Analysis of diastereomeric DAG naphthylethylurethanes by normal-phase HPLC with on-line electrospray MS

Normal-phase HPLC resolution of sn-1,2(2,3)- and x-1,3-DAG generated by partial Grignard degradation from natural TAG was carried out with both (R)-(−) and (S)-(+)-1-(1-naphthyl)ethylurethane derivatives. The diastereomeric sn-1,2- and sn-2,3-DAG derivatives were resolved using two Supelcosil LC-Si (5 μm, 25 cm × 4.6 mm i.d.) columns in series and an isocratic elution with 0.37% isopropanol in hexane at a flow rate of 0.7 mL/min. The DAG were detected by UV absorption at 280 nm and were identified by electrospray ionization MS in the positive ion mode following postcolumn addition of chloroform/methanol/30% ammonium hydroxide (75∶24.5∶0.5, by vol) at 0.6 mL/min. Application of the method to a stereospecific analysis of the molecular species of TAG of rat VLDL showed that the TAG composition of VLDL circulating under basal conditions differs markedly from that of VLDL secreted by the liver during inhibition of serum lipases. The inhibition of serum lipases resulted in a significant proportional decrease in 16∶0 and PUFA and an increase in 18∶0 and oligoenoic FA in the sn-1-position, whereas the FA compositions in the sn-2- and sn-3-positions were much less affected.     

Iron Behavior in the Ozonation and Filtration of Groundwater

In Finnish groundwater, the main substances that require treatment are iron and manganese. In addition to this, groundwaters are soft and acidic. Iron removal is usually relatively effective by oxidizing dissolved iron into an insoluble form, either by aeration or chemical oxidization and removing the formed precipitate by sand filtration. Sometimes, if the untreated water contains high amounts of organic matter, problems may arise for iron removal. In Finland, it is quite common that groundwater contains high levels of both iron and natural organic matter, mainly as humic substances. The groundwater of the Kukkala intake plant in Liminka has been found to be problematic, due to its high level of natural organic matter. This research studied the removal of iron from this water by means of oxidation with ozone and filtration. While the oxidation of iron by ozone was rapid, the precipitate particles formed were small, and thus could not be removed by sand and anthracite filtration, and the iron residue in the treated water was more than 2 mgL^?1. And while the filtration was able to remove iron well without the feed of ozone, the iron residue in the treated water was only 0.30 mgL^?1. In this case, iron was led to the filter in a bivalent dissolved form. So, the result of iron removal was the best when the sand/anthracite filter functioned largely as an adsorption filter.     

Reaction engineering studies in a polytropic fixed-bed reactor over a highly active and selective catalyst for oxidative methane coupling

The oxidative coupling of methane (OCM) was carried out in a polytropic fixed-bed reactor applying a Zr/La/Sr catalyst developed by the Neste company. Over this catalyst the OCM reaction follows a complex reaction scheme which includes primary parallel reaction steps to CO, CO₂ and C₂H₆ and consecutive reactions of ethane to ethylene or CO_x. Yield of higher hydrocarbons C₂₊ obtained with this catalyst strongly depended on reaction conditions, i.e. low partial pressures of methane and oxygen obtained by diluting the feed gas with nitrogen and high reaction temperatures promoted C₂₊ selectivity and yield. The maximum yield amounted to 21.4% (20 Vol.-% CH₄, 9 Vol.-% O₂, 71 Vol.-% N₂, T = 860°C; X_CH4 = 41.8%, S = 52.5%). This result belongs to the highest yields reported in the open literature.     

Optical performance characterization of flexible mobile displays

The high interest in the display industry to produce curved or flexible displays for mobile, wearable, and television markets has raised concerns on the performance of displays in their bent state. Flexible display technologies have been developed for this purpose, but their optical characteristics have not been previously reported at various degrees of curvature. The measurement of flexible displays is possible only with special measurement arrangements using common display characterization devices. A conoscope with a working distance of 15 mm was used to demonstrate the curvature dependence of luminance, viewing angle, and color coordinates of the white point of a flexible active‐matrix organic light‐emitting display. The results show that the effect of curvature on the optical characteristics of the display is most evident at the smallest measured bending radii of +/?50 mm and that the effects are most visible when viewing the bent ends of the display, from the central normal vantage point, with uniform curvature along the display.     

Diffractive backlight grating array for mobile displays

Abstract— The display backlight unit (BLU) is the most power‐consuming subunit in mobile liquid‐crystal displays. The state‐of‐the‐art BLUs utilize scattering, refractive, and reflective microstructures to generate a uniform distribution of white light through the display. More effective means of transmitting light through the display color filters could be obtained by using diffraction, but previously proposed diffractive backlights do not fully utilize all the possibilities to design gratings effectively for optimal color separation and outcoupling. This paper presents a new pixelated diffractive backlight grating array as an approach for overcoming these obstacles in BLU design. A model array was fabricated to couple out red, green, and blue primary colors from the respective subpixel locations. The results show that it is possible to manufacture such an array and that the light couples out as intended, giving a starting point to design mobile‐display modules with low light‐transmission losses.     

Normalising OLAP cubes for controlling sparsity

A poorly designed OLAP (on-line analytical processing) cube can have a size much larger than the volume of information, potentially leading to problems with performance and usability. We give a new normal form for OLAP cube design and synthesis and decomposition algorithms to produce normalised OLAP cube schemata. OLAP cube normalisation controls the structural sparsity resulting from inter-dimensional functional dependencies. We assume that functional dependencies are used to describe the constraints of the application universe of discourse. Our methods help the user to identify cube schemata with structural sparsity, and to change the design in order to obtain more economy of space.