Synthesis of Hollow Three-Dimensional Channels LiNi_(0.5)Mn_(1.5)O_4 Microsphere by PEO Soft Template Assisted with Solvothermal Method

A appropriate size with three-dimension(3 D) channels for lithium diffusion plays an important role in constructing highperforming LiNi_(0.5)Mn_(1.5)O_4(LNMO) cathode materials, as it can not only reduce the transport path of lithium ions and electrons, but also reduce the side effects and withstand the structural strain in the process of repetitive Li~+ intercalation/deintercalation. In this work, an e fficient method for designing the hollow LNMO microsphere with 3 D channels structure by using polyethylene oxide(PEO) as soft template agent assisted solvothermal method is proposed. Experimental results indicate that PEO can make the reagents mingle evenly and nucleate slowly in the solvothermal process, thus obtaining a homogeneous distribution of carbonate precursors. In the final LNMO products, the hollow 3 D channels structure obtained by the decomposition of PEO and carbonate precursor in the calcination can provide abundant electroactive zones and electron/ion transport paths during the charge/discharge process, which benefits to improve the cycling performance and rate capability. The LNMO prepared by adding 1 g PEO possesses the most outstanding electrochemical performance, which presented an excellent discharge capacity of 143.1 mAh g~(-1) at 0.1 C and with a capacity retention of 92.2% after 100 cycles at 1 C. The superior performance attributed to the 3 D channels structure of hollow microspheres, which provide uninterrupted conductive systems and therefore achieve the stable transfer for electron/ion.     

Optical design of the Lyman alpha based beam emission spectroscopy(LAB)diagnostic on the HL-2A tokamak

In this article, we present the optical design of a novel diagnostic on the HL-2 A tokamak, i.e. the20-channel edge Lyman-alpha beam emission spectroscopy, which is a promising solution for edge density turbulence research on tokamaks, as it offers the possibility of density fluctuation measurement with a 3.3 mm spatial resolution while maintains a high temporal resolution of1 μs. The optical path, including the reflective collection optics, the high-dispersion spectrometer, and the linear detector array, is carefully optimized to obtain a good image quality and a high throughput. The maximum root mean square radius of the collection optics is 64 μm.The detected photon flux is estimated to be about 10~(11) photons/s/channel.     

Thermodynamic analysis of ethanol synthesis from hydration of ethylene coupled with a sequential reaction

Coal-based ethanol production by hydration of ethylene is limited by the low equilibrium ethylene conversion at elevated temperature. To improve ethylene conversion, coupling hydration of ethylene with a potential ethanol consumption reaction was analyzed thermodynamically. Five reactions have been attempted and compared: (1) dehydration of ethanol to ethyl ether ({\mathrm{2C}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}\mathrm{OH}\iff{\mathrm{C}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{OC}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{+H}}_{\mathrm{2}}\mathrm{O}), (2) dehydrogenation of ethanol to acetaldehyde ({\mathrm{C}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}\mathrm{OH}\iff {\mathrm{CH}}_{\mathrm{3}}{\mathrm{CHO+H}}_{\mathrm{2}}), (3) esterification of acetic acid with ethanol ({\mathrm{C}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{OH+CH}}_{\mathrm{3}}\mathrm{COOH}\iff {\mathrm{CH}}_{\mathrm{3}}{\mathrm{COOC}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{+H}}_{\mathrm{2}}\mathrm{O}), (4) dehydrogenation of ethanol to ethyl acetate ({\mathrm{2C}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}\mathrm{OH}\iff {\mathrm{CH}}_{\mathrm{3}}{\mathrm{COOC}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{+2H}}_{\mathrm{2}}), and (5) oxidative dehydrogenation of ethanol to ethyl acetate ({\mathrm{2C}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{OH+O}}_{\mathrm{2}}\iff {\mathrm{CH}}_{\mathrm{3}}{\mathrm{COOC}}_{\mathrm{2}}{\mathrm{H}}_{\mathrm{5}}{\mathrm{+2H}}_{\mathrm{2}}\mathrm{O}). The equilibrium constants and equilibrium distributions of the coupled reactions were calculated and the effects of feed composition, temperature and pressure upon the ethylene equilibrium conversion were examined. The results show that dehydrogenation of ethanol to acetaldehyde has little effect on ethylene conversion, whereas for dehydrogenation of ethanol to acetaldehyde and ethyl acetate, ethylene conversion can be improved from 8% to 12.8% and 18.5%, respectively, under conditions of H₂O/C₂H₄ = 2, 10 atm and 300°C. The esterification of acetic acid with ethanol can greatly enhance the ethylene conversion to 22.5%; in particular, ethylene can be actually completely converted to ethyl acetate by coupling oxidative dehydrogenation of ethanol.     

A computer aided design method for car form and its application based on shape parameters

In the early design stage, automotive modeling should both meet the requirements of aesthetics and engineering. Therefore, a vehicle CAD (computer aided design) model that can be easily adjusted by feedbacks is necessary. Based on CE-Bézier surface, this paper presents a set of algorithms for parametric segmentation and fairing surface generation in a car model. This model is defined by a simplified automotive template and relevant control points, shape parameters and segmentation parameters, which can be modified to alter the car form efficiently. With this model and the corresponding adjustment method, more than fifty various vehicle models are established in this research according to different parameters. And two methods for calculating similarity index between car models are constructed, which are suitable for brand design trend analysis and modelling design decisionmaking.     

浅析有机热载体的更换或再生

探讨了有机热载体的几个物理属性参数，同时提出了有机热载体进行更换或再生的简易判断式。     

Applications of Skyrme Energy-Density Functional to Fusion Reactions for Synthesis of Superheavy Nuclei

It is of great importance to predict fusion cross sections and to analyze reaction mechanism for massive heavy-ion fusion reactions, especially for fusion reactions leading to superheavy nuclei. In those reactions, the calculation of the capture cross section is of crucial importance. It is known that Wong＇s formula based on one-dimensional barrier penetration can describe the fusion excitation function well for light reaction systems, while it fails to give satisfying results for heavy reaction systems at energies near and below the barrier. For solving this problem, we applied the Skyrme energy-density functional for the first time to study heavy-ion fusion reactions. The barrier for fusion reaction was calculated by the Skyrme energy-density functional together with the semi-classical extended Thomas-Fermi method.     

EXPERIMENTAL INVESTIGATIONS ON LONGITUDINAL DISPERSION CHARACTERISTICS OF TIDAL RIVERS

1 .　ＩＮＴＲＯＤＵＣＴＩＯＮＵｎｄｅｒｔｈｅｉｎｆｌｕｅｎｃｅｏｆｎａｔｕｒａｌｔｉｄｅｓ,ｔｈｅｉｎｔｅｒａｃ ｔｉｏｎｓｂｅｔｗｅｅｎｆｌｏｗｆｅａｔｕｒｅｓａｎｄｐｏｌｌｕｔａｎｔｌｏｎｇｉｔｕｄｉｎａｌｄｉｆｆｕｓｉｏｎｉｎｔｉｄａｌｒｉｖｅｒｓａｒｅｉｍｐｏｒｔａｎｔｆｏｒｗａｔｅｒｅｎｖｉ ｒｏｎｍｅｎｔｒｅｃｔｉｆｉｃａｔｉｏｎｉｎｅｓｔｕａｒｉｎｅｒｅｇｉｏｎｓ.Ｔｈｅｄｉｆｆｕ ｓｉｏｎａｎｄｔｒａｎｓｐｏｒｔｏｆｐｏｌｌｕｔａｎｔｉｎｎａｔｕｒａｌｒｉｖｅｒｓｆａｌｌｉｎ ｔｏｍ…     

A NEW LARGE CAVITATION CHANNEL IN CHINA SHIP SCIENTIFIC RESEARCH CENTER

1 .　INTRODUCTIONIntherecentdecades ,itisrealizedthatitisquitenecessarytocarryouttestsathighReynoldsnumberwithalowbackgroundnoiselevelinordertomeetmoreandmoreurgentneedsofmodernnavyandmaritimeindustry .Anewlargecavita tionchannelisdevelopedinCSSRCfortestingcompletehull/ propulsor/appendagesarrange ments[1] .Itrepresentsoneofthelatestintechno logicallyadvancedlargecavitationtestfacilities.Inthefollowingsections ,thefeaturesandthefirsttestresultsofthechannelwillbedescribed .2 .　DICRIP…     

用热导仪检测祖母绿

用热导仪检测祖母绿我曾先后报导过三种热导仪，它们都是设计来检测有色宝石和钻石的仿制品的。现在我发现我没有强调这类仪器的另一种极有意义的功能。最近，我用热导仪测了一个吉尔森合成祖母绿，更加证实合成祖母绿的热导至少是天然祖母绿的两倍。为了更彻底地探索这种...     

EXPERIMENTAL INVESTIGATIONS ON DIFFUSION CHARACTERISTICS OF HIGH CONCENTRATION JET FLOW IN NEAR REGION

1 .　ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｒｅｓｅａｒｃｈｏｆｊｅｔｉｓａｎｉｍｐｏｒｔａｎｔｆｉｅｌｄｉｎｆｌｕｉｄｍｅｃｈａｎｉｃｓ.Ｉｔａｌｓｏｈａｓｍａｎｙａｐｐｌｉｃａｔｉｏｎｓｉｎｅｎｇｉｎｅｅｒｉｎｇ ,ｆｏｒｅｘａｍｐｌｅ ,ｔｈｅｄｉｓｃｈａｒｇｅｏｆｐｏｌｌｕｔａｎｔａｎｄｃｏｏｌｉｎｇｗａｔｅｒｉｎｉｎｄｕｓｔｒｉｅｓ .Ｗｈｅｎｔｈｅｉｎｉｔｉａｌｄｅｎｓｉｔｙｏｆｔｈｅｊｅｔｉｓｄｉｆｆｅｒｅｎｔｆｒｏｍｔｈａｔｏｆｔｈｅａｍｂｉｅｎｔｗａｔｅｒｂｏｄｙ ,ｔｈｅｊｅｔｗｉｌｌｂｅａｆ…