Rainfall intensity affects runoff responses in a semi-arid catchment

The source and hydrochemical makeup of a stream reflects the connectivity between rainfall, groundwater, the stream, and is reflected to water quantity and quality of the catchment. However, in a semi-arid, thick, loess covered catchment, temporal variation of stream source and event associated behaviours are lesser known. Thus, the isotopic and chemical hydrographs in a widely distributed, deep loess, semi-arid catchment of the northern Chinese Loess Plateau were characterized to determine the source and hydrochemical behaviours of the stream during intra-rainfall events. Rainfall and streamflow were sampled during six hydrologic events coupled with measurements of stream baseflow and groundwater. The deuterium isotope (²H), major ions (Cl⁻, SO₄²⁻, NO₃⁻, Ca²⁺, K⁺, Mg²⁺, and Na⁺) were evaluated in water samples obtained during rainfall events. Temporal variation of ²H and Cl⁻ measured in the groundwater and stream baseflow prior to rainfall was similar; however, the isotope compositions of the streamflow fluctuated significantly and responded quickly to rainfall events, likely due to an infiltration excess, overland dominated surface runoff during torrential rainfall events. Time source separation using ²H demonstrated greater than 72% on average, the stream composition was event water during torrential rainfall events, with the proportion increasing with rainfall intensity. Solutes concentrations in the stream had loglinear relationships with stream discharge, with an outling anomaly with an example of an intra-rainfall event on Oct. 24, 2015. Stream Cl⁻ behaved nonconservative during rainfall events, temporal variation of Cl⁻ indicated a flush and washout at the onset of small rainfall events, a dilution but still high concentration pattern in high discharge and old water dominated in regression flow period. This study indicates rainfall intensity affects runoff responses in a semi-arid catchment, and the stored water in the thick, loess covered areas was less connected with stream runoff. Solute transport may threaten water quality in the area, requiring further analysis of the performance of the eco-restoration project.     

湖南省似大地水准面2017模型及精度分析

利用近7万个湖南及邻近省份重力观测数据、502个GNSS/水准控制点及数字高程模型，以EIGEN-6C4全球重力场模型作参考重力场，采用顾及地球曲率影响的各类地形质量位及引力的第二类Helmert凝集法严密算法，利用高分辨率地形数据恢复甚短波扰动重力场，确定空间分辨率2′×2′的高精度湖南省似大地水准面模型（HNGG2017）。经外部检核，模型整体精度均优于±0.022 m。与历史模型相比，新模型在湖南北部常德汉寿、西南部永州江永等地区精度得到显著改善。     

宣郁通经汤合少腹逐瘀汤加减治疗子宫内膜异位症痛经48例总结

目的：观察宣郁通经汤合少腹逐瘀汤加减治疗子宫内膜异位症痛经的临床疗效。方法：将96例子宫内膜异位症痛经患者随机分为2组，每组各48例。治疗组予宣郁通经汤合少腹逐瘀汤加减治疗，对照组予米非司酮治疗，疗程均为4个月。比较2组综合疗效及治疗前后痛经积分的变化情况。结果：总有效率治疗组为93.75%，对照组为75.00%，2组比较，差异有统计学意义（P<0.05）；2组痛经积分治疗前后组内比较及治疗后组间比较，差异均有统计学意义（P<0.01）。结论：宣郁通经汤合少腹逐瘀汤加减治疗子宫内膜异位症痛经较单用米非司酮治疗效果更好。     

顾及地类转换差异的城市空间扩展元胞自动机模型及应用研究

元胞自动机模型已经成为城市空间扩展模拟研究的重要方法之一,并得到广泛应用。然而,现有的城市扩展元胞自动机模型仍存在不足。由于元胞状态设置较为简单,从而使模型转换规则中对不同用地类型向城市用地转换的差异与强度考虑不够。基于此本文在元胞自动机模型的框架下,设计了多元结构的元胞状态及转换规则,提出了顾及地类转换差异与强度的城市扩展元胞自动机模型。在计算非城市用地向城市用地转换的转换概率时,该模型考虑了3个方面的概率：① 地形地貌、经济发展等城市发展的驱动因素对城市用地扩展的影响概率,该概率采用logistics方法进行计算;② 邻域元胞的用地类型对中心元胞转换概率的影响,该概率采用扩展摩尔型方法进行计算;③ 不同类型的非城市用地（本研究中包括耕地、林地和裸地3种类型）向城市用地转换的强度,该概率由模拟基期土地利用数据与目标年份土地利用数据的叠加,得出不同类型的非城市用地在此时间段内向城市用地转换的规模,进而确定不同类型的非城市用地向城市用地转换的强度。最后,将以上3种概率的乘积作为元胞转换的概率。通过转换概率与转换阈值的对比判断中心元胞是否在下一个阶段转换为城市用地。经过迭代计算,不断增加城市用地元胞的数量。当模拟城市用地的结果与目标年份的城市用地规模差值在一定的范围内时停止模拟,得出最终结果。模型构建完成后,本文以长株潭城市群核心区为例进行了模拟实验。以2001年该地区的土地利用数据为基期数据,模拟2010年该地区的城市用地规模和空间分布。研究结果表明,根据本文提出的模型模拟的城市扩展结果与真实数据相比具有较高的一致性。模拟结果正确率达到68.66%,比基于传统logistics回归的元胞自动机模型的模拟精度提高了4.25%,Kappa系数为0.675。该模型较好地模拟了长株潭城市群核心区城市扩展,在城市空间扩展模拟中具有较好的适应性与有效性。     

张掖盆地地下水硝酸盐污染与人体健康风险评价

地下水是张掖盆地的重要水资源，其硝酸盐污染尚未得到足够重视。对张掖盆地2004、2015年地下水硝酸盐浓度进行了系统分析，并采用美国环境保护署（USEPA）推荐的健康风险评价模型评估了地下水硝酸盐的健康风险。结果表明：自2004年以来张掖盆地地下水硝酸盐污染日趋严重。2015年硝酸盐浓度最高已达到283.32 mg·L^-1，17.61%的采样点硝酸盐氮浓度超过GB5749-2006《生活饮用水卫生标准》中饮用地下水限量值（20 mg·L^-1）。研究区人群经皮肤接触途径摄入硝酸盐的健康风险在可接受水平，而饮水摄入硝酸盐的健康风险较高，总风险中饮水途径引起健康风险的贡献率占99.40%，远大于皮肤接触途径。儿童经饮水摄入和皮肤接触两种途径的健康风险均显著高于成人，分别为成人的1.544倍和1.039倍。32.39%的采样点地下水硝酸盐对儿童的健康风险超出了可接受水平，14.79%的采样点地下水硝酸盐对成人的健康风险不可接受。甘州区城区、临泽县北部边缘及高台县城区周围硝酸盐浓度最高，这些区域内所有人群都面临硝酸盐引发的高健康风险，其余区域硝酸盐引发的健康风险相对较低。     

北京主城区伪基站时空规律分析

随着公众移动通信的快速发展,伪基站的泛滥不仅破坏正常电信秩序,危害公共安全,而且严重损害群众财产权益,侵犯公民个人隐私,已成为社会一大公害。如何从垃圾短信大数据中挖掘出伪基站活动的时空规律,寻找有效的防控方案,从源头上进行打击和治理成为管理部门和研究者共同关注的焦点。本文基于北京市垃圾短信数据,利用非负矩阵分解的方法分析伪基站的时空分布规律;并利用TF-IDF构建垃圾短信分类模型,对垃圾短信进行分类,结合土地利用数据,分析伪基站在发送不同类型垃圾短信时的时空分布规律。结果显示：北京市垃圾短信多分布于路网和中心城区;白天垃圾短信数量远远多于晚上;垃圾短信的分布随时间的推移沿着路网逐渐向内收缩;发送不同类型垃圾短信的伪基站的时空分布具有一定的差异;通过非负矩阵分解得到的结果,与垃圾短信分类后得到的结果有很好的匹配。研究表明,非负矩阵分解具有实现上的简便性、分解形式和分解结果上的可解释性等优点,可以有针对性的为有关部门建言打击伪基站的有效方案,对于伪基站违法行为的治理具有一定的意义。     

紫外-可见分光光度法测定多花黄精多糖含量

目的：测定湖南洪江国家黄精标准化基地多花黄精中的多糖含量，为多花黄精的进一步开发利用及药材质量标准研究奠定基础。方法：以葡萄糖为标准品，采用硫酸-蒽酮试剂显色，应用紫外-可见分光光度法测定多花黄精多糖含量。结果：葡萄糖在3.28～19.68μg/mL范围内线性良好（r=0.9992），多花黄精多糖平均含量为8.05%。结论：洪江种植基地的多花黄精品质优良，洪江是道地黄精药材种植理想基地。     

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.     

Enhanced a novel β-agarase production in recombinant Escherichia coli BL21(DE3) through induction mode optimization and glycerol feeding strategy

Agarases are hydrolytic enzymes that act on the hydrolysis of agar and have a broad range of applications in food,cosmetics and pharmaceutical industries. In this study, a glycerol feeding strategy based on induction mode optimization for high cell density and β-agarase production was established, which could effectively control acetate yield. First, exponential feeding strategy of glycerol with different overall specific growth rates(μ) was applied in the pre-induction phase. The results showed that the low μ(μ=0.2) was suggested to be the optimal for cell growth and β-agarase production. Second, the effects of induction temperature and the inducer concentration on cell growth and β-agarase production were investigated in the post-induction phase. When induced by isopropyl-β-d-thiogalactoside(IPTG), the strategy of 0.8 mmol/L IPTG induction at 20℃ was found to be optimal for β-agarase production. When cultivation was induced by continuous lactose feeding strategy of 1.0 g/(L·h), the β-agarase activity reached 112.5 U/mL, which represented the highest β-agarase production to date.Furthermore, the β-agarase was capable of degrading G. lemaneiformis powder directly to produce neoagarooligosaccharide, and the hydrolysates were neoagarotetraose(NA4) and neoagarohexaose(NA6). The overall research may be useful for the industrial production and application of β-agarase.     

利用超快速精密星历约束的北斗卫星实时精密定轨

以广播星历为起算轨道的北斗卫星实时滤波精密定轨往往需要较长收敛时间，针对此，提出利用超快速精密星历约束的实时精密定轨方法。通过MGEX跟踪网全球分布的51个测站连续7 d的实测数据，利用平方根信息滤波对北斗卫星实时精密轨道进行确定，并以3 d解事后轨道作为参考，评估北斗卫星实时滤波轨道精度。结果表明，利用广播星历作起算轨道时，北斗实时滤波轨道平均需要经过15 h收敛才能达到稳定，而新方法在这段时间内轨道变化较为平稳，未出现明显的收敛现象，并且7 d时间内GEO卫星在切向、法向和径向上RMS分别优于2.5 m、20 cm和30 cm，IGSO和MEO卫星在3个方向上分别优于30 cm、15 cm和10 cm。