For complex reactions, the choice of reactor type is important for attaining optimum product yields. Strategies for specifying reactor types have beenIn this paper, product yield in a Van de Vusse reaction scheme has been studied for a wide range of the rate constants, in a reactor system consisting 相似文献
In this paper, an all-optical miniaturized binary to gray code converter is designed and analyzed. The all-optical domain is now an alternative for electronic devices, where performance and speed are the key issues. Code converters are significantly used in digital data transmission in the areas of error detection and correction. Gray code is one of the cyclic codes, where the cyclic shift of each codeword is also a code word. An all-optical XOR gate, realized using a Y-shaped power combiner is used in this design to generate the desired gray code from the given binary code. The insertion loss and extinction ratio parameters are found to be 0.347 dB and 22.26 dB, respectively. The entire simulation is carried out using finite-difference time-domain method. The obtained practical results are verified mathematically using MATLAB.
Microsystem Technologies - This paper presents the design a capacitive shunt type RF-MEMS switch with high isolation, high switching speed and low actuation voltage for Ka-band applications. The... 相似文献
AC-impedance spectroscopic studies in the temperature range of 30–400 °C are carried out on solid solutions of lead magnesium niobate (PMN) with lead titanate (PT) and lead zirconate (PZ), both of them in the 65/35 atomic ratio. For PMN–PT this corresponds to the morphotropic phase boundary composition (with normal ferroelectric behaviour), and for PMN–PZ it is near the phase boundary between normal ferroelectric and relaxor ferroelectric compositions. The variation of dielectric permittivity with temperature at different frequencies shows normal ferroelectric and relaxor-like dependence for PMN–PT and PMN–PZ, respectively. Temperature-dependent spectroscopic modulus plots reveal a much broader peak for PMN–PZ compared to that for PMN–PT, which is consistent with the dielectric behaviour. PMN–PT shows nearly ideal Debye behaviour below Tm (the temperature of the permittivity maximum) and the behaviour departs from ideality above Tm, whereas non-ideal Debye behaviour is seen both below and above Tm for PMN–PZ. Complex modulus plots fit well with two depressed semicircles and three depressed semicircles, respectively, for PMN–PT and PMN–PZ. The relaxation observed in the spectroscopic plots around 1 MHz for PMN–PT has been assigned to polarisation relaxation expected for normal-sized domains. No such relaxation could be observed for PMN–PZ around 1 MHz because of the mesoscopic domain sizes. 相似文献
The severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) is responsible for the current COVID-19 pandemic. In SARS-CoV-2, the channel-forming envelope (E) protein is almost identical to the E protein in SARS-CoV, and both share an identical α-helical channel-forming domain. Structures for the latter are available in both detergent and lipid membranes. However, models of the extramembrane domains have only been obtained from solution NMR in detergents, and show no β-strands, in contrast to secondary-structure predictions. Herein, we have studied the conformation of purified SARS-CoV-2 E protein in lipid bilayers that mimic the composition of ER–Golgi intermediate compartment (ERGIC) membranes. The full-length E protein at high protein-to-lipid ratios produced a clear shoulder at 1635 cm−1, consistent with the β-structure, but this was absent when the E protein was diluted, which instead showed a band at around 1688 cm−1, usually assigned to β-turns. The results were similar with a mixture of POPC:POPG (2-oleoyl-1-palmitoyl-sn-glycero-3-phosphocholine/3-glycerol) and also when using an E-truncated form (residues 8–65). However, the latter only showed β-structure formation at the highest concentration tested, while having a weaker oligomerization tendency in detergents than in full-length E protein. Therefore, we conclude that E monomer–monomer interaction triggers formation of the β-structure from an undefined structure (possibly β-turns) in at least about 15 residues located at the C-terminal extramembrane domain. Due to its proximity to the channel, this β-structure domain could modulate channel activity or modify membrane structure at the time of virion formation inside the cell. 相似文献
The Integrated Computer Aided Manufacturing (ICAM) program of the U.S. Air Force identified a need to better communicate and analyze manufacturing for the people involved in improving productivity. To satisfy that need, the ICAM program developed the IDEF (ICAM Definition) method to address particular characteristics of manufacturing. This IDEF method is equally applicable in analyzing other types of organizations. IDEF comprises three modeling methodologies: function model methodology (IDEF0), information model methodology (IDEF1) and dynamics model methodology (IDEF2). This paper reports on the Information model methodology only. This methodology is used to construct an information model that helps in understanding the structure of information needed to support the functions of an organization. 相似文献
Bismuth-based nanostructures (BBNs) have attracted extensive research attention due to their tremendous development in the fields of photocatalysis and electro-catalysis. BBNs are considered potential photocatalysts because of their easily tuned electronic properties by changing their chemical composition, surface morphology, crystal structure, and band energies. However, their photocatalytic performance is not satisfactory yet, which limits their use in practical applications. To date, the charge carrier behavior of surface-engineered bismuth-based nanostructured photocatalysts has been under study to harness abundant solar energy for pollutant degradation and water splitting. Therefore, in this review, photocatalytic concepts and surface engineering for improving charge transport and the separation of available photocatalysts are first introduced. Afterward, the different strategies mainly implemented for the improvement of the photocatalytic activity are considered, including different synthetic approaches, the engineering of nanostructures, the influence of phase structure, and the active species produced from heterojunctions. Photocatalytic enhancement via the surface plasmon resonance effect is also examined and the photocatalytic performance of the bismuth-based photocatalytic mechanism is elucidated and discussed in detail, considering the different semiconductor junctions. Based on recent reports, current challenges and future directions for designing and developing bismuth-based nanostructured photocatalysts for enhanced photoactivity and stability are summarized. 相似文献
In this article, we report on the application of our spherical nanoindentation data analysis protocols to study the mechanical
response of grain boundary regions in as-cast and 30% deformed polycrystalline Fe–3%Si steel. In particular, we demonstrate
that it is possible to investigate the role of grain boundaries in the mechanical deformation of polycrystalline samples by
systematically studying the changes in the indentation stress–strain curves as a function of the distance from the grain boundary.
Such datasets, when combined with the local crystal lattice orientation information obtained using orientation imaging microscopy,
open new avenues for characterizing the mechanical behavior of grain boundaries based on their misorientation angle, dislocation
density content near the boundary, and their propensity for dislocation source/sink behavior. 相似文献
Transient flow during nominally steady conditions is responsible for many intermittent defects during the continuous casting of steel. The double-ruler electromagnetic field configuration, or “FC-Mold EMBr,” is popular in commercial slab casting as it provides independent control of the applied static field near the jet and free surface regions of the mold. In the current study, transient flow in a typical commercial caster is simulated in the absence and in the presence of a double-ruler magnetic field, with rulers of equal strengths. Large eddy simulations with the in-house code CU-FLOW resolve the important transient behavior, using grids of over five million cells with a fast parallel solver. In the absence of a magnetic field, a double-roll pattern is observed, with transient unbalanced behavior, high surface velocities (~0.5 m/s), surface vortex formation, and very large surface-level fluctuations (~±12 mm). Applying the magnetic field suppresses the unbalanced behavior, producing a more complex mold flow pattern, but with much lower surface velocities (~0.1 m/s), and a flat surface level with small level fluctuations (<±1 mm). Nail board measurements taken at this commercial caster, in the absence of the field, matched reasonably well with the calculated results, both quantitatively and qualitatively. 相似文献
Hydrogen storage in titanium dioxide (TiO2) functionalized (10, 10) armchair single walled carbon nanotube (SWCNT) is investigated through first principle calculations using density functional theory (DFT). This first principles study uses Vienna Ab-initio Simulation Package (VASP) with ultrasoft pseudopotentials and local density approximation (LDA). The necessary benchmark and other systematic calculations were carried out to project the hydrogen storage capability of the designed system. Interestingly, the TiO2 molecules functionalized on the outer surface of SWCNT do not undergo any dimerization/clustering thus giving excellent stability and usable gravimetric hydrogen storage capacity of 5.7 wt.% and the value nearly fulfills the US DOE target (i.e. 6 wt.%). The band structure and density of states (DOS) plots suggest that the functionalization can lead a way to transform the nature (metallic → semiconducting) of the pristine SWCNT. The nominal values of H2 storage capacity and binding energies give much hope for using CNT functionalized with TiO2 as a practical and reversible hydrogen storage medium (HSM). 相似文献