The synthesis of block copolyetherketones based on 4,4′‐dichlorodiphenylketone,phenolphthaleine, and bisphenol A and investigation of their properties

Block structured polyethers based on phenolphthaleine, 4,4′‐dichlorodiphenylketone, and bisphenol A with different degrees condensation (n = 1, 5, 10, and 20) were synthesized by means of acceptor‐catalytic polycondensation. Equaimolar quantities of chloranhydrides of iso‐ and terephthalic acids were used. Higher molecular masses were obtained from longer oligoketones with higher condensation degrees. Better molecular packing, increased thermal and mechanical properties were obtained with higher condensation degrees of oligoketones. © 2007 Wiley Periodicals, Inc. JAppl Polym Sci, 2008     

Optimized Machine Learning Algorithms for Investigating the Relationship Between Economic Development and Human Capital

Computational Economics - In Economic Development, human capital was previously seen as production factors but gradually evolved into endogenous growth theories. Most of the previous studies have...     

Combined forecasts in portfolio optimization: A generalized approach

In this paper a general mathematical model for portfolio selection problem is proposed. By considering a forecasting performance according to the distributional properties of residuals, we formulate an extended mean-variance-skewness model with 11 objective functions. Returns and return errors for each asset obtained using different forecasting techniques, are combined in optimal proportions so as to minimize the mean absolute forecast error. These proportions are then used in constructing six criteria related to the mean, variance and skewness of return forecasts of assets in the future and forecasting errors of returns of assets in the past. The obtained multi-objective model is scalarized by using the conic scalarization method which guarantees to find all non-dominated solutions by considering investor preferences in non-convex multi-objective problems. The obtained scalar problem is solved by utilizing F-MSG algorithm. The performance of the proposed approach is tested on a real case problem generated on the data derived from Istanbul Stock Exchange. The comparison is conducted with respect to different levels of investor preferences over return, variance, and skewness and obtained results are summarized.     

Reconstructing 3D trajectories of independently moving objects using generic constraints

The 3D reconstruction of scenes containing independently moving objects from uncalibrated monocular sequences still poses serious challenges. Even if the background and the moving objects are rigid, each reconstruction is only known up to a certain scale, which results in a one-parameter family of possible, relative trajectories per moving object with respect to the background. In order to determine a realistic solution from this family of possible trajectories, this paper proposes to exploit the increased linear coupling between camera and object translations that tends to appear at false scales. An independence criterion is formulated in the sense of true object and camera motions being minimally correlated. The increased coupling at false scales can also lead to the destruction of special properties such as planarity, periodicity, etc. of the true object motion. This provides us with a second, ‘non-accidentalness’ criterion for the selection of the correct motion among the one-parameter family.     

Performance of a Tied-Arch Reinforced Concrete Railway Bridge: Rating, Safety Assessment, and Bond Length Evaluation

This study presents investigations regarding visual inspection, dynamic testing, and finite-element modeling of an approximately 80-year old reinforced concrete tied-arch railway bridge that is still in service in Turkey. Investigations were conducted as part of a systematic periodic inspection along Ankara-Zonguldak railway line. The bridge is subject to heavy freight trains with increasing axle loads. Field tests such as material tests and dynamic tests were used to calibrate the finite-element model of the bridge. Detailed information regarding testing and model updating procedure is given. Based on test results, computer model was refined. The calibrated model of the bridge structure was then used for structural assessment and evaluation. Despite sufficient overall safety, local details were found to be problematic. Due to insufficient bond length in hanger-to-arch connection, a strengthening scheme using steel channel sections was proposed.     

Computational analysis of fouling by low energy surfaces

Fouling is a cost increasing problem for a variety of industries including aerospace, chemical, petroleum, and food. There have been studies on mitigation of fouling some of which recommend use of lower surface free energy materials, manufactured by different techniques, as an alternative to conventional materials. Although modeling of fouling for a given surface has been an area of interest; there is a lack in the models about correlating the surface free energy with deposit amount computationally. In this study, computational model, including the effect of surface energy and operational parameters, was proposed and validated to estimate amount of foulants deposits and rate of deposition. Towards this purpose, four coated surfaces (Microlube/PTFE, TM117P, AMC148, and CNT) were compared with stainless steel (SS316 as control) for flow rates of 3 and 10 g/s and inlet milk temperatures of 40 and 60 °C. The percent error for the decrease in outlet milk temperatures between the experimental data and computed results was between 2% and 18% except for CNT (29.2%). The calculations of deposit amount for each test case and the surfaces tested were in good agreement with the experiments, i.e., average percent difference values between measured and calculated values were from 11.1% to 38.1% (except CNT) with overall average of 21.5%.     

Human T cell leukemia virus type I expression in salivary glands of infected patients

Human T cell leukemia virus type I (HTLV-I) sequences were sought in labial salivary glands of patients with HTLV-I-associated myelopathy or tropical spastic paraparesis and of seropositive neurologically healthy carriers. HTLV-I proviral DNA was found by polymerase chain reaction amplification in DNA extracted from lip biopsies of every patient. Viral RNA was found by in situ hybridization in the acini epithelium, as well as in lymphocytic infiltrates. This observation suggests that HTLV-I expression in labial salivary glands could participate in the inflammatory lesions observed in these patients. Some seronegative patients with Sj?gren's syndrome or dryness syndrome were also positive for viral transactivator tax DNA (41% in Martinique and 16% in non-HTLV-I-endemic region). Despite histologic signs of lymphocytic infiltration, no viral expression was found in the labial salivary glands of these patients.     

Extending onshore pipeline repair to offshore steel risers with carbon–fiber reinforced composites

In the last 15 years, glass fiber hoop reinforced composite systems emerged as an acceptable, successful method for repairing corroded and mechanically-damaged onshore pipelines where the primary load is internal pressure. The feasibility of extending these repairs to offshore pipes such as risers require a thorough understanding of the complex combined load profiles; overlay of significant tension, bending, internal and external pressure. Herein an innovative design based on integrated computational models and full-scale tests is presented to address the viability of reinstating capacity to offshore pipelines and risers. The experimental program was based on a collaborative test matrix developed with the participation of composite repair manufacturers. The outcome guided and led to an easily deployable carbon–fiber composite repair system which was based on limit analysis methods and strain-based design techniques. It is anticipated that the results of this program will foster future investigations by integrating operator’s insight and in situ data gathering to extend composite repair for offshore needs.     

The stabilization of bisphenol‐A based polycarbonate by phosphine oxide

A Bisphenol‐A based polycarbonate was stabilized by a new polymer stabilizer named di(p‐butoxyphenyl)cyclohexylphosphine oxide. The stabilizer was mixed with the polymer in methylene chloride solution. Later, the solution was vaporized and the stabilized polymer was dried. Specimens were cut and heat treated at different temperature and durations. Small amounts of stabilizer enhanced the breaking strength and elongation at break properties of as molded and heat treated polycarbonate. The modulus of elasticity reduced with stabilization. The stabilizer had a plasticizing effect too. At high stabilizer rates (c > 1%) both thermal and mechanical properties were deteriorated. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010