赤潮治理方法综述

文章综述目前赤潮治理的主要方法,其中物理法重点介绍机械搅动法、超声波法、吸附法和气浮法,化学法重点介绍无机药剂法、有机药剂法和胶体絮凝沉淀法,生物法主要介绍引入赤潮藻类生物天敌、微生物技术和化感技术,分析各自优势和不足,采用微生物技术和化感技术具有重要意义和发展前景。     

Salinivibrio sp.YH4胞外丝氨酸蛋白酶EYHS耐盐性及生物信息学分析

摘要：目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性，属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高，α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高，且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸，并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示，α螺旋和β片层围成了蛋白酶的催化腔，EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体，且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性，并有助于其催化功能的发挥，为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。     

ATG-6118H型测氢仪校准与性能检测及其结果

氢气具有较强的映震灵敏性,氢气观测是探索地震短临预报的新途径。ATG-6118H痕量氢气在线自动分析仪是一种用于测量地下流体逸出氢气的新型数字化观测仪器,可以现场进行全自动连续测定,具有灵敏度高、自动化程度高、功耗低、操作简单等特点,具有网络远程诊断和数据处理分析功能,可以精确分析空气及井水中逸出的痕量氢背景值。目前我国尚未形成统一的痕量氢分析仪的检测规范,本文根据实际检测要求,对ATG-6118H痕量氢气在线自动分析仪进行了校准实验、检出限实验以及精确度实验,并对8台仪器性能进行了对比。通过指标评价确定了该仪器的性能检测方法的可行性,适合在具备数字化观测条件的全国地震地下流体台站以及具备断层气观测条件的台站推广应用。     

东天山博格达晚石炭世双峰式火山岩地球化学特征及意义

东天山博格达造山带晚石炭世柳树沟组为一套由玄武岩和流纹岩组成的双峰式火山岩,形成于晚石炭世,其Si O_2含量介于46.18%～46.56%和76.06%～76.25%之间,具有明显的Daly成分间断。其中,玄武岩具富Na贫K特征,Ti O_2、Al_2O_3、Ca O和MgO含量均较高,∑REE为75.54×10~(-6)～80.22×10~(-6),LREE/HREE值为3.00～3.12,以富集Ba、Rb等大离子亲石元素(LILE)和不相容元素(P、K),相对亏损Ti、Ta、Nb等高场强元素(HFSE)和不相容元素(U、Th)为特征;流纹岩Na_2O/K_2O值为0.32～0.36,属低Ti、低Mg类流纹岩,∑REE为520.72×10~(-6)～595.26×10~(-6),LREE/HREE值为5.60～6.53,具有Rb、Th、K、La、Ce、Zr、Hf、Sm等元素的富集以及Ba、U、Ta、Nb、Sr、P和Ti元素的亏损特征。柳树沟组双峰式火山岩形成于大陆裂谷环境,具板内成因特征,玄武岩可能为亏损尖晶石相地幔橄榄岩向石榴石相地幔橄榄岩过渡相较高程度部分熔融的产物,受到地壳物质混染;流纹岩具典型的A型花岗岩的地球化学特征。     

象山港海域分区评价方法研究

文章根据2011-2018年在象山港海域调查的象山港水文、水团、水环境、沉积物环境、生物生态等调查数据，将象山港海域划分为若干个具有不同生态变化特征的区域，研究象山港海域内的空间异质性，以便剖析各区域环境的问题。研究发现：象山港水交换特征、水团分布、水环境、沉积环境和生物生态特征将象山港划分为A、B、C、D、E 5个区评价较为合理。该方法可以有效并合理地对象山港海域做出评价，并为相关海洋科学工作者和管理者提供科学依据。     

Refining the ice flow chronology and subglacial dynamics across the migrating Labrador Divide of the Laurentide Ice Sheet with age constraints on deglaciation

The Laurentide Ice Sheet was characterized by a dynamic polythermal base. However, important data and knowledge gaps have led to contrasting reconstructions in areas such as the Labrador Ice Divide. In this study, detailed fieldwork was conducted at the southeastern edge of a major landform boundary to resolve the relative ice flow chronology and constrain the evolution of the subglacial dynamics, including the migration and collapse of the Labrador Ice Divide. Surficial mapping and analysis of 94 outcrop‐scale ice flow indicators were used to develop a relative ice flow chronology. ¹⁰Be exposure ages were used with optical ages to confine the timing of deglaciation within the study area. Four phases of ice flow were identified. Flow 1 was a northeasterly ice flow preserved under non‐erosive subglacial conditions associated with the development of an ice divide. Flow 2 was a northwest ice flow, which we correlate to the Ungava Bay Ice Stream and led to a westward migration of the ice divide, preserving Flow 2 features and resulting in Flow 3's eastward‐trending indicators. Flow 4 is limited to sparse fine striations within and around the regional uplands. The new optical ages and ¹⁰Be exposure ages add to the regional geochronology dataset, which further constrains the timing of ice margin retreat in the area to around 8.0 ka. Copyright © 2019 The Authors. Journal of Quaternary Science Published by John Wiley & Sons Ltd.     

冰期—间冰期气候旋回中古火灾的变化规律及其控制因子

火对气候、生物地球化学循环和人类健康产生广泛影响,为了避开人类活动的干扰,在整体上把握古火灾、古植被和古气候之间的相互作用关系,并为进一步的深入研究古火灾提供框架,本文聚焦冰期—间冰期时间尺度,整理了深海沉积、湖泊沉积、黄土等沉积物中的古火灾信息,并与对应的古气候、古植被情况结合讨论,总结归纳在冰期—间冰期尺度上不同地区的火灾机制情况,并分析其异同及原因。全球不同海域的深海沉积物中黑碳记录所指示的古火灾没有统一的规律和解释,自然火灾发生机制存在区域性差异。长时间尺度的湖泊记录反映的冰期—间冰期火灾活动情况较一致,今后更多长时间尺度的湖泊沉积物研究可以为火灾活动的轨道驱动研究增添有力证据。黄土中的冰期—间冰期的火灾演化规律存在不同观点,这可能是选用火灾代用指标不同导致,黄土中的黑碳沉积通量可能更准确的揭示古火灾历史。     

应用重力场模型GL1500E和LLR天平动参数估算月核大小及其组成

针对月核大小及密度估计问题,利用高分辨率重力场模型GL1500E的二阶位系数和LLR(lunar laser ranging)天平动参数,考虑月核分层为外核和内核的情况,结合非线性粒子群优化算法,对月核大小和组成进行了估计。大批量的统计结果表明,大概率分布的外核半径rc1约为469 km,内核半径rc2约为303 km,外核密度ρc1约为4613 kg/m3,内核密度ρc2约为7004 kg/m3,月幔密度ρm约为3340 kg/m3。月幔密度非常接近地质研究结果3360 kg/m3,内外核半径与近期其他研究结果相近,估算的月核大小与密度组成具有一定的参考价值。若月核由纯铁和硫化亚铁组成,则研究表明,内核大部分由纯铁组成,外核大部分由硫化亚铁组成。     

Predicting size effect on diffusion-limited current density of oxygen reduction by copper wire

The size effect of copper wire radius (0.04–0.82 mm) on the diffusion-limited current density of an oxygen reduction reaction in stagnant simulated seawater (naturally aerated 0.5 mol/L NaCl) is investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) and compared with the results obtained in 0.5 mol/L H2SO4. In the oxygen diffusion-limited range, size effect is found to occur independent of electrolytes, which is attributed to non-linear diffusion. Additionally, to sati...     

Predicting size effect on diffusion-limited current density of oxygen reduction by copper wire

The size effect of copper wire radius (0.04–0.82 mm) on the diffusion-limited current density of an oxygen reduction reaction in stagnant simulated seawater (naturally aerated 0.5 mol/L NaCl) is investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) and compared with the results obtained in 0.5 mol/L H2SO4. In the oxygen diffusion-limited range, size effect is found to occur independent of electrolytes, which is attributed to non-linear diffusion. Additionally, to satisfy application in a marine setting, an empirical equation correlating oxygen diffusion-limited current density to copper wire radius is proposed by fitting experimental data.