Laboratory Studies to Determine Suitable Chemicals to Improve Oil Recovery from Garzan Oil Field

Garzan oil field is located at the south east of Turkey. It is a mature oil field and the reservoir is fractured carbonate reservoir. After producing about 1% original oil in place (OOIP) reservoir pressure started to decline. Waterflooding was started in order to support reservoir pressure and also to enhance oil production in 1960. Waterflooding improved the oil recovery but after years of flooding water breakthrough at the production wells was observed. This increased the water/oil ratio at the production wells. In order to enhance oil recovery again different techniques were investigated. Chemical enhanced oil recovery (EOR) methods are gaining attention all over the world for oil recovery. Surfactant injection is an effective way for interfacial tension (IFT) reduction and wettability reversal. In this study, 31 different types of chemicals were studied to specify the effects on oil production. This paper presents solubility of surfactants in brine, IFT and contact angle measurements, imbibition tests, and lastly core flooding experiments. Most of the chemicals were incompatible with Garzan formation water, which has high divalent ion concentration. In this case, the usage of 2-propanol as co-surfactant yielded successful results for stability of the selected chemical solutions. The results of the wettability test indicated that both tested cationic and anionic surfactants altered the wettability of the carbonate rock from oil-wet to intermediate-wet. The maximum oil recovery by imbibition test was reached when core was exposed 1-ethly ionic liquid after imbibition in formation water. Also, after core flooding test, it is concluded that considerable amount of oil can be recovered from Garzan reservoir by waterflooding alone if adverse effects of natural fractures could be eliminated.     

磨料有序排布电镀砂轮的制备及其把持力研究

为解决电镀砂轮磨削加工中容屑空间不足的问题，采用点胶微粘接的方法制备了磨料有序排布的电镀砂轮，分析了磨料粘接效果和镀层力学性能。通过SEM分析了磨料/镀层/导电胶的结合界面，并进行了干磨削试验。研究结果表明，直径约为磨料粒径40%的胶点可粘接住磨料，单个胶点上粘接多颗磨料的占比小于6%；双脉冲电镀工艺制备的镀层显微硬度大于500HV，表层残余应力小于100MPa，磨料/镀层/导电胶之间的界面贴合紧密，无明显缺陷；砂轮在磨削时没有出现磨料脱落现象。     

Estimating long-term time-resolved indoor PM2.5 of outdoor and indoor origin using easily obtainable inputs

To evaluate the separate impacts on human health and establish effective control strategies, it is crucial to estimate the contribution of outdoor infiltration and indoor emission to indoor PM_2.5 in buildings. This study used an algorithm to automatically estimate the long-term time-resolved indoor PM_2.5 of outdoor and indoor origin in real apartments with natural ventilation. The inputs for the algorithm were only the time-resolved indoor/outdoor PM_2.5 concentrations and occupants’ window actions, which were easily obtained from the low-cost sensors. This study first applied the algorithm in an apartment in Tianjin, China. The indoor/outdoor contribution to the gross indoor exposure and time-resolved infiltration factor were automatically estimated using the algorithm. The influence of outdoor PM_2.5 data source and algorithm parameters on the estimated results was analyzed. The algorithm was then applied in four other apartments located in Chongqing, Shenyang, Xi'an, and Urumqi to further demonstrate its feasibility. The results provided indirect evidence, such as the plausible explanations for seasonal and spatial variation, to partially support the success of the algorithm used in real apartments. Through the analysis, this study also identified several further development directions to facilitate the practical applications of the algorithm, such as robust long-term outdoor PM_2.5 monitoring using low-cost light-scattering sensors.     

磁悬浮控制力矩陀螺高速转子的高精度位置控制

在受到陀螺效应、动框架效应等影响后产生的磁力非线性问题是磁悬浮控制力矩陀螺(MSCMG)高速转子位置精度下降的主要因素。为解决以上问题,提高转子位置精度,本文分析了转子所受磁力的特性,建立了转子系统非线性动力学模型,提出了神经网络滑模控制方法。设计滑模控制律,采用径向基函数神经网络逼近控制律中的非线性模型,自适应算法根据误差在线调整神经网络的权值,同时可以保证整个系统的稳定性。仿真和实验结果表明,所提出方法的转子位置精度达到99%,稳态误差为0.000 2 mm。神经网络滑模控制可以实现MSCMG转子系统的高精度位置控制。     

漆包机烘炉加热失效原因探究及处理

针对漆包机烘炉加热失效形式及产生原因,进行了深入的研究和分析。结果表明,影响烘炉加热失效的主要原因是加热管损坏及装配异常、催化剂表面粘有金属化合物等颗粒杂质、排废风机转速设定不合理,并对加热管、催化剂、排废风机提出了合理实用的技术措施,为降低烘炉加热失效提高加热效果提供帮助。     

300M超高强钢在中性盐雾环境中的腐蚀行为及机制

摘要：为了研究300M超高强钢在中性盐雾环境中的腐蚀行为及腐蚀机制，采用失重法，宏观、微观腐蚀形貌分析，三维表面轮廓分析及电化学分析的研究方法，来表征腐蚀实验现象并进行分析。结果表明：300M超高强钢在中性盐雾环境中的腐蚀产物为FeOOH、Fe2O3、Fe(OH)3和Fe3O4；腐蚀速率随着腐蚀时间逐渐降低，腐蚀后期（72h）腐蚀速率降低50%；腐蚀初期以点蚀为主，点蚀坑通过横向扩展，逐渐发展为后期的均匀腐蚀，腐蚀表面形貌呈沟壑状；外腐蚀层对基体的保护能力很弱，Cr元素在锈层靠近基体的一侧偏聚使内腐蚀层具有一定的抗腐蚀性。     

废菌渣活性炭的制备及对废水中硝基苯的吸附

以废菌渣为原料制备活性炭，采用能量-色散光谱（EDS）和傅里叶变换红外光谱仪（FTIR）进行表征，结果表明：活性炭表面具有多种官能团，有利于提高对硝基苯的吸附。并研究了活性炭吸附硝基苯的影响因素（pH、初始浓度、吸附时间、投加量）、吸附等温线及热力学。结果表明：在常温中性pH条件下，初始浓度为50mg/L，活性炭用量为0.15g时硝基苯去除率可达98%，出水水质满足《污水综合排放标准》（GB 8978－1996）中对硝基苯浓度低于2.0mg/L的要求。活性炭对硝基苯的吸附具有较快的吸附速率，即1min接近平衡。该吸附行为是自发放热反应，可以用Freundlich模型很好地拟合。废菌渣活性炭对硝基苯的吸附主要是疏水作用和氧化钼活化共同作用的结果。因此，以农业废弃物-废菌渣制备得到的废菌渣活性炭具有良好的经济实用性，可用于废水处理中，实现以废治废的目的。