂的重力场、磁场分布随着深、浅部地层岩性发育的差异而有所变化。浑河断裂的重力场和磁场梯度带主要位于抚顺以西至沈阳一带,浑河断裂历史以来有记录的最大破坏性地震位于重力梯度变化较大的沈阳段。综合浑河断裂地球物理场特征及区域地质资料,浑河断裂虽然活动性一般,但抚顺地区的采煤活动对断裂的活动性有一定影响。近些年抚顺地区频发的沉降、滑坡和地裂缝等地质灾害应当引起对浑河断裂活动性研究的重视。     

中国耕地土壤相对湿度时空分异

以全国653个农业气象站1993-2013年耕地的土壤相对湿度数据为基础,运用地统计方法,分析中国耕地土壤相对湿度时空分异特征与规律。结果表明：自1993年以来全国耕地的土壤相对湿度呈现波动上升趋势。全国耕地的土壤相对湿度普遍大于60%,分布区域自4月中旬开始随夏季风推移不断向北向西扩大,自10月下旬开始向东、南方向缩小。耕地土壤相对湿度值随土壤深度的增加而增加。年际尺度上,耕地的土壤相对湿度在夏秋季上升速度最快,变化幅度随土层深度增加而变小。土壤相对湿度与降水量存在较强的正相关关系,与潜在蒸发量、气温普遍存在较强的负相关关系。土壤相对湿度与各气象要素的相关性随深度加深而减弱。春、夏、秋季气象因素对旱地土壤相对湿度影响较大,冬季气象因素对水田影响更大。     

Tidal Effects on the Bottom Thermal Front of North Yellow Sea Cold Water Mass near Zhangzi Island in Summer 2009

Three seabed-mounted TD/CTD chains and two upward-looking acoustic Doppler current profilers(ADCPs) in the southwest of Zhangzi Island are used and a simultaneous cruise observation in the northern North Yellow Sea(NYS) is conducted to study temperature variation in the bottom thermal front zone of the NYS Cold Water Mass(NYSCWM) during the summer of 2009. In the flood-ebb tidal cycles, the bottom temperature decreases(increases) during flood(ebb) tides, which are dominated by the tidal-current induced horizontal advection. The ebb tide-induced temperature increase is larger than the flood tide-induced temperature decrease due to seasonal warming. In the spring-neap tidal cycles, the temperature and the vertical temperature structure show notable fortnightly variation from 16 July to 25 August. The bottom temperature increases from neap to spring tides and decreases from spring to neap. The Richardson number demonstrates strengthened vertical mixing during spring tides but enhanced stratification during neap tides. The spring-neap variation in vertical shear caused by tidal current is the dominant factor that induces the fortnightly variation in vertical mixing and thus bottom temperature.     

Total Synthesis of Marine Cyclic Enol-Phosphotriester Salinipostin Compounds

Due to their structural diversity and variety of biological activities, marine natural products have been the subject of extensive study. These compounds, especially phospholipid polycyclic aromatic hydrocarbons, have a wide range of pharmacological applications, including embedded DNA and central nervous system, anti-tumor, anti-virus, anti-parasite, anti-bacterial, and antithrombotic effects. Unfortunately, the insufficient drug sources have limited the development of these compounds. In this study, we isolated salinpostin compounds from a fermentation solution of marine-derived Salinospora sp., which has a common bicyclic enol-phosphotriester core framework, as well as potent and selective antimalarial activities against P. falciparum with EC_(50)=50 nmolL~(-1). The chemical synthesis of these compounds in greater quantities is necessary for their use in bioactivity studies. Thus we explored a short route with high yields and mild reaction conditions, which can generate combinatorial libraries for drug discovery and lead optimization. We developed a new total synthesis method for six cyclic enol-phosphotriester salinipotin compounds and their diastereomers. For the total synthesis of cyclipostin P, we prepared cyclic enol-phosphotriester salinipostin compounds in 10 steps from a readily accessible starting material, 1,3-dihydroxyacetone, and obtained an overall yield of 1.29%. We fully characterized these compounds by proton nuclear magnetic resonance(~1H-NMR), carbon-13 NMR(~(13)C-NMR), and high-resolution mass spectrometry(HRMS) analyses, and found they coincide absolutely with the same compounds reported previously.     

Seismogenic Structures of the 2006 ML4.0 Dangan Island Earthquake Offshore Hong Kong

The northern margin of the South China Sea, as a typical extensional continental margin, has relatively strong intraplate seismicity. Compared with the active zones of Nanao Island, Yangjiang, and Heyuan, seismicity in the Pearl River Estuary is relatively low. However, a ML4.0 earthquake in 2006 occurred near Dangan Island(DI) offshore Hong Kong, and this site was adjacent to the source of the historical M5.8 earthquake in 1874. To reveal the seismogenic mechanism of intraplate earthquakes in DI, we systematically analyzed the structural characteristics in the source area of the 2006 DI earthquake using integrated 24-channel seismic profiles, onshore–offshore wide-angle seismic tomography, and natural earthquake parameters. We ascertained the locations of NW-and NE-trending faults in the DI sea and found that the NE-trending DI fault mainly dipped southeast at a high angle and cut through the crust with an obvious low-velocity anomaly. The NW-trending fault dipped southwest with a similar high angle. The 2006 DI earthquake was adjacent to the intersection of the NE-and NW-trending faults, which suggested that the intersection of the two faults with different strikes could provide a favorable condition for the generation and triggering of intraplate earthquakes. Crustal velocity model showed that the high-velocity anomaly was imaged in the west of DI, but a distinct entity with low-velocity anomaly in the upper crust and high-velocity anomaly in the lower crust was found in the south of DI. Both the 1874 and 2006 DI earthquakes occurred along the edge of the distinct entity. Two vertical cross-sections nearly perpendicular to the strikes of the intersecting faults revealed good spatial correlations between the 2006 DI earthquake and the low to high speed transition in the distinct entity. This result indicated that the transitional zone might be a weakly structural body that can store strain energy and release it as a brittle failure, resulting in an earthquake-prone area.     

风机基础TLP平台在波浪中运动性能的CFD数值分析

随着海上风能的开发向深水发展，支撑风机的载体平台越来越受到关注。在经济性与安全性、稳定性的多重要求下，张力腿平台（TLP）在海洋风能资源的开发中体现出了重要地位。采用基于开源平台OpenFOAM开发的计算流体动力学（CFD）水动力学求解器naoe-FOAM-SJTU对一座处于中等水深下的风机基础水下TLP（STLP）的运动响应进行了数值模拟与研究。文中使用弹簧锚链模型模拟STLP的垂向系泊锁链系统，模拟该平台在不同波浪环境下的运动响应情况。首先将STLP单自由度自由衰减CFD模拟结果与已有全耦合时域分析结果进行对比，验证了naoe-FOAM-SJTU求解器及使用弹簧模型模拟STLP系泊系统的准确性与可靠性。随后在考虑非线性波浪载荷的情况下研究极端海况下与一般作业海况下STLP的运动响应情况，计算工况中的风机基础所受弯矩及锚链受力情况，并详细展示流场、速度场信息，分析高阶波浪成分、不同海况等条件对于STLP运动性能的影响。研究结果表明，TLP在中等水深中具有良好的运动性能，naoe-FOAM-SJTU求解器可以有效模拟水中生产平台在波浪环境下的水动力问题，并可以对整个流场进行可视化展示与分析。     

羌塘中部白措花岗岩岩石地球化学特征、锆石U Pb年龄和Hf同位素组成及其构造意义

本文对羌塘中部白措花岗岩的研究表明，岩体是由花岗闪长岩和二长花岗岩同时侵位的复合岩基，锆石U Pb年龄分别为213. 8±1. 3 Ma、210. 0±1. 1 Ma和208. 1±1. 4 Ma。白措花岗岩为硅过饱和的准铝质—弱过铝质岩石，Eu负异常明显，富集大离子亲石元素，亏损高场强元素，显示典型的壳源特征。εHft)为负值，主要集中于-10～-15，对应的Hf同位素二阶段模式年龄峰值为1. 78 Ga，显示源区为古元古代古老地壳；同时，花岗岩中含有大量闪长质暗色包体，表明有壳幔岩浆混合作用，推测为同时期玄武质岩浆的底侵作用，在地壳深部诱发富硅质基底岩石重熔，快速喷发形成玄武岩—流纹岩双峰式组合，而花岗岩则是由玄武质岩浆在地壳充分熔融后，岩浆沿羌塘中部已有的构造破碎带侵入形成，并且在熔融过程中有镁铁质岩浆注入少量结晶的长英质岩浆中形成暗色包体。因此，花岗岩与双峰式火山岩是同一裂陷动力机制的产物。花岗岩的侵入预示了晚三叠世羌塘盆地构造岩浆活动的结束，之上开始了羌塘侏罗纪海相盆地的沉积。