Precise Measurement of Isotope Ratios with a Double-Focusing Magnetic Sector ICP Mass Spectrometer

The potential of a commercially available double-focusing magnetic sector ICP mass spectrometer (Element, Finnigan MAT, Bremen, Germany) for precise isotope ratio measurement at the low-resolution setting (R = 300) was evaluated. Optimization of scanning conditions led to a relative standard deviation for a set of 10 consecutive 2 min measurements of ～0.1% ((206)Pb(+)/(207)Pb(+)) at signal intensities of ～200?000 counts/s (peak height). This compares favorably with the best values ever reported for quadrupole ICPMS and barely exceeds the theoretical value (counting statistics). Increasing the signal intensity to values ≥500?000 counts/s (peak height) resulted in a further reduction of the RSDs obtained (for both (25)Mg(+)/(26)Mg(+) and (206)Pb(+)/(207)Pb(+)) to typically 0.04%. These figures are remarkably better than those reported for commercially available quadrupole ICPMS systems. This improvement significantly reduces the difference between isotope ratio precision of ICPMS on one hand and those of thermal ionization mass spectrometry and plasma source multiple collector mass spectrometry on the other.     

A survey on question answering technology from an information retrieval perspective

This article provides a comprehensive and comparative overview of question answering technology. It presents the question answering task from an information retrieval perspective and emphasises the importance of retrieval models, i.e., representations of queries and information documents, and retrieval functions which are used for estimating the relevance between a query and an answer candidate. The survey suggests a general question answering architecture that steadily increases the complexity of the representation level of questions and information objects. On the one hand, natural language queries are reduced to keyword-based searches, on the other hand, knowledge bases are queried with structured or logical queries obtained from the natural language questions, and answers are obtained through reasoning. We discuss different levels of processing yielding bag-of-words-based and more complex representations integrating part-of-speech tags, classification of the expected answer type, semantic roles, discourse analysis, translation into a SQL-like language and logical representations.     

Highly discriminative statistical features for email classification

This paper reports on email classification and filtering, more specifically on spam versus ham and phishing versus spam classification, based on content features. We test the validity of several novel statistical feature extraction methods. The methods rely on dimensionality reduction in order to retain the most informative and discriminative features. We successfully test our methods under two schemas. The first one is a classic classification scenario using a 10-fold cross-validation technique for several corpora, including four ground truth standard corpora: Ling-Spam, SpamAssassin, PU1, and a subset of the TREC 2007 spam corpus, and one proprietary corpus. In the second schema, we test the anticipatory properties of our extracted features and classification models with two proprietary datasets, formed by phishing and spam emails sorted by date, and with the public TREC 2007 spam corpus. The contributions of our work are an exhaustive comparison of several feature selection and extraction methods in the frame of email classification on different benchmarking corpora, and the evidence that especially the technique of biased discriminant analysis offers better discriminative features for the classification, gives stable classification results notwithstanding the amount of features chosen, and robustly retains their discriminative value over time and data setups. These findings are especially useful in a commercial setting, where short profile rules are built based on a limited number of features for filtering emails.     

New method for threshold voltage extraction of high-voltage MOSFETs based on gate-to-drain capacitance measurement

This letter reports on the extraction of the threshold voltage of laterally diffused MOS transistors. A clear analysis of the device physics is performed, highlighting the correlation between the change of the electron charge distribution along the channel and the device capacitance variations when the gate voltage is swept. Using numerical simulations, it is shown that the peak of the gate-to-drain capacitance is related to the transition of the surface from weak to moderate inversion in the intrinsic MOS transistor at the location of the maximum doping concentration, which corresponds to the threshold voltage of the device according to the MOS theory. Comparison between conventional I/sub D///spl radic/g/sub m/ extraction and the new proposed capacitance peak method is performed on both technology computer-aided design simulations and measurements in order to confirm the new experimental technique and related theory.     

Determination of platinum and rhodium in environmental matrixes by solid sampling-electrothermal vaporization-inductively coupled plasma mass spectrometry

Electrothermal vaporization from a graphite furnace was used in combination with inductively coupled plasma mass spectrometry (ICPMS) for the determination of Pt and Rh in environmental matrixes. Solid samples of tunnel dust, grass, and atmospheric aerosol collected on a cellulose filter could be analyzed directly, such that sample dissolution-which is not self-evident for the determination of platinum group metals-could be avoided. By heating the graphite furnace according to a multistep temperature program, spectral interferences were avoided, since a "dry" plasma was obtained, while "parent" ions such as Cu, Zn, and Pb, giving origin to interfering molecular ions, were vaporized during the thermal pretreatment step. For tunnel dust, the most demanding sample matrix, a mixture of HCl and HF was used as a modifier to stimulate the vaporization of matrix components during the thermal pretreatment step and, hence, to alleviate matrix-induced analyte signal suppression during the actual vaporization step. Calibration was accomplished by means of single standard addition with an aqueous standard solution. The results obtained agreed within the experimental uncertainty with the corresponding reference values (certified values or results obtained using pneumatic nebulization ICPMS), while relative standard deviations of < or = 15% were typical for both Pt and Rh. In all samples, a Pt/Rh ratio of approximately 6-8 was established. For a typical sample mass of 2 mg, limits of detection were 0.35 ng/g for Pt and 0.05 ng/g for Rh.     

Use of transportable test stations for measuring satellite coverage dependent parameters during IOT campaigns

The in-orbit tests of the satellite coverage dependent parameters require the rotation of the satellite around its pitch and roll axes in order to ‘bring’ the various coverage locations onto one fixed IOT station. Alternatively, several transportable test stations can be located at different sites in the coverage area in order to measure the satellite performances on site. Although the second technique does not provide enough measurement points to reconstruct the complete coverage of shaped beam antennas, it presents several advantages for which it is still used by EUTELSAT for the IOTs of its satellites in conjunction with measurements based on the satellite attitude movements. In particular, the transportable test stations are used to test the stability of satellite EIRP and IPFD at the edges of the coverage areas, where the performances are more sensitive to the pointing errors induced by thermal deformation or satellite attitude changes. This paper presents the common experience gained by EUTELSAT and ESA in testing the coverage dependent parameters of the first and second generation of EUTELSAT satellites. In particular, the paper deals with the use of the transportable test stations during the EUTELSAT II F1 to F3 acceptance tests and with the test campaigns performed at several sites in the eastern European countries. In the first case, the transportable test stations were used in conjunction with satellite rotations around the pitch axis in order to measure the coverage dependent parameters along several cuts parallel to the equatorial plane at different roll angles. In the second case, the transportable test stations were used to periodically repeat the EIRP measurements of many satellite channels over several hours in order to test the EIRP stability of the EUTELSAT II satellites. For both cases, the paper presents a synthesis of the most significant IOT results together with a comparison between these results and the values of the coverage dependent parameters predicted on the basis of the on-ground tests.     

Identification of inorganic pigments used in porcelain cards based on fusing Raman and X-ray fluorescence (XRF) data

Raman spectroscopy and X-ray fluorescence (XRF) spectroscopy are often used as complementary techniques that are well suited for the analysis of art objects because both techniques are fast, sensitive, and noninvasive and measurements can take place in situ. In most of these studies, both techniques are used separately, in the sense that the spectra are evaluated independently and single conclusions are obtained, considering both results. This paper presents a data fusion procedure for Raman and XRF data for the characterization of pigments used in porcelain cards. For the classification of the analyzed points of the porcelain cards principal component analysis (PCA) was used. A first attempt was made to develop a new procedure for the identification of the pigments using a database containing the fused Raman-XRF data of 24 reference pigments. The results show that the classification based on the fused Raman-XRF data is significantly better than the classifications based on the Raman data or the XRF data separately.     

Ultrafast floating 75-V lateral IGBT with a buried hole diverter and an effective junction isolation

A low-voltage lateral insulated gate bipolar transistor (IGBT) is proposed for junction-isolated smart power technologies. An effective suppression of the substrate current is obtained through the use of a double buried layer structure. This structure, with the buried layer of p-type (BLP) on top of the buried layer of n-type, also ensures fast switching and a wide safe operating area as the BLP serves as a buried hole diverter in the on state and during turnoff. The floating capability of the device is also provided by the double buried layer. This lateral IGBT (LIGBT) is made in a standard smart power technology without adding extra masks. Due to the low power losses in the on state and during switching, this n-type LIGBT is competitive with n-type DMOS devices.     

A Multi-Disciplinary Contribution to the Provenance Determination of Ancient Greek and Roman Marble Artifacts

The problem of determining the provenance of the white marble used for antique artifacts has been tackled in different ways. During the past decade it became clear that a multimethod approach is required to solve the problem. In addition, reliable reference material, i.e., samples collected at the ancient quarry sites in an archaeologically and geologically justified manner, turned out to be a prerequisite for reliable provenance determination. A multimethod approach based on petrography, stable isotope analysis of O and C, and trace element analysis yields complementary information. These methods were applied to the same set of 225 quarry samples. When processed with powerful statistical methods, the data thus obtained allowed all major types of marble used in antiquity to be distinguished. Thus, most problems concerning the provenance of artifacts can be solved. This approach was successfully applied to the provenance determination of about 75 artifacts from different museums in Europe and the USA.