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1.
A novel CdS/CaFe2O4 (CS/CFO) heterogeneous p-n junction was created by thermal deposition of CaFe2O4 nanoparticles on CdS rods. The CS/CFO hetero-structured photocatalysts exhibited increasingly efficient visible light harvesting compared to the bare CdS. The CS/CFO composites also presented higher photocurrent and slower decay of photoluminescence, suggesting a better separation of the photo-generated electrons and holes. The photocatalytic H2 evolution quantity on the optimized CS/CFO composite from water in the presence of ethanol was up to 2200 μmol after 3-h visible light illumination, which is more than twice that of the pristine CdS. The chemical interaction between CdS and CaFe2O4 was confirmed by the shifts in the XPS peaks, which made it possible for the charge carriers to transfer across the p-n junction interface. This research highlights the importance of forming an interfacial p-n heterojunction between two semiconductors for efficient charge separation and improved photocatalytic performance. 相似文献
2.
A new aqueous slurry-based laminated object manufacturing process for porous ceramics is proposed: firstly, an organic mesh sheet is pre-paved as a pore-forming template before slurry layer scraping; secondly, the 2D pattern is built with laser outline cutting of the dried mesh–ceramic composite layer; finally, the pore structure is formed after degreasing and sintering. Alumina parts with porosities of 51.5 %, round hole diameters of 80 ± 5 μm were fabricated using 70 wt. % solid content slurry and 100 mesh nylon net. Using an organic mesh as the framework and template not only reduces the risk of damage of the green body but also ensures the regularity, uniformity and connectivity of the micron scaled pore network. The layer-by-layer drying method avoids the delamination phenomenon and improves the paving density. The new method can realize the flexible design of the pore structure by using various organic mesh templates. 相似文献
3.
4.
济阳坳陷下古生界潜山油气藏特征及成藏模式 总被引:1,自引:1,他引:0
济阳坳陷下古生界潜山具有多样性、复杂性的特点,潜山差异性的形成演化、油气成藏主控因素和控藏模式不明确,严重制约了该区潜山油气勘探。在潜山分类的基础上,综合利用系统恢复、分类对比和典型解剖等方法,揭示了济阳坳陷下古生界不同类型潜山的形成演化过程和油气成藏主控因素差异性,分类建立了油气成藏模式。研究表明,济阳坳陷下古生界主要发育高位新盖侵蚀残丘潜山、中位古盖拉张断块潜山、中位新古盖拉张剪切断块潜山、中位中古盖挤压拉张断块潜山和低位古盖拉张滑脱断块潜山5种潜山类型。不同类型潜山的形成演化和油气成藏各具特色,其中,高位新盖侵蚀残丘潜山的发育受隆升、侵蚀作用控制,油气成藏主要受控于油源和盖层条件,表现为"单向供烃、砂体-不整合岩溶体联合输导、残丘控藏"的成藏模式;中位古盖拉张断块潜山的发育受掀斜、断裂作用控制,油气成藏主要受控于储集条件,表现为"单向供烃、顺向断层输导、反向断层控藏"的成藏模式;中位新古盖拉张剪切断块潜山的发育受反转、翘倾和走滑切割作用控制,油气成藏主要受控于输导条件,表现为"多源供烃、断溶体立体输导、断裂控藏"的成藏模式;中位中古盖挤压拉张断块潜山的形成受强烈挤压、拉张滑脱作用控制,油气成藏主要受控于储集条件,表现为"多源供烃、断缝体输导、断褶控藏"的成藏模式;低位古盖拉张滑脱断块潜山的形成受强烈拉张滑脱作用控制,油气成藏主要受控于输导条件,表现为"顶部供烃、断缝体输导、断裂控藏"的成藏模式。 相似文献
5.
Bo Wang Edison Huixiang Ang Yang Yang Yufei Zhang Hongbo Geng Minghui Ye Cheng Chao Li 《Advanced functional materials》2020,30(28)
Orthorhombic molybdenum trioxide (MoO3) is one of the most promising anode materials for sodium‐ion batteries because of its rich chemistry associated with multiple valence states and intriguing layered structure. However, MoO3 still suffers from the low rate capability and poor cycle induced by pulverization during de/sodiation. An ingenious two‐step synthesis strategy to fine tune the layer structure of MoO3 targeting stable and fast sodium ionic diffusion channels is reported here. By integrating partially reduction and organic molecule intercalation methodologies, the interlayer spacing of MoO3 is remarkably enlarged to 10.40 Å and the layer structural integration are reinforced by dimercapto groups of bismuththiol molecules. Comprehensive characterizations and density functional theory calculations prove that the intercalated bismuththiol (DMcT) molecules substantially enhanced electronic conductivity and effectively shield the electrostatic interaction between Na+ and the MoO3 host by conjugated double bond, resulting in improved Na+ insertion/extraction kinetics. Benefiting from these features, the newly devised layered MoO3 electrode achieves excellent long‐term cycling stability and outstanding rate performance. These achievements are of vital significance for the preparation of sodium‐ion battery anode materials with high‐rate capability and long cycling life using intercalation chemistry. 相似文献
6.
研究了不同工艺参数对980 MPa级连续退火双相钢组织及力学性能的影响,利用光学显微镜、透射电镜(TEM)以及拉伸试验对双相钢的微观组织和力学性能进行测试及分析。结果表明:DP980钢的退火组织主要由铁素体、马氏体岛和少量的贝氏体组成,马氏体岛附近的位错密度较高。随着均热温度的升高,DP980钢的抗拉强度呈现先降低后升高的趋势,屈服强度与抗拉强度的趋势一致,伸长率先升高后降低。随着过时效温度的升高,DP980钢的抗拉强度和屈服强度降低,降低幅度较小,伸长率上升,但变化不明显,说明通过调整过时效温度来调控其力学性能的作用较小。 相似文献
7.
In this study, 30 subjects were exposed to different combinations of air temperature (Ta: 24, 27, and 30°C) and CO2 level (8000, 10 000, and 12 000 ppm) in a high-humidity (RH: 85%) underground climate chamber. Subjective assessments, physiological responses, and cognitive performance were investigated. The results showed that as compared with exposure to Ta = 24°C, exposure to 30°C at all CO2 levels caused subjects to feel uncomfortably warm and experience stronger odor intensity, while increased mental effort and greater intensity of acute health symptoms were reported. However, no significant effects of Ta on task performance or physiological responses were found. This indicated that subjects had to exert more effort to maintain their performance in an uncomfortably warm environment. Increasing CO2 from 8000 to 12 000 ppm at all Ta caused subjects to report higher rates of headache, fatigue, agitation, and feeling depressed, although the results were statistically significant only at 24 and 27°C. The text typing performance and systolic blood pressure (SBP) decreased significantly at this exposure, whereas diastolic blood pressure (DBP) and thermal discomfort increased significantly. These effects suggest higher arousal/stress. No significant interaction effect of Ta and CO2 concentration on human responses was identified. 相似文献
8.
Wei Lai Lihong Ge Huaming Li Yilin Deng Bin Xu Bo Ouyang Erjun Kan 《International Journal of Hydrogen Energy》2021,46(53):26861-26872
The electrochemical water splitting to produce H2 in high efficiency with earth-abundant-metal catalysts remains a challenge. Here, we describe a simple “cyclic voltammetry + ageing” protocol at room temperature to activate Ni electrode (AC-Ni/NF) for hydrogen evolution reaction (HER), by which Ni/Ni(OH)2 heterostructure is formed at the surface. In situ Raman spectroscopy reveals the gradual growth of Ni/Ni(OH)2 heterostructure during the first 30 min of the aging treatment and combined with polarization measurements, it suggests a positive relation between the Ni/Ni(OH)2 amount and HER performance of the electrode. The obtained AC-Ni/NF catalyst, with plentiful Ni–Ni(OH)2 interfaces, exhibits remarkable performance towards HER, with the low overpotential of only 30 mV at a H2-evolving current density of 10 mA/cm2 and 153 mV at 100 mA/cm2, as well as a small Tafel slope of 46.8 mV/dec in 1 M KOH electrolyte at ambient temperature. The excellent HER performance of the AC-Ni/NF could be maintained for at least 24 h without obvious decay. Ex situ experiments and in situ electrochemical-Raman spectroscopy along with density functional theory (DFT) calculations reveal that Ni/Ni(OH)2 heterostructure, although partially reduced, can still persist during HER catalysis and it is the Ni–Ni(OH)2 interface reducing the energy barrier of H1 adsorption thus promoting the HER performance. 相似文献
9.