Structure and electrical properties of Ca2+-doped (Na0.47Bi0.47Ba0.06)TiO3 lead-free piezoelectric ceramics

The lead-free piezoelectric ceramics (Na_.47Bi_.47Ba_.06)_1-xCa_xTiO₃ (x?=?0, 0.01, 0.02, 0.03, 0.05, and 0.08, abbreviated as BNBTC/0, BNBTC/1, BNBTC/2, BNBTC/3, BNBTC/5, and BNBTC/8, respectively) were obtained using the solid-state reaction method. The structure, electric conductivity, and dielectric, ferroelectric, and piezoelectric properties of the Ca²⁺-doped (Na_.47Bi_.47Ba_.06)TiO₃ ceramics were thoroughly investigated. The ceramics sintered at 1200?°C exhibit dense microstructures, having relative densities higher than 96%. The X-ray diffraction results demonstrate that all ceramics have a pure perovskite structure. The mean grain sizes of the ceramics are related to the Ca²⁺ quantity. A small quantity of Ca²⁺ ions (x?≤?0.03) improves the piezoelectric and ferroelectric properties of the samples. The dielectric behavior of the samples is sensitive to the Ca²⁺ content and electric poling. The results demonstrate that the electrical properties of the (Na_.47Bi_.47Ba_.06)TiO₃ lead-free ceramics can be well tuned by varying the Ca²⁺ quantity.     

GIS在深圳市三防指挥信息系统中的应用

深圳市三防指挥信息系统利用GIS技术,结合水利(水务)、防汛、抗旱的具体业务,建立了水情遥测数据处 理分系统、工况监测数据处理分系统、水务行业三防信息管理分系统、决策支持分系统、水源优化调度分 系统,提高了现代化管理水平。     

溶剂浸渍树脂的萃取分离性能研究

介绍了溶剂浸渍树脂的制备及性能,阐述了溶剂浸渍树脂在产物提纯和废水处理等分离过程中的应用,并对使用溶剂浸渍树脂处理含酚废水进行了初步研究.     

黄骅坳陷新生代断裂构造系统研究

黄骅坳陷断裂构造极为发育，其新生代构造系统主要为伸展构造系统，以铲形正断层或坡坪式正断层为主干伸展断层，以不同尺度的北东一北东东向正断层和具调节性质的北西一北西西向断层为特征。经过对黄骅坳陷新生代构造应力场的分析，黄骅坳陷盖层中极难出现明确的走滑断裂，其雁列状排列的断层应为倾斜滑动断层；黄骅坳陷中不同凹陷或断块之间不同的伸展程度往往为横向地垒状凸起、鼻状凸起或鼻状背斜所调节，在横向凸起和凹陷之间伴生北西向正断层，它们与挤压变形体系中具有走滑性质的横向变换断层又有本质上的不同。     

走向长壁俯仰斜连续综放开采技术的实践

对走向长壁俯仰斜连续综放开采技术进行了实践,积累了大量的技术数据,针对回采过程中遇到的问题,提出了切实可行的技术措施,经济技术效果显著。     

通信性能评估的仿真实验研究

研究了流量控制和差错控制对通信性能的综合影响，着重分析了停止-等待协议和连续ARQ协议的优缺点，讨论了信道利用率和帧长的关系。介绍了几种多点接人技术的基本原理，如CSMA和CSMA／CD，并给出了各自相应的性能仿真曲线。所设计的通信性能评估实验，仿真界面形象丰富，与实验知识点紧密结合，可以大大提高实验教学的效率和质量。     

Deformation evolution during initiation of transgranular stress corrosion cracking

Face centered cubic metals and alloys have multiple slip systems and are characterized by high dislocation velocities. Nevertheless, these materials suffer from transgranular stress corrosion cracking (T-SCC), that occurs by environmentally-induced cleavage. Since plasticity precedes fracture in all T-SCC phenomena, the evolution of deformation patterning during T-SCC is an important element of the local microfracture mode. Experimental observations show that the presence of the SCC-causing environment during straining is promoting localized plastic deformation at the near-surface region and producing an entirely different deformation pattern compared with that developing in laboratory air. The deformation evolving in the presence of the SCC electrolyte is highly localized, exhibiting closely spaced, coarse slip bands. The amount of localized strain developing at the near-surface region prior to nucleation of stress corrosion cracks is equivalent to the strain required for ductile fracture of the material in air, suggesting the existence of a fundamental fracture criterion. The above phenomenology of the deformation evolution is considered in relation to T-SCC initiation and propagation. The T-SCC is suggested to be a macroscopically brittle but microscopically ductile fracture occurring by localized plastic flow. An environment-induced deformation localization mechanism is described where the role of the environment involves generation of vacancies and subsequent dislocation nucleation from the near-surface region at loads well below those required for normal yielding. The evolution of the localized deformation pattern during T-SCC is suggested to be an outcome of nonuniformity and periodicity in the dissolution process.Presented at Fourth Greek National Congress on Mechanics, 26–29 June 1995, held at Xanthi, Greece.     

湿硫化氢环境下的球罐腐蚀状况分析

在湿硫化氢环境下 ,尤其储存介质中的硫化氢含量超标时 ,很容易对储存容器壳体 (含焊缝和母材 )造成硫化氢应力腐蚀或氢鼓包。作者较仔细分析了 1 0 0 0m3 丙烯球罐产生硫化氢应力腐蚀开裂和40 0m3 LPG球罐产生氢鼓包的原因。提出了此类设备在设计选材、设备制造、施工安装和使用维护等环节应注意的问题。     

水溶性丙烯酸涂料的环氧树脂改性

本实验论述了水溶性丙烯酸钢铁底漆涂料制备、性能以及用环氧树脂对其进行改性。原水溶性丙烯酸钢铁底漆涂料在进行耐盐雾测定试验时仅为 72h ,未通过国家规定标准。本实验的目的在于 ,以丙烯酸树脂为主要成膜物质 ,加入其他的辅助成膜物质 ,如环氧树脂来改善其抗盐雾、抗腐蚀、耐候等性能。结果表明 ,一定温度下在水溶性丙烯酸钢铁底漆涂料中加入 1/ 7的环氧树脂后 ,经测定其耐盐雾性可达 10 6h ,达到了国家的规定标准