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排序方式: 共有935条查询结果,搜索用时 15 毫秒
1.
P. Sampath Brijesh Kakarla Raghava Reddy C. Venkata Reddy Nagaraj P. Shetti Raghavendra V. Kulkarni Anjanapura V. Raghu 《化学工程与技术》2020,43(7):1240-1248
Hydrogen fuel is a promising alternative to fossil fuels because of its energy content, clean nature, and fuel efficiency. However, it is not readily available. Most current producion processes are very energy intensive and emit carbon dioxide. Therefore, this article reviews technological options for hydrogen production that are eco-friendly and generate clean hydrogen fuel. Biological methods, such different fermentation processes and photolysis are discussed together with the required substrates and the process efficiency. 相似文献
2.
Mani Balamurugan Hui‐Yun Jeong Venkata Surya Kumar Choutipalli Jung Sug Hong Hongmin Seo Natarajan Saravanan Jun Ho Jang Kang‐Gyu Lee Yoon Ho Lee Sang Won Im Venkatesan Subramanian Sun Hee Kim Ki Tae Nam 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(25)
The electrochemical reduction of carbon dioxide (CO2) to hydrocarbons is a challenging task because of the issues in controlling the efficiency and selectivity of the products. Among the various transition metals, copper has attracted attention as it yields more reduced and C2 products even while using mononuclear copper center as catalysts. In addition, it is found that reversible formation of copper nanoparticle acts as the real catalytically active site for the conversion of CO2 to reduced products. Here, it is demonstrated that the dinuclear molecular copper complex immobilized over graphitized mesoporous carbon can act as catalysts for the conversion of CO2 to hydrocarbons (methane and ethylene) up to 60%. Interestingly, high selectivity toward C2 product (40% faradaic efficiency) is achieved by a molecular complex based hybrid material from CO2 in 0.1 m KCl. In addition, the role of local pH, porous structure, and carbon support in limiting the mass transport to achieve the highly reduced products is demonstrated. Although the spectroscopic analysis of the catalysts exhibits molecular nature of the complex after 2 h bulk electrolysis, morphological study reveals that the newly generated copper cluster is the real active site during the catalytic reactions. 相似文献
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Mingming Zhang Venkat Kamavaram Ramana G. Reddy 《Journal of Phase Equilibria and Diffusion》2005,26(2):124-130
Thermodynamic properties of 1-butyl-3-methylimidazolium chloride (C4mim[Cl]) ionic liquid were determined using thermogravimetric (TG) differential thermal analysis (DTA). A new method called
DTA mass-difference baseline, was used to measure the heat capacity and enthalpy change of phase transformation of ionic liquid
from DTA curves. Based on this, the changes in standard enthalpy, entropy, and Gibbs energy were determined. The results show
that standard enthalpy and entropy changes of C4mim[Cl] increase nonlinearly with increasing temperature, while the standard Gibbs energy change decreases nonlinearly with
increasing temperature within the temperature range studied (298–453 K). The standard enthalpy of melting and enthalpy of
vaporization were determined to be 0.93 and 11.07 kJ/mol, respectively. 相似文献
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Liping Wang Ramana V. Grandhi Dale A. Hopkins 《International journal for numerical methods in engineering》1995,38(10):1721-1738
The objective of this paper is to conduct reliability-based structural optimization in a multidisciplinary environment. An efficient reliability analysis is developed by expanding the limit functions in terms of intermediate design variables. The design constraints are approximated using multivariate splines in searching for the optimum. The reduction in computational cost realized in safety index calculation and optimization are demonstrated through several structural problems. This paper presents safety index computation, analytical sensitivity analysis of reliability constraints and optimization using truss, frame and plate examples. 相似文献
8.
A novel processing technology was developed to investigate in situ synthesis of TiC-Al (Ti) nanocomposite powders by thermal plasma technology. Thermodynamic analysis was performed to predict
possible starting materials and synthesizing conditions of TiC-Al (Ti) nanocomposite powders. A mathematical model was developed
to describe temperature profile and velocity distribution in the reactor. The model is applied to optimize feeding rate, input
power, and other processing parameters of TiC-Al (Ti) nanocomposite powders by thermal plasma technology, and to predict which
materials can be used as starting materials. This paper emphasizes the investigation of the effect of feeding rate, input
power, mole ratio, and other process parameters on synthesis of TiC-Al (Ti) nanocomposite powders by thermal plasma technology.
The experimental results showed that TiC-Al (Ti) nanocomposite powders can be synthesized in situ by thermal plasma technology, and the average size of TiC-Al (Ti) nanocomposite powders was less than 100 nm. 相似文献
9.
Pori Maja Arčon Iztok Dasireddy Venkata D. B. C. Likozar Blaž Orel Zorica Crnjak Marinšek Marjan 《Catalysis Letters》2021,151(11):3114-3134
Catalysis Letters - Industrial Cu/ZnO/Al2O3 or novel rate catalysts, prepared with a photochemical deposition method, were studied under functional CH3OH synthesis conditions at the set temperature... 相似文献
10.
Distortion as a result of the quenching process is predominantly due to the thermal gradient and phase transformations within
the component. Compared with traditional liquid quenching, the thermal boundary conditions during gas quenching are relatively
simple to control. By adjusting the gas-quenching furnace pressure, the flow speed, or the spray nozzle configuration, the
heat-transfer coefficients can be designed in terms of both the component geometry and the quenching time. The purpose of
this research is to apply the optimization methodology to design the gas-quenching process. The design objective is to minimize
the distortion caused by quenching. Constraints on the average surface hardness, and its distribution and residual stress
are imposed. The heat-transfer coefficients are used as design variables. DEFORM-HT is used to predict material response during
quenching. The response surface method is used to obtain the analytical models of the objective function and constraints in
terms of the design variables. Once the response surfaces of the objective and constraints are obtained, they are used to
search for the optimum heat-transfer coefficients. This process is then used instead of the finite-element analysis. A one-gear
blank case study is used to demonstrate the optimization scheme. 相似文献