Influence of ultrasonication energy on the dispersion consistency of Al2O3–glycerol nanofluid based on viscosity data,and model development for the required ultrasonication energy density

Achieving homogenised and stable suspensions has been one of the important research topics in nanofluid investigations. Preparing nanofluids, especially from the two-step method, is often accompanied with varying degrees of agglomerations depending on some parameters. These parameters include the physical structure of the nanoparticle, the prevalent particle charge, the strength of van der Waals forces of attraction and repulsiveness strength. Amongst the methods of deagglomeration, the use of ultrasonic vibration is most popular for achieving uniform dispersion. However, there are very few works related to its effect on the thermo-physical properties of nanofluids, and above all, standardising the minimum required ultrasonication time/energy for nanofluids synthesis. In this work, the optimum energy required for uniform and initially stable nanofluid has been investigated through experimental study on the combined influence of ultrasonication time/energy, nanoparticle size, volume fraction and temperature on the viscosity of alumina–glycerol nanofluids. Three different sizes of alumina nanoparticles were synthesised with glycerol using ultrasonication-assisted two-step approach. The viscosities of the nanofluid samples were measured between temperatures of 20–70?°C for volume fractions up to 5%. Based on the present experimental results, the viscosity characteristics of the nanofluid samples were dependent on particle size, volume fraction and working temperature. Using viscometry, the optimum energy density required for preparing homogenous nanofluid was obtained for all particle sizes and volume fractions. Finally, an energy density model was derived using dimensionless analysis based on the consideration of nanoparticle binding/interaction energy in base fluid, particle size, volume fraction, temperature and other base fluid properties. The model's empirical constants were obtained using nonlinear regression based on the present experimental data.     

Tri-metallic quantum dot under the influence of solvent additive for improved performance of polymer solar cells

CdTeSe colloidal quantum dot (QD) was used to enhance photon capture in thin film polymer solar cells (TFPSC). The QDs were synthesized in aqueous media from two different precursors. Bulk heterojunction (BHJ) polymer blends composed of P3HT and PCBM were used as an absorber layer of the solar cell to investigate the effect of QDs. Different concentrations of QDs were used in the polymer matrix, which significantly impacted the power conversion efficiency (PCE) of the doped devices. More device performance growth was recorded by employing a small amount of solvent additives to disperse the QDs and increase the polymer's crystallinity in the medium. Hence, the addition of 1, Chloronaphthalene (CN) solvent additive in the QD-doped bulk heterojunction film further enhanced the overall performance of the TFPSC due to improved film morphology that has significantly influenced the charge transport processes. Consequently, the PCE of the solar cell increased by nearly 50% compared to the pristine TFPSC due to the effect of solvent additives.     

Interfacial energy for solutions of nanoparticles,surfactants, and electrolytes

The addition of surfactants to modify the surface property of nanoparticles (NPs) from hydrophilic to hydrophobic also enhances their interfacial properties. Several approaches were previously proposed to calculate the surface tension/interfacial tension (IFT) for different systems in the presence of NPs, surfactants, and electrolytes. However, most of these approaches are indirect and require several measured parameters. Therefore, a mathematical model is developed here to calculate the surface tension/IFT for these systems. The developed model takes into account the cohesive energy due to the interaction of the surfactant CH₂ groups, the electric double layer effect due to the interaction among the ions of NPs, surfactants, and electrolytes, and the dipole–dipole interaction of NPs and electrolytes. The developed model is compared and validated with the laboratory experimental data in literature. The results reveal further understanding of the mechanisms involved in stabilization of oil/water emulsion in the presence of NPs, surfactants, and electrolytes.     

Experimental investigations into viscosity,pH and electrical conductivity of nanofluid prepared from palm kernel fibre and a mixture of water and ethylene glycol

Extensive research has been carried out on the synthesis and applications of nanofluid produced from metals, nonmetals and their oxides. However, little or no attention has been paid to bio-based nanoparticles. The need for the use of bio-based nanoparticles and bio-based nanofluids is imperative to mitigate over-dependence on toxic synthetic nanoparticles. This idea is also in line with renewable and sustainable developmental goals. Moreover, bio-based materials like palm kernel fibre (PKF) constitute environmental waste in some quarters and its conversion to useful products for engineering application will take a long time in solving environmental issues and health hazards. In this study, the top-down approach was used to synthesize nanoparticles from PKF using a ball-milling machine. The PKF nanoparticles with an average size of \(\sim \)40 nm were dispersed in an ethylene glycol (EG)/water (50:50) base fluid up to 0.5% of the volume fraction. The viscosity, pH and electrical conductivity of PKF–water and EG (50:50) were studied for temperature ranging from 10 to 60\(^{\circ }\)C. The results showed that the viscosity of the PKF-based nanofluid increases with an increase in volume fraction and decreases exponentially with an increase in the working temperature of the nanofluid. The pH and the electrical conductivity increased as the volume fraction of the PKF nanoparticle was increased from 0.1 to 0.5%. However, the pH decreased with an increase in the temperature while the electrical conductivity increased with an increase in the volume fraction. Since the notable theoretical models in the literature were unable to estimate the viscosity of the PKF–EG/water nanofluid, in the present case an empirical correlation based on dimensional analysis was proposed to estimate the viscosity of the PKF–EG/water nanofluids.     

The Viscosity of Nanofluids: A Review of the Theoretical,Empirical, and Numerical Models

The enhanced thermal characteristics of nanofluids have made it one of the most raplidly growing research areas in the last decade. Numerous researches have shown the merits of nanofluids in heat transfer equipment. However, one of the problems is the increase in viscosity due to the suspension of nanoparticles. This viscosity increase is not desirable in the industry, especially when it involves flow, such as in heat exchanger or microchannel applications where lowering pressure drop and pumping power are of significance. In this regard, a critical review of the theoretical, empirical, and numerical models for effective viscosity of nanofluids is presented. Furthermore, different parameters affecting the viscosity of nanofluids such as nanoparticle volume fraction, size, shape, temperature, pH, and shearing rate are reviewed. Other properties such as nanofluid stability and magnetorheological characteristics of some nanofluids are also reviewed. The important parameters influencing viscosity of nanofluids are temperature, nanoparticle volume fraction, size, shape, pH, and shearing rate. Regarding the composite of nanofluids, which can consist of different fluid bases and different nanoparticles, different accurate correlations for different nanofluids need to be developed. Finally, there is a lack of investigation into the stability of different nanofluids when the viscosity is the target point.     

Thermohydraulic and entropy characteristics of Al2O3-water nanofluid in a ribbed interrupted microchannel heat exchanger

In this study, an interrupted microchannel heat sink with rib turbulators was studied for its thermohydraulic effectiveness and entropy generation in a compact space. The rib edges are modified to enhance the overall functioning of the system by reducing the pressure drop. The working fluid used was Al₂O₃-water nanofluid, and increasing the Reynolds number and nanoparticle concentration triggered a reduction in the heat sink's maximum temperature. These also offer a decrease in resistance to heat transfer, and there is an improvement in the evenness of the temperature of the interrupted microchannel heat sink, as regions with the likelihood of hot spot reduced drastically. At Re = 100, increasing the nanoparticle concentration from 0% to 4% enhanced the heat transfer coefficient by 38.41% for the interrupted microchannel heat sink-base (IMCH-B) configuration. Under similar conditions, the convective heat transfer coefficient for the interrupted microchannel heat sink-fillet (IMCH-F) increased by 43.69%. Furthermore, at 0.5% concentration, changing the Reynolds number from 100 to 700 augmented the heat transfer coefficient by 70.65%. Thus, the maximum temperature of the substrate's bottom surface was reduced by 53.83°C when the system was operated at Re = 700 and nanoparticle concentration of 4%. The IMCH-C also showed relatively close results at all observed volume fractions. For the IMCH-C, the maximum temperature of the bottom surface was reduced by 41.98°C at Re = 700 when compared with Re = 100% and 4% concentration. Although at high Reynolds numbers and concentrations, the pressure drops are higher, the performance enhancement criteria prove that the nanofluid is superior to water and the edge modifications show significant performance improvement. More importantly, the IMCH-F heat sink showed the optimum performance based on the performance evaluation criteria at Re = 300 and $\phi =2\%$ (ie, at this point, the heat transfer coefficient is maximum and the pressure drop is minimum). On the other hand, the optimal thermodynamic performance was observed at Re = 700 and $\phi =4\%$. The numerical results demonstrated a potential way to exploit nano-suspensions for thermal applications, especially for high-energy flux systems with compact space constraints.     

GEOCHEMICAL CHARACTERISTICS OF CRUDE OILS FROM THE SHARARA-C OIL FIELD,MURZUQ BASIN,SOUTHWESTERN LIBYA

Crude oil samples from the Sharara-C oil field (Concession NC-115, Murzuq Basin, SW Libya) were analysed by organic geochemical methods in order to infer the geochemical characteristics of their respective source rocks. Aromatic hydrocarbons were analysed by gas chromatography – mass spectrometry (GC-MS), and gas chromatography – tandem mass spectrometry (GC-MS-MS) was used to analyse saturated biomarkers. The Sharara-C oils are interpreted to have been generated by marine shales containing mixed terrigenous and marine organic materials deposited in an intermediate (suboxic) environment. Age-specific biomarker ratios indicated that the oils are older than Cretaceous, and maturation-related parameters pointed to their high thermal maturity. Consistent with previous studies, source rocks are inferred to be “hot” shales in the Lower Silurian Tanezzuft Formation. Almost all the parameter ratios calculated varied over a very narrow range, indicating that the investigated oils were compositionally similar. The only significant difference that was noted concerned the sterane/hopane ratios whose variation suggested that there was some variability in the composition of the source organic material. The organic geochemical parameters determined for the Sharara-C crude oils were compared with published data on other crude oils from Concession NC-115. Almost all the parameters agreed well with previously published data on oils from this part of the Murzuq Basin. The greatest deviation concerned the values of some of the maturity parameters. This tended to confirm the conclusions of previous studies concerning the presence of a number of distinct oil families and sub-families in the Sharara oil field area which are genetically related but which have different maturities.     

Mutual effect of extrinsic defects and electronic carbon traps of M-TiO2 (M = V,Co, Ni) nanorod arrays on photoexcited charge extraction of CdS for superior photoelectrochemical activity of hydrogen production

Understanding the photoexcited charge carrier dynamics such as separation, transportation and extraction in smart hybrid nanocomposites is the key to high performance solar cells. Nanocomposites possess advantage of broader solar absorption with their fast photoexcited charge separation and transportation but their use as photocorrosion-stable material is yet to be explored. Also, bulk and surface defects in individual components of the nanocomposites boost the efficiency of the solar cells, despite of the fact the recombination of the photoexcited charges at the interfaces lead to a substantial loss of charges and realizing a big challenge. Herein, the extrinsic defects like bulk and surface defects are induced by transition metal (M = V, Co, Ni) doping of M ? TiO₂ nanorod arrays. Consequently, the hydrothermal synthesis method offers the tuning of the carbon trapping states depending upon the type of the metal doped in M ? TiO₂ that decelerates the charge carrier dynamics in the M-TiO₂/CdS (M = V, Co, Ni) nanocomposites with the increase in the amount of carbon. Excellent charge extraction is observed in VTiO₂ (4% carbon) from its CdS sensitizer with photocurrent density of 2.06 mA/cm² than NiTiO₂ (14.6% carbon), TiO₂ (18.94% carbon) and CoTiO₂ (39.2% carbon) with photocurrent densities of 1.83, 1.46 and 1.34 mA/cm² at 0 V versus Ag/AgCl under 100 mW/cm² light intensity, respectively. This shows primary dependence of photoexcited charge dynamics upon the density of the carbon trapping states to be least while secondary dependence upon the density of the extrinsic defects in M ? TiO₂ to be maximum. This work creates a paradigm for future studies to have a broader insight of the photocatalyst's overall functioning to boost the efficiencies in solar cells by controlling the amount of electronic carbon traps during the synthesis of a large class of inorganic semiconductor photocatalysts.     

Radiation interaction parameters of commercial building glasses at energies of interest for potential nuclear accidents

Elemental composition, mass attenuation coefficients (MACs), effective atomic numbers (EANs), and effective electron densities (EEDs) give information about the nuclear applications of materials (dosimetry, shielding, etc.). In this work, MAC of some commercial building glasses were determined using the WinXCom computer program and GATE Monte Carlo code; additionally,EAN and EED of these glasses were also determined using related formulas, after the elemental compositions of the samples were determined by energy dispersive X-ray spectroscopy (EDS) technique. These properties were determined at 59.5 keV (Am-241), 380 keV (Ir-192), 662 keV (Cs-237), 1173 keV (Co-60), and 1332 keV (Co-60). These energies are of interest for any potential nuclear accident. The elemental compositions show the presence of C, O, Na, Mg, Si, and Ca in various percentages; MAC values ranged from about 0.05 to 0.225 cm²/g; EAN also ranged from about 9 to 11and EED is almost constant at all energies considered except at 59.5 keV where higher values were shown. The radiation interaction properties of the investigated glasses showed that they could be used as a dosimeters during emergency radiation exposure situations.