碳水化合物的组合合成

碳水化合物的组合合成是一项新兴技术，该技术可以在短时间内合成大量用于进行生物活性筛选的寡糖及拟糖物。液相与固相合成技术可以极大地加快药物研究与开发进程。作者针对该技术在碳水化合物合成方面的研究进展情况进行讨论。     

Absolute spectrophotomery of comets 1973XII and 1975IX: II. Profiles of the Swan bands

Absolute spectrophotometric measurements of the Swan bands of two comets have been compared with computed synthetic spectra using modern Franck-Condon and Hönl-London factors, and varying rotational, vibrational, and electronic excitation temperatures. Rotational and vibrational temperatures were obtained for the comets. Although the electronic excitation temperature and the molecular column density cannot be separated, a relationship is found between these two quantities. A review is made of recent determinations of column densities for CN in comets.     

Multi‐year water balance assessment of a newly constructed wetland,Fort McMurray,Alberta

Oil sands mining in Alberta transforms the boreal landscape of forests and wetlands into open pits, tailings ponds and overburden piles. Whereas reclamation efforts have primarily focused on upland forests, rebuilding wetland systems has recently become a motivation for research. Wetland creation and sustainability in this region is complicated by the sub‐humid climate and salinity of underlying mining material. In 2012, Syncrude Canada Ltd. completed the construction of the Sandhill Fen Watershed (SFW), a 52‐ha upland‐wetland system to evaluate wetland reclamation strategies on soft tailings. SFW includes an active pumping system, upland hummocks, a fen wetland and underdrains. To evaluate the influence of management practices on the hydrology of the system, this study reports the water balance from January 2013 to December 2014, the first 2 years after commissioning. A semi‐distributed approach was taken to examine the fluxes and stores of water in uplands and lowlands. Natural and artificial inputs and outputs were measured using a series of precipitation gauges and pumps, and evapotranspiration was quantified using three eddy covariance towers. A series of near surface wells recorded water table position. Both 2013 and 2014 were normal rainfall years, with 2013 having more and 2014 less snow than normal. In 2013, inflow/outflow from pumping was the predominant hydrological fluxes, resulting in considerable variability in water table position and storage changes throughout the summer. In 2014, the artificial addition of water was negligible, yet the water table remained near the surface in lowland locations, suggesting that wetland conditions could be maintained under current conditions. Evapotranspiration rates between uplands and lowlands were similar between years and sites, ranging from 2.2 ± 1.8 to 2.5 ± 1.2 mm/day and were largely controlled by climate. These rates were less than nearby older upland systems, suggesting that water balance partitioning will change as vegetation develops. Comparison between years and with natural systems provides insight on how management practices influence hydrologic dynamics and the overall water balance of the SFW. Copyright © 2016 John Wiley & Sons, Ltd.     

A comparison of the main methods for estimating probabilities of extreme still water levels

Sea-level return periods are estimated at 18 sites around the English Channel using: (i) the annual maxima method; (ii) the r-largest method; (iii) the joint probability method; and (iv) the revised joint probability method. Tests are undertaken to determine how sensitive these four methods are to three factors which may significantly influence the results; (a) the treatment of the long-term trends in extreme sea level; (b) the relative magnitudes of the tidal and non-tidal components of sea level; and (c) the frequency, length and completeness of the available data. Results show that unless sea-level records with lengths of at least 50 years are used, the way in which the long-term trends is handled in the different methods can lead to significant differences in the estimated return levels. The direct methods (i.e. methods i and ii) underestimate the long (> 20 years) period return levels when the astronomical tidal variations of sea level (relative to a mean of zero) are about twice that of the non-tidal variations. The performance of each of the four methods is assessed using prediction errors (the difference between the return periods of the observed maximum level at each site and the corresponding data range). Finally, return periods, estimated using the four methods, are compared with estimates from the spatial revised joint probability method along the UK south coast and are found to be significantly larger at most sites along this coast, due to the comparatively short records originally used to calibrate the model in this area. The revised joint probability method is found to have the lowest prediction errors at most sites analysed and this method is recommended for application wherever possible. However, no method can compensate for poor data.     

Plate and intraplate processes of Hercynian Europe during the late paleozoic

It is speculated that until Late Carboniferous time the region of Hercynian Europe was occupied by an elongated island arc system underlain by a segment of continental crust. In the Upper Carboniferous, two subduction zones are assumed to have extended from the north and south beneath Hercynian Europe. An extensive zone of hot, partially molten upper mantle lay above and between these, and diapiric uprise of portions of this material led to separation of mafic magmas, widespread partial melting in the lower and middle crust, high temperature-low pressure metamorphism in crustal rocks, and regional uplift and extension of the crust, as indicated by intermontane troughs and their associated volcanic rocks.In Visean to Westphalian time Hercynian Europe collided with both the large neighbouring plates North America-Europe and Africa. During these diachronous collisions and owing to reduced rigidity of the relatively hot island arc crust, the irregular continental margins of the larger and thicker continental plates induced oroclinal bending of Hercynian Europe. After the collision processes had been terminated, processes of upper mantle activity continued, causing further crustal uplift and even, enhanced crustal extension for several tens of million years into the Lower Permian. Decline of the upper mantle activity beneath Hercynian Europe is indicated by crustal subsidence and formation of a peneplain in Permian time followed by the Upper Permian transgression of both the Zechstein sea and the Tethys sea which mark the end of the Hercynian geodynamic cycle.     

Electron beam analytical instruments and the determination of modes,spatial variations of minerals and textural features of rocks in polished section

Point counts based on X-ray intensities collected with an automated electron beam analytical instrument can be used to estimate the accurate modes required by modern physical-chemical modelling of rock-forming processes. In addition, the spatial distributions of mineral species and mineral compositions can be extracted from the coordinates of the point counting grid. Statistical tests of whether the mineral and porosity distributions are uniform can be performed by comparing the results from subareas of the polished section. The separate and composite contributions of the mineral phases to the texture and structure of the rock can be visually represented with mineral distribution maps. Qualitative differences in grain size can be recognized because the nonzero, finite electron beam diameter can detect grain boundaries. Spots on the minerals are identified by comparing the ranking of X-ray intensities with the ranking of intensities on a set of standards. For example, this method identified more than 88% of the spots on the surface of a polished section of an alkali olivine basalt. A small additional number of spots, approximately 1%, were identified because their spectra were dominated by the X-ray intensities of two characteristic elements. This method was particularly efficient in identifying phases with a small grain size and simple chemistry, e.g. apatite. The modal amounts of an alkali olivine basalt obtained with a microprobe are within approximately one standard deviation of the results obtained by point counting the same areas of the polished section under reflected and transmitted light if the minerals are major constituents and occur only in the groundmass. Accessory and phenocryst phases agree to within approximately three standard deviations.     

Long-term climate monitoring and extreme events

Problems with long-term monitoring of various extreme meteorological events (including tropical and extratropical cyclones, extreme winds, temperatures and precipitation, and mesoscale events) are examined. For many types of extreme events, the maintenance of long-term homogeneity of observations is more difficult than is the case for means of variables. In some cases, however, a strategy of using more than a single variable to define an event, along with the careful elimination of biases in the data, can provide quantitative information about trends. Special care needs to be taken with extreme events deduced from meteorological analyses, because changes in analysis and observation systems are certain to have affected extremes. Also, compositing of observations from more than one station, using differences in means (of temperature for instance) to produce a single long-term site, may not remove the biases in the extremes. These problems, along with ambiguities in defining extreme events, and difficulties in combining different analyses from different sites, complicate (and perhaps invalidate) attempts to determine whether extreme weather is becoming more frequent. The best that is likely to be achieved, even with increased emphasis on attaining the high-level of homogeneity necessary in the observations, is to monitor long-term variations in certain important extreme events, in select locations with high-quality data. Regional indices of important extreme events, selected on the basis of their damage potential and capable of adequate monitoring, may be established. If, in the future, we are to answer the question “Are extreme weather events becoming more frequent?”, we must establish and protect high-quality stations capable of monitoring the most important extreme events (perhaps with such regional indices), and ensure that changes affecting the recording of extreme events (e.g., changes in exposure) are meticulously documented.     

On the definition of the flux of sensible heat

The definition of the sensible heat flux is examined in the light of a paper published by Brook (1978). We show that the convergence of the flux defined in this paper and that of the standard definition are related to different quantities and that care must be taken to ensure that compatible definitions are used.     

Evolution of late pleistocene and holocene climates in the circum-south pacific land areas

Paleovegetation maps were reconstructed based on a network of pollen records from Australia, New Zealand, and southern South America for 18 000, 12000, 9000, 6000, and 3000 BP and interpreted in terms of paleoclimatic patterns. These patterns permitted us to speculate on past atmospheric circulation in the South Pacific and the underlying forcing missing line mechanisms. During full glacial times, with vastly extended Australasian land area and circum-Antarctic ice-shelves, arid and cold conditions characterized all circum-South Pacific land areas, except for a narrow band in southern South America (43° to 45°S) that might have been even wetter and moister than today. This implies that ridging at subtropical and mid-latitudes must have been greatly increased and that the storm tracks were located farther south than today. At 12000 BP when precipitation had increased in southern Australia, New Zealand, and the mid-latitudes of South America, ridging was probably still as strong as before but had shifted into the eastern Pacific, leading to weaker westerlies in the western Pacific and more southerly located westerlies in the eastern Pacific. At 9000 BP when, except for northernmost Australia, precipitation reached near modern levels, the south Pacific ridges and the westerlies must have weakened. Because of the continuing land connection between New Guinea and Australia, and reduced seasonality, the monsoon pattern had still not developed. By 6000 BP, moisture levels in Australia and New Zealand reached their maximum, indicating that the monsoon pattern had become established. Ridging in the South Pacific was probably weaker than today, and the seasonal shift of the westerlies was stronger than before. By 3000 BP essentially modern conditions had been achieved, characterized by patterns of high seasonal variability.Contribution to Clima Locarno — Past and Present Climate Dynamics; Conference September 1990, Swiss Academy of Sciences — National Climate Program