Macroscopic criteria for Green type porous materials with spheroidal voids: application to double porous materials

Combined effects of matrix plastic compressibility and void shape are investigated for ductile porous materials. To this end, a spheroidal volume containing a confocal spheroidal (prolate or oblate) void subjected to uniform strain rate boundary conditions has been first studied. A Green type matrix is chosen as a prototype for investigating effects of plastic compressibility. This is carried out by using a kinematics limit analysis theory from which a closed‐form expression of the macroscopic criterion is established for the considered class of materials. These results are then extended to ductile porous materials made up of a green matrix containing randomly oriented spheroidal voids. In the framework of a two‐step homogenization procedure, the obtained results are implemented to describe the macroscopic behavior of double porous materials involving spherical voids at the microscale and randomly oriented and distributed spheroidal voids at the mesoscale. For validation purpose, the new derived criteria are assessed and validated by comparing their predictions to available upper bounds and numerical data from literature. Copyright © 2017 John Wiley & Sons, Ltd.     

Investigation of local time dependence of Mercury's sodium exosphere based on a numerical simulation

Mercury has a surface-bounded exosphere (SBE) similar to that of the Moon. One of the atmospheric species, sodium, was found by ground-based observations to be the most prominent component. Mercury's sodium SBE is known to be non-uniform with respect to local time (LT) in low-latitude regions: the sodium column density in the dawn-side region is larger than that in the dusk-side region, and the sodium abundance is the largest in the morning-noon region. To reveal the production processes for the exosphere near Mercury's surface, the LT dependence of the exosphere was investigated through a numerical simulation. Three data sets of sodium column densities observed for the dawn-side hemisphere, observed by Sprague et al. [1997. Distribution and abundance of sodium in Mercury's atmosphere, 1985-1988. Icarus 12, 506-527], were compared with results simulated by a 3D Monte Carlo method, and the source rates and density of sodium of the planetary surface were estimated. In the simulation, the photon-stimulated desorption (PSD) and thermal desorption (TD) processes were assumed as the release mechanisms. The sodium source rates for the three data sets, at respective heliocentric distances of about 0.33, 0.42, and 0.44 AU, were estimated as 1-4×10⁸ Na/cm²/s with weak LT dependence. In contrast, the expected sodium surface density showed clear dependence on LT and the heliocentric distance. The sodium surface density decreases from early morning to noon by a few orders, and, particularly for large heliocentric distances, the surface is in a condition of sodium excess and depletion with respect to the surface sodium density assumed by Killen et al. [2004. Source rates and ion recycling rates for Na and K in Mercury's atmosphere. Icarus 171, 1-19] in the early morning and morning-noon regions, respectively. This study implies that the decrease in sodium surface density from the early morning to noon regions might produce the characteristic LT dependence in the low-latitude dawn-side region.     

Sound velocity and density of liquid Ni68S32 under pressure using ultrasonic and X-ray absorption with tomography methods

A new experimental setup for simultaneous P-wave velocity (V_P) and density (ρ) measurements for liquid alloys is developed using ultrasonic and X-ray absorption methods combined with X-ray tomography at high pressures and high temperatures. The new setup allows us to directly determine adiabatic bulk moduli (K_S) and to discuss the correlation between the V_P and ρ of the liquid sample. We measured V_P and ρ of liquid Ni₆₈S₃₂ up to 5.6 GPa and 1045 K using this technique. The effect of pressure on the V_P and ρ values of liquid Ni₆₈S₃₂ is similar to that of liquid Fe₅₇S₄₃. (Both compositions correspond to near-eutectic ones.) The obtained K_S values are well fitted to the finite strain equation with a $K_{{\text{S}}_0}$ value (K_S at ambient pressure) of 31.1 GPa and a dK_S/dP value of 8.44. The measured V_P was found to increase linearly with increasing ρ, as approximated by the relationship: V_P [m/s] = 1.29 ρ [kg/m³] – 5726, suggesting that liquid Ni–S follows an empirical linear relationship, Birch's law. The dV_P/dρ slope is similar between Ni₆₈S₃₂ and Fe₅₇S₄₃ liquids, while the V_P–ρ plot of liquid Ni–S is markedly different from that of liquid Fe–S, which indicates that the effect of Ni on Birch's law is important for understanding the V_P–ρ relation of planetary and Moon's molten cores.     

Intermittent generation of mafic enclaves in the 1991–1995 dacite of Unzen Volcano recorded in mineral chemistry

Mafic enclaves in the 1991–1995 dacite of Unzen volcano show chemical and textural variability, such as bulk SiO₂ contents ranging from 52 to 62 wt% and fine- to coarse-grained microlite textures. In this paper, we investigated the mineral chemistry of plagioclase and hornblende microlites and distinguished three enclave types. Type-I mafic enclaves contain high-Mg plagioclase and low-Cl hornblende as microlites, whereas type-III enclaves include low-Mg plagioclase and high-Cl hornblende. Type-II enclaves have an intermediate mineral chemistry. Type-I mafic enclaves tend to show a finer-grained matrix, have slightly higher bulk rock SiO₂ contents (56–60 wt%) when compared with the type-III mafic enclaves (SiO₂?=?53–59 wt%), but the overall bulk enclave compositions are within the trend of the basalt–dacite eruptive products of Quaternary monogenetic volcanoes around Unzen volcano. The origin of the variation of mineral chemistry in mafic enclaves is interpreted to reflect different degree of diffusion-controlled re-equilibration of minerals in a low-temperature mushy dacitic magma reservoir. Mafic enclaves with a long residence time in the dacitic magma reservoir, whose constituent minerals were annealed at low-temperature to be in equililbrium with the rhyolitic melt, represent type-III enclaves. In contrast, type-I mafic enclaves result from recent mafic injections with a mineral assemblage that still retains the high-temperature mineral chemistry. Taking temperature, Ca/(Ca?+?Na) ratio of plagioclase, and water activity of the hydrous Unzen magma into account, the Mg contents of plagioclase indicate that plagioclase microlites in type-III enclaves initially crystallized at high temperature and were subsequently re-equilibrated at low-temperature conditions. Compositional profiles of Mg in plagioclase suggest that older mafic enclaves (Type-III) had a residence time of ~100 years at 800 °C in a stagnant magma reservoir before their incorporation into the mixed dacite of the 1991–1995 Unzen eruption. Presence of different types of mafic enclaves suggests that the 1991–1995 dacite of Unzen volcano tapped mushy magma reservoir intermittently replenished by high-temperature mafic magmas.     

Disturbance of recruitment success of mantis shrimp in Tokyo Bay associated with effects of hypoxia on the early life history

We investigated effects of severe hypoxia (dissolved oxygen <1 ml l⁻¹) on recruitment of mantis shrimp Oratosquilla oratoria in Tokyo Bay. Ten-year field surveys were conducted to examine quantitative relationships in annual mean densities of larvae and juveniles, and spatial distribution of juveniles and severe hypoxia. There was no significant correlation between annual mean densities of larvae and juveniles, suggesting that mortality during larval or juvenile stages varies among years, which might have regulated abundance of young-of-the-year juveniles. Juvenile density was low in the severely hypoxic area, implying that hypoxia could affect survivals and spatial distribution of juveniles. Meanwhile, there are yearly fluctuations in juvenile density in normoxic areas of both northern and southern part of the bay. This evidence suggests that abundance of post-settled juveniles might have been determined by not only effects of hypoxia, but also other factors influencing mortality during the early life stages.     

次固结沉降对压缩时间曲线的影响研究

提出了一种新的考虑次固结影响的一维固结方程,并用于计算粘土的压缩时间关系曲线。通过试验结果和计算分析验证了该方程的合理性。为了考察不同最大排水距离和加载时间间隔对固结过程的影响,对重塑正常固结粘土进行了一系列固结试验,研究了次固结对固结系数和压缩量的影响;将试验结果与解析方法的预测结果进行了比较。可为软土路基和填土路基的沉降问题提供设计参考。     

Optical properties of the red tide in Isahaya Bay,southwestern Japan: Influence of chlorophyll a concentration

Remote sensing reflectance [R _rs(λ)] and absorption coefficients of red tides were measured in Isahaya Bay, southwestern Japan, to investigate differences in the optical properties of red tide and non-red tide waters. We defined colored areas of the sea surface, visualized from shipboard, as “red tides”. Peaks of the R _rs(λ) spectra of non-red tide waters were at 565 nm, while those of red tides shifted to longer wavelengths (589 nm). The spectral shape of R _rs(λ) was close to that of the reciprocal of the total absorption coefficient [1/a(λ)], implying that the R _rs(λ) peak is determined by absorption. Absorption coefficients of phytoplankton [a _ph(λ)], non-pigment particles and colored dissolved organic matter increased with increasing chlorophyll a concentration (Chl a), and those coefficients were correlated with Chl a for both red tide and non-red tide waters. Using these relationships between absorption coefficients and Chl a, variation in the spectrum of 1/a(λ) as a function of Chl a was calculated. The peak of 1/a(λ) shifted to longer wavelengths with increasing Chl a. Furthermore, the relative contribution of a _ph(λ) to the total absorption in red tide water was significantly higher than in non-red tide water in the wavelength range 550–600 nm, including the peak. Our results show that the variation of a _ph(λ) with Chl a dominates the behavior of the R _rs(λ) peak, and utilization of R _rs(λ) peaks at 589 and 565 nm may be useful to discriminate between red tide and non-red tide waters by remote sensing.