Thermal and aqueous stability improvement of graphene oxide enhanced diphenylalanine nanocomposites

Abstract

Nanocomposites of diphenylalanine (FF) and carbon based materials provide an opportunity to overcome drawbacks associated with using FF micro- and nanostructures in nanobiotechnology applications, in particular their poor structural stability in liquid solutions. In this study, FF/graphene oxide (GO) composites were found to self-assemble into layered micro- and nanostructures, which exhibited improved thermal and aqueous stability. Dependent on the FF/GO ratio, the solubility of these structures was reduced to 35.65% after 30 min as compared to 92.4% for pure FF samples. Such functional nanocomposites may extend the use of FF structures to e.g. biosensing, electrochemical, electromechanical or electronic applications.     

Intelligent System for Adapting to a User’s Characteristics

In this paper, we propose an intelligent system that adapts itself to a user’s characteristics or habits. The proposed intelligent system is composed of two Learning Vector Quantisation (LVQ) networks, commonly used in the fields of pattern recognition and signal processing. From the external condition of the plant, the first LVQ network learns to recognise the pattern of the sensed signal, and then aids the second LVQ to learn the user’s characteristics or habits so as to automatically produce the user’s favoured output. To verify the usefulness of the proposed method, we simulated and experimented with a variable illuminator. Both simulation and experimental results showed that the proposed intelligent system learns to automatically produce the illuminator output that the user most favours for the circumstances.     

Reports of the DAS02 working groups

This document is a collection of four working group reports in the areas of digital libraries, document image retrieval, layout analysis, and Web document analysis. These reports were the outcome of discussions by participants at the Fifth IAPR International Workshop on Document Analysis Systems held in Princeton, NJ on 19-21 August 2002.Published online: 16 March 2004     

Antimicrobial efficacies of essential oils/nanoparticles incorporated polylactide films against L. monocytogenes and S. typhimurium on contaminated cheese

Polylactide based films were formulated by incorporating polyethylene glycol, selected nanopowders (zinc oxide, silver-copper), and essential oils (cinnamon, garlic, and clove) by solvent casting method. Films were tested against three foodborne pathogens (one gram-positive and two gram-negative) for their antibacterial activity. The effectiveness of selected cinnamon oil-based film was ascertained by performing a challenge test with cheese as a food model. In vitro antibacterial efficacies of nanopowders and essential oils were also determined by the decimal reduction concentrations and the minimum bactericidal concentrations for those foodborne pathogens. It was observed that nanopowders exhibited considerably poorer decimal reduction concentrations and minimum bactericidal concentration values in comparison to the essential oils. Silver-copper alloy nanopowders exhibited lower decimal reduction concentrations and minimum bactericidal concentrations values than ZnO against tested pathogens whereas essential oils showed distinct antimicrobial effectiveness against all those pathogens with in vitro decimal reduction concentration values of 87–157 and 77–220 µg/mL for cinnamon and clove oils, respectively. Among the various formulations, it was observed that only essential oils (especially cinnamon and clove) incorporated films exhibited a significant antimicrobial activity against the selected microorganisms. These results indicate that the poor antibacterial activity of the nanopowders and the hydrophobicity of polylactide could be responsible for the ineffectiveness of nanopowders in polylactide based films. Furthermore, the challenge test indicated the polylactide/polyethylene glycol/cinnamon oil film was appropriate to inhibit the growth of L. monocytogenes and S. typhimurium on cheese up to 11 days at refrigerated storage.     

A pilot level approach to remove anionic species from industrial effluents using a novel carbonate-steam pyrolysed activated charcoal system

In our laboratory, we synthesized a novel surface tailored activated charcoal in removing nitrite species from fertilizer industrial effluents. A customized high temperature carbonate-steam activation technique was adopted to develop the sodium carbonate impregnated activated charcoal (SCIAC). The surface properties of the material were determined using SEM, TG and X-RD techniques. Batch adsorption experiments were performed for optimizing various conditions such as solution pH, contact time, temperature and adsorbent dose for maximizing the nitrite adsorption onto SCIAC. Considerably, a very high nitrite adsorption percentage of 83.8 was obtained for an initial nitrite concentration of 5.0?mg/L at pH 3.0. Among the various equilibrium and kinetic models, Freundlich and pseudo-second-order expressions, respectively, were well enough to explain the adsorption processes. In general, it may conclude that the change in surface characteristics of the adsorbent material after the pyrolysis process is highly favorable for effective removal of nitrite ions from aqueous systems. Adsorption capacity of SCIAC was 27.03?mg/g and studies revealed that the material was feasible in removing nitrite from industrial effluents.     

Sustainable recovery of grape skins for use in an apple beverage with antiglycation properties

An apple puree formulated with red grape skins was developed on pilot scale as a new beverage with antiglycation properties. The addition level of grape skins was selected by a liking test with 70 consumers. The selected formulation was a fibre‐rich source and delivered grape anthocyanins, flavonols and flavanols resulting in ~ twofold higher antiglycation activity than the apple puree. Pasteurisation (3‐D in the target microorganism Alicyclobacillus acidoterrestris) did not affect the antiglycation activity, which decreased by 30% upon sterilisation. Storage for 1 month in the temperature range 15–35 °C affected the contents of anthocyanins, monomeric, dimeric and oligomeric flavanols, while chlorogenic acid, flavonols and dihydrochalcones were stable. About 90% antiglycation activity was retained after one‐month storage at 15 °C. The use of red grape skin as ingredient could represent an opportunity for the apple processing industry to develop a value‐added product.     

Nanoglass–Nanocrystal Composite—a Novel Material Class for Enhanced Strength–Plasticity Synergy

The properties of a material can be engineered by manipulating its atomic and chemical architecture. Nanoglasses which have been recently invented and comprise nanosized glassy particles separated by amorphous interfaces, have shown promising properties. A potential way to exploit the structural benefits of nanoglasses and of nanocrystalline materials is to optimize the composition to obtain crystals forming within the glassy particles. Here, a metastable Fe‐10 at% Sc nanoglass is synthesized. A complex hierarchical microstructure is evidenced experimentally at the atomic scale. This bulk material comprises grains of a Fe₉₀Sc₁₀ amorphous matrix separated by an amorphous interfacial network enriched and likely stabilized by hydrogen, and property‐enhancing pure‐Fe nanocrystals self‐assembled within the matrix. This composite structure leads a yield strength above 2.5 GPa with an exceptional quasi‐homogeneous plastic flow of more than 60% in compression. This work opens new pathways to design materials with even superior properties.     

The effect of speed of balanced rotor on nonlinear vibrations associated with ball bearings

The paper deals with the structural dynamic response of rotor supported by ball bearings. The mathematical model takes into account the sources of nonlinearity such as Hertzian contact force, surface waviness, varying compliance and internal radial clearance resulting transition from no contact to contact state between rolling elements and races. In terms of the feature that the nonlinear bearing forces act on the system, a new reduction method and corresponding integration technique is used to increase the numerical stability and decrease computer time for system analysis. The effects of speed of balanced rotor in which ball bearings show periodic, quasi-periodic and chaotic behavior are analyzed. The results are presented in the form of time displacement responses, frequency spectra and Poincarè maps. It is implied from the frequency spectra that peak amplitude of vibrations appear at the varying compliance frequency.