聚乙二醇-三聚氰胺甲醛和聚乙烯醇半互穿网络的构建及表征

为提高三聚氰胺甲醛(MF)树脂制品的柔韧性,以聚乙二醇接枝三聚氰胺(M-PEG)替代部分三聚氰胺,并与甲醛、聚乙烯醇(PVA)在碱性条件下合成了聚乙二醇-三聚氰胺甲醛(PEG-MF)与PVA的半互穿聚合物网络体系(SemiIPN)。采用红外光谱、拉曼光谱、热重分析、差示扫描量热法等手段对Semi-IPN的微观结构进行了剖析,并分析了PEG、PVA等柔性链段对Semi-IPN黏度、游离甲醛含量、柔韧性等性能的影响。结果表明,PVA作为线型结构贯穿于聚乙二醇-三聚氰胺甲醛树脂交联网络体系结构中,形成了半互穿网络结构;所形成的Semi-IPN的热分解温度比MF树脂降低了60℃左右;Semi-IPN的韧性比纯MF树脂提高了800%,最高可达到19.700kJ/m2。     

Removal of imidacloprid and acetamiprid from tea infusions by microfiltration membrane

Removal of imidacloprid and acetamiprid in tea infusions by microfiltration membrane using dead‐end model was investigated in the present study. The results showed that microfiltration significantly promoted the removal of both pesticides (P < 0.05) in tea infusions. Furthermore, the extent of removal was strongly influenced by the pore size of membrane, operational pressure and the concentrations of tea infusions. The initial concentration of imidacloprid and acetamiprid showed no significant effect on their removal rates. The maximum removal rates were 79.7% for imidacloprid and 81.9% acetamiprid. The changes in major chemical components of tea infusions after microfiltration were evaluated. The results indicated that microfiltration caused no considerable changes in total polyphenols and total free amino acids, and small but statistically significant losses (6.3–18.0%) of eight catechins and three methylxanthines when filtration volume reached to 200 mL. The present study validated the application of microfiltration as a potentially feasible and promising method for the removal of imidacloprid and acetamiprid residues from tea infusions.     

海底电缆交叉鬼波化双检合并技术改进及应用

双检合并技术在海底电缆地震资料处理中被广泛应用,可衰减电缆鬼波的影响。传统方式以水、陆检记录的波场记录相同为假设,电缆鬼波压制效果差,合并效果并不理想。在分析交叉鬼波化双检合并技术基本原理的基础上,综合利用水检资料与陆检鬼波褶积的结果和陆检资料与水检鬼波褶积的结果求取刻度算子,同时在地震资料处理中利用陆检资料标定水检资料,从而优化了交叉鬼波化双检合并技术。实际资料处理结果表明,改进后的技术可有效衰减电缆鬼波,分离出上行波场,大幅度拓宽地震资料频带,提高地震资料分辨率,从而提供更丰富的构造细节信息。     

生产过程质量不合格品系统(IQS)方案建模及优化

针对不合格品的高效处置、数据的有效分析对企业质量控制具有深远的意义,其是装备制造领域质量管理研究的重点。文章以SAP接口二次开发、IQS流程建模、数据库建立、系统实用价值等方面展开详细论述,确保质量信息可追溯分析。     

新型计量斗在锰粉料制块配料中的改进应用

锰粉料制块是解决铁合金冶炼精料入炉的主要途径之一,生产过程中为解决锰粉料粘附计量斗的问题,介绍了一种新型计量斗,阐述他的结构特点和工作原理,实施改进后下料流畅,降低了劳动强度,提高了生产效率。     

Structural dependence of microwave dielectric properties of spinel structured Mg2(Ti1-xSnx)O4 solid solutions: Crystal structure refinement,Raman spectra study and complex chemical bond theory

Mg₂(Ti_1-xSn_x)O₄ (x?=?0–1) ceramics were prepared through conventional solid-state method. This paper focused on the dependence of microwave dielectric properties on crystal structural characteristics via crystal structure refinement, Raman spectra study and complex chemical bond theory. XRD spectrums delineated the phase information of a spinel structure, and structural characteristic of these compositions were achieved with the help of Rietveld refinements. Raman spectrums were used to depict the correlations between vibrational phonon modes and dielectric properties. The variation of permittivity is ascribed to the Mg₂(Ti_1-xSn_x)O₄ average bond covalency. The relationship among the B-site octahedral bond energy, tetrahedral bond energy and temperature coefficient are discussed by defining on the change rate of bond energy and the contribution rate of octahedral bond energy. The quality factor is affected by systematic total lattice energy, and the research of XPS patterns illustrated that oxygen vacancies can be effectively restrained in rich oxygen sintering process. Obviously, the microwave dielectric properties of Mg₂(Ti_1-xSn_x)O₄ compounds were obtained (${\epsilon }_r$= 12.18, $Q\times f$?=?170,130?GHz, ${\tau }_f$?=??53.1?ppm/°C, x?=?0.2).