Al2O3 Colloidal Nanocrystals with Strong UV Emission

A facile sol–gel procedure has been developed for the synthesis of colloidal alumina nanocrystals. For the first time, optical characterization procedures were employed to study the quantum confinement effects in optical properties of the prepared Al₂O₃ sol. Accordingly, the hyperbolic band model was used to determine the optical band gap of colloidal alumina nanocrystals. X‐Ray diffraction pattern was used to study the crystallographic phase of the dried gel. Morphological characterization was performed using scanning electron microscopy (SEM). Inductively Coupled Plasma (ICP) emission spectroscopy was used to determination purity of the Al₂O₃ powder. High‐resolution TEM showed that the diameter of colloidal nanocrystals is about 10 nm. Photoluminescence spectroscopy demonstrated that quantum yields for colloidal nanocrystals are 68% with 300 nm excitation wavelength. The experimental observations confirm that highly stable alumina sol with strong UV emission was synthesized. The mentioned optical properties have not been reported before.     

An H∞non‐fragile observer‐based adaptive sliding mode controller design for uncertain fractional‐order nonlinear systems with time delay and input nonlinearity

In this paper the problem of non‐fragile adaptive sliding mode observer design is addressed for a class of nonlinear fractional‐order time‐delay systems with uncertainties, external disturbance, exogenous noise, and input nonlinearity. An H_∞ observer‐based adaptive sliding mode control considering the non‐fragility of the observer is proposed for this system. The sufficient asymptotic stability conditions are derived in the form of linear matrix inequalities. It is proven that the sliding surface is reachable in finite time. An illustrative example is provided which corroborates the effectiveness of the theoretical results.     

A NEW AGENT MATCHING SCHEME USING AN ORDERED FUZZY SIMILARITY MEASURE AND GAME THEORY

In this paper, an agent matching method for bilateral contracts in a multi-agent market is proposed. Each agent has a hierarchical representation of its trading commodity attributes by a tree structure of fuzzy attributes. Using this structure, the similarity between the trees of each pair of buyer and seller is computed using a new ordered fuzzy similarity algorithm. Then, using the concept of Stackelberg equilibrium in a leader–follower game, matchmaking is performed among the sellers and buyers. The fuzzy similarities of each agent with others in its personal viewpoint have been used as its payoffs in a bimatrix game. Through a case study for bilateral contracts of energy, the capabilities of the proposed agent-based system are illustrated.     

ConsilientSFL: using preferential voting system to generate combinatorial ranking metrics for spectrum-based fault localization

Spectrum-based fault localization (SFL) techniques have shown considerable effectiveness in localizing software faults. They leverage a ranking metric to automatically assign suspiciousness scores to certain entities in a given faulty program. However, for some programs, the current SFL ranking metrics lose effectiveness. In this paper, we introduce ConsilientSFL that is served to synthesize a new ranking metric for a given program, based on a customized combination of a set of given ranking metrics. ConsilientSFL can be significant since it demonstrates the usage of voting systems into a software engineering task. First, several mutated, faulty versions are generated for a program. Then, the mutated versions are executed with the test data. Next, the effectiveness of each existing ranking metric is computed for each mutated version. After that, for each mutated version, the computed existing metrics are ranked using a preferential voting system. Consequently, several top metrics are chosen based on their ranks across all mutated versions. Finally, the chosen ranking metrics are normalized and synthesized, yielding a new ranking metric. To evaluate ConsilientSFL, we have conducted experiments on 27 subject programs from Code4Bench and Siemens benchmarks. In the experiments, we found that ConsilientSFL outperformed every single ranking metric. In particular, for all programs on average, we have found performance measures recall, precision, f-measure, and percentage of code inspection, to be nearly 7, 9, 12, and 5 percentages larger than using single metrics, respectively. The impact of this work is twofold. First, it can mitigate the issue with the choice and usage of a proper ranking metric for the faulty program at hand. Second, it can help debuggers find more faults with less time and effort, yielding higher quality software.

     

Model updating of multistory shear buildings for simultaneous identification of mass,stiffness and damping matrices using two different soft-computing methods

In this research, two novel methods for simultaneous identification of mass–damping–stiffness of shear buildings are proposed. The first method presents a procedure to estimate the natural frequencies, modal damping ratios, and modal shapes of shear buildings from their forced vibration responses. To estimate the coefficient matrices of a state-space model, an auto-regressive exogenous excitation (ARX) model cooperating with a neural network concept is employed. The modal parameters of the structure are then evaluated from the eigenparameters of the coefficient matrix of the model. Finally, modal parameters are used to identify the physical/structural (i.e., mass, damping, and stiffness) matrices of the structure. In the second method, a direct strategy of physical/structural identification is developed from the dynamic responses of the structure without any eigenvalue analysis or optimization processes that are usually necessary in inverse problems. This method modifies the governing equations of motion based on relative responses of consecutive stories such that the new set of equations can be implemented in a cluster of artificial neural networks. The number of neural networks is equal to the number of degree-of-freedom of the structure. It is shown the noise effects may partially be eliminated by using high-order finite impulse response (FIR) filters in both methods. Finally, the feasibility and accuracy of the presented model updating methods are examined through numerical studies on multistory shear buildings using the simulated records with various noise levels. The excellent agreement of the obtained results with those of the finite element models shows the feasibility of the proposed methods.     

Lower limits of spin detection efficiency for two-parameter two-qubit (TPTQ) states with non-ideal ferromagnetic detectors

We have investigated a TPTQ state as an input state of a non-ideal ferromagnetic detectors. Minimal spin polarization required to demonstrate spin entanglement according to entanglement witness and CHSH inequality with respect to (w.r.t.) their two free parameters have been found, and we have numerically shown that the entanglement witness is less stringent than the direct tests of Bell’s inequality in the form of CHSH in the entangled limits of its free parameters. In addition, the lower limits of spin detection efficiency fulfilling secure cryptographic key against eavesdropping have been derived. Finally, we have considered TPTQ state as an output of spin decoherence channel and the region of ballistic transmission time w.r.t. spin relaxation time and spin dephasing time has been found.     

Hydrogenation of p‐Nitrophenol to p‐Aminophenol as a Test Reaction for the Catalytic Activity of Supported Pt Catalysts

Hydrogenation of p‐nitrophenol (PNP) to p‐aminophenol (PAP) using NaBH₄ as a reducing agent was studied as a test reaction for determining the catalytic activity of supported Pt catalysts. The initial reaction rate, which is accessible within less than 10 min via online UV‐vis spectroscopy at room temperature, ambient pressure, and in water as solvent, was applied as measure for catalytic activity. For three Pt catalysts supported on porous SiO₂, porous glass, and Al₂O₃, respectively, significant differences in the catalytic activity by almost one order of magnitude were observed. However, especially in the case of very active catalysts, limitations of the reaction by internal or external mass transfer have to be considered.     

Low-loss Ti:LiNbO3-waveguide bends prepared by MgOindiffusion

A significant bend loss reduction for z-cut Ti:LiNbO₃ waveguides was achieved with a single and very efficient technique. The refractive index on the outer sides of an S bend was decreased through indiffusion of a double-MgO layer for reducing the radiation losses, and a broadening of the bent waveguide sections was used for further decreasing of the radiation losses and additionally reducing the transition losses. The acceptable bend radius for an allowed excess loss of 1 dB could thus be reduced from 24 mm down to 5 mm for TM polarization and from 26 mm down to 10 mm for TE polarization