YBa_2Cu_(2.88)Fe_(0.12)O_(7-δ)高Tc超导体的M(?)ssbauer谱研究

本文研究了YBa_2Cu_(2.88)Fe_(0.12)O_(7-δ)高Tc超导体氧化物的穆斯堡尔效应,测定了Fe的价态和环境,并用点电荷模型进行了计算。Fe有三个亚晶位(Fe(1)、Fe(2)和Fe(3)),Fe(1)和Fe(3)占有YBa_2Cu_3O_(7-δ)氧化物的Cu(1)晶位,但Fe(1)周围氧的分布与Fe(3)的不同。Fe(2)占有Cu(2)晶位。Fe(1)和Fe(2)是低自旋的Fe~(+3),而Fe(3)是高自旋的Fe~(+3)。掺铁引进一些附加氧原子,它们处在Y-Ba-Cu-O体系中(001)平面的非Cu-O链上,这造成晶格趋向于四方结构。     

YBa2Cu2.88Fe0.12O7—δ高温超导氧化物随温度变化的穆斯堡尔谱研究

本文研究了YB_(a2)Cu(2.88)Fe(0.12)O_(7-8)超导氧化物在78～300K 温度区间的穆斯堡尔效应。我们发现当温度降至130K 附近时,三个晶位上的(57)~Fe 的四极裂距明显增加,且随温度降低继续增大。它们的同质异能移位则在130K 附近明显下降,在110K 附近降到最低点。我们认为导致这些变化的原因是:晶格的正交畸变明显增大,氧在Cu-O 平面排列的有序度增加。     

The Mssbauer Effect of Y-Ba-Cu-Fe-O Superconductive Oxide

We have studied the Mossbauer effect ofYBa_2Cu_(2.88)Fe_(0.12)O_(7-x) superconductive oxide from78 to 273K. Two minima of recoilless fractionand Debye temperature were found near 110K and220K. It means that lattice softening happenednear these two temperatures. We also observedminima of isomer shift near 110K and quadrupolesplitting increase when temperature is lowerthan 110K. We suggest that lattice softeningwould lead to the displacement of oxygen atoms.This may be relative to superconductivetransition.