Distributions of dissolved and particulate biogenic thiols in the subartic Pacific Ocean

Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation.     

Interpreting tracer breakthrough tailing in a conduit-dominated karstic aquifer

Breakthrough tailing has been observed during dye-tracing recovery tests in the Norville aquifer system (chalk), France. Karst-conduit flow and transport parameters were assessed using two different interpretative methods: the linear graphical method and the Chatwin method (implemented in the Qtracer2 program). The linear graphical method was used to model the observed tailing effects, which was explained by a second smaller delayed breakthrough curve. By comparing the results of tracer-test interpretation for the two methods, it was possible to relate the area of this second curve to the importance of turbulent flow in spring discharge. The more turbulent the flow, the less important the contribution of the second breakthrough curve and the tailing effect. The observed tailing could possibly be controlled by hydrodynamics to a greater extent than usually expected, the tailing effects being mostly attributed to diffusion phenomena. Tailing effects were expected to increase with discharge and the piezometric level, which would have resulted in overpressure in conduits, fissure flooding, etc. Instead, breakthrough tailing tended to disappear with increasing aquifer discharge, which would support the hypothesis of there being mostly hydrodynamic-controlled tailing effects instead of matrix- or fissure-diffusion.An erratum to this article can be found at     

Lateral extrusion along the Altyn Tagh Fault,Qilian Shan (NE Tibet): insight from a 3D crustal budget

The lithospheric strike‐slip Altyn Tagh Fault has accommodated hundreds of kilometres of displacement between the Qaidam and Tarim blocks since its Eocene reactivation. However, the way the deformation is accommodated in the Qilian Shan and further east remains uncertain. Based on 360 km of north‐eastward migration of the relatively rigid Qaidam block along the Altyn Tagh Fault and 3D isovolumetric balancing of the crustal deformation within the Altyn Tagh Fault–Qilian Shan system, we demonstrate that 250 ± 28 km (43.8–49.4%) of N20E directed crustal shortening and an additional ~250–370 km of eastward motion of the Qilian Shan crust must be accounted for by strike‐slip faulting in the Qilian Shan and crustal thickening in the Qinling area, as well as by extension in the adjoining North China block graben systems.     

Orbital scale vegetation change in Africa

Palynological records of Middle and Late Pleistocene marine sediments off African shores is reviewed in order to reveal long-term patterns of vegetation change during climate cycles. Whether the transport of pollen and spores from the source areas on the continent to the ocean floor is mainly by wind or predominantly by rivers depends on the region. Despite the differences in transportation, accumulation rates in the marine sediments decline exponentially with distance to the shore. The marine sediments provide well-dated records presenting the vegetation history of the main biomes of western and southern Africa. The extent of different biomes varied with the climate changes of the glacial interglacial cycle. The Mediterranean forest area expanded during interglacials, the northern Saharan desert during glacials, and the semi-desert area in between during the transitions. In the sub-Saharan mountains ericaceous scrubland spread mainly during glacials and the mountainous forest area often increased during intermediate periods. Savannahs extended or shifted to lower latitudes during glacials. While the representation of the tropical rain forest fluctuated with summer insolation and precession, that of the subtropical biomes showed more obliquity variability or followed the pattern of glacial and interglacials.     

Influence des rejets atmosphériques d'anhydride sulfureux sur la qualité de l'eau des lacs de la région de Rouyn‐Noranda*

Résumé

En mars 1982, le ministère de l'Environnement du Québec a entrepris un échantillonnage physico‐chimique de 64 lacs de tête de la région de Rouyn‐Noranda. Les objectifs de l'étude étaient de déterminer la sensibilité des lacs de cette région et de délimiter l'aire d'influence de la plus importante source anthropique d'émission d'anhydride sulfureux au Québec.

Le traitement graphique et statistique des résultats, ainsi que l'application de modèles empiriques d'acidification ont permis de dégager les zones les plus vulnérables à l'acidification. L'application de ces techniques d'analyse a montré, entre autres, que les concentrations de sulfates en lac étaient beaucoup plus élevées à proximité de Rouyn‐Noranda où est située l'usine Mines Noranda Itée. De fait, la concentration de sulfates dans les lacs de cette région passe de 16 mg L^?1, aux alentours de Rouyn‐Noranda, à moins de 2 mg L^?1 en direction du nord‐est, alors qu'elle baisse à 8 mg L^?1 en bordure de la rivière des Outaouais. De plus, en faisant abstraction de la distribution en forme de cloche des concentrations de sulfates autour de Rouyn‐Noranda, l'étude a permis de faire ressortir la décroissance générale des sulfates du sud‐ouest vers le nord‐est.

Les points majeurs qui ressortent de cette étude sont la présence de lacs très acides à proximité de Rouyn‐Noranda et V extrême vulnérabilité des plans d'eau situés au sud et sud‐est de la ville. En effet, l'eau des lacs de la région du Témiscamingue est en général moins minéralisée et plus acide que celle des lacs au nord de cette région. Cette distinction est due à la nature géologique des substrats dans les bassins versants. Ainsi, les lacs sensibles à l'acidification sont principalement situés sur des bassins versants associés à des roches granitiques et gneissiques, comparativement aux roches volcaniques et aux dépôts d'argiles lacustres qui caractérisent les lacs aux eaux plus minéralisées.     

What meta-analysis can tell us about vulnerability of marine biodiversity to ocean acidification?

Ocean acidification has been proposed as a major threat for marine biodiversity. Hendriks et al. [Hendriks, I.E., Duarte, C.M., Alvarez, M., 2010. Vulnerability of marine biodiversity to ocean acidification: a meta-analysis. Estuarine, Coastal and Shelf Science, doi:10.1016/j.ecss.2009.11.022.] proposed an alternative view and suggested, based on a meta-analysis, that marine biota may be far more resistant to ocean acidification than hitherto believed. However, such a meta-analytical approach can mask more subtle features, for example differing sensitivities during the life-cycle of an organism. Using a similar metric on an echinoderm database, we show that key bottlenecks present in the life-cycle (e.g. larvae being more vulnerable than adults) and responsible for driving the whole species response may be hidden in a global meta-analysis. Our data illustrate that any ecological meta-analysis should be hypothesis driven, taking into account the complexity of biological systems, including all life-cycle stages and key biological processes. Available data allow us to conclude that near-future ocean acidification can/will have dramatic negative impact on some marine species, including echinoderms, with likely consequences at the ecosystem level.     

Study of the moist Convective Boundary Layer structure by backscattering lidar

Measurements of the structure of the Convective Boundary Layer (CBL) were made from the ground and from the ARAT aircraft with a backscattering lidar during the preliminary phase of the French project LEANDRE. A numerical model of Mie theory diffusion was used to determine a theoretical profile of the extinction coefficient, as a function of relative humidity. Comparisons between theoretical and measured profiles were made. Good agreement was found, which confirms that the variation of the extinction coefficient in the CBL is primarily controlled by the relative humidity. This paper also presents a detailed analysis of the small-scale structure of the CBL. The normalized length and number of thermals are estimated. Results are in agreement with previousin-situ measurements. An analysis of the bidimensional cross-section of the extinction coefficient shows that this coefficient permits one to retrieve more quantitative information than the range-corrected signal, as the fractions of entrained air and surface-layer air at a given altitude.     

Transport and deposition of suspended particles in saturated porous media: hydrodynamic effect

A laboratory study was undertaken to determine the transport and deposition rate of suspended particles in columns of saturated porous media (gravel and glass beads), where the porous media were subjected to steady-state flow. Silt particles with a mode of 14 μm diameter (used as the suspended particles) and fluorescein (as the conservative tracer) were injected into the columns in short pulses. The breakthrough curves were competently described with the analytical solution of a convection–dispersion equation with a first-order deposition rate. The experiments were performed using different flow rates. The suspended particle size distribution, the porous media, and the flow rates themselves were the main factors retained in this study to investigate the mechanisms governing the transport and deposition kinetics in detail. The results showed the existence of a flow rate, beyond which suspended particles travel faster than the conservative tracer. A decrease of the deposition rate of suspended particles beyond a critical flow velocity was also observed. Such behaviour led to consideration of the couple hydrodynamic-gravity forces at high flow rates. As the hydrodynamic force increases, particle deposition rates are reduced due to the effect of hydrodynamic forces inhibiting the deposition.     

Fine sediment transport and accumulations at the mouth of the Seine estuary (France)

A comprehensive study of fine sediment transport in the macrotidal Seine estuary has been conducted, including observations of suspended particulate matter (SPM), surficial sediment, and bathymetric data, as well as use of a three dimensional mathematical model. Tide, river regime, wind, and wave forcings are accounted. The simulated turbidity maximum (TM) is described in terms of concentration and location according to tidal amplitude and the discharge of the Seine River. The TM is mainly generated by tidal pumping, but can be concentrated or stretched by the salinity front. The computed deposition patterns depend on the TM location and are seasonally dependent. The agreement with observations is reasonable, although resuspension by waves may be overestimated. Although wave resuspension is likely to increase the TM mass, it generally occurs simultaneously with westerly winds that induce a transverse circulation at the mouth of the estuary and then disperse the suspended material. The resulting effect is an output of material related to wind and wave events, more than to high river discharge. The mass of the computed TM remains stable over 6 months and independent of the river regime, depending mainly on the spring tide amplitude. Computed fluxes at different cross-sections of the lower estuary show the shift to the TM according to the river flow and point out the rapidity of the TM adjustment to any change of river discharge. The time for renewing the TM by riverine particles has been estimated to be one year.