Theoretical Prediction of Chiral 3D Hybrid Organic–Inorganic Perovskites

Hybrid organic–inorganic perovskites (HOIPs), in particular 3D HOIPs, have demonstrated remarkable properties, including ultralong charge‐carrier diffusion lengths, high dielectric constants, low trap densities, tunable absorption and emission wavelengths, strong spin–orbit coupling, and large Rashba splitting. These superior properties have generated intensive research interest in HOIPs for high‐performance optoelectronics and spintronics. Here, 3D hybrid organic–inorganic perovskites that implant chirality through introducing the chiral methylammonium cation are demonstrated. Based on structural optimization, phonon spectra, formation energy, and ab initio molecular dynamics simulations, it is found that the chirality of the chiral cations can be successfully transferred to the framework of 3D HOIPs, and the resulting 3D chiral HOIPs are both kinetically and thermodynamically stable. Combining chirality with the impressive optical, electrical, and spintronic properties of 3D perovskites, 3D chiral perovskites is of great interest in the fields of piezoelectricity, pyroelectricity, ferroelectricity, topological quantum engineering, circularly polarized optoelectronics, and spintronics.     

Portable system for data acquisition and transmission based on handheld PC technology

A portable system is developed to monitor physical activity by acquiring and storing data from body-mounted sensors; a handheld PC is used for managing data acquisition and storage, including radio-transmission to a remote host. An application related to the use of a gyro-accelerometric sensor for determining walking distance is discussed.     

Nitrogen addition to iron powder by mechanical alloying

Nitrogen was alloyed into iron (a) by mechanical processing in a nitrogen gas environment, and (b) by mechanically alloying with iron-nitride powders to characterize resulting nano-structure and nitrogen distribution. Although the infused nitrogen concentration was significantly greater than the thermodynamic equilibrium solubility of iron, no nitrides formed, even for nitrogen concentrations as high as 4.1 wt.% However, a bctFe phase did form. Lattice expansion calculations indicate that the sum of the interstitial bcc-Fe and bctFe nitrogen concentrations was significantly less than the total measured nitrogen concentration. A considerable portion of the mechanically infused nitrogen was determined to be associated with nanograin boundaries.     

A behavioral probe of the growth of intake potential during the inter-meal interval in the rat.

The rat's willingness to ingest glucose after an initial intraoral intake test was probed by beginning a 2nd intraoral intake test at variable durations (1–220 min). In Exp 1, after an initial meal of 12.5% glucose solution averaging 26.9?±?1.7 ml, the size of the 2nd (probe) meal of the same stimulus increased linearly from 4.0?±?0.9 ml after a 1-min delay to 15.4?±?2.7 ml after a 120-min delay. In Exp 2, intraoral intake of a more concentrated (37.5%) glucose solution rose more slowly as a function of delay from 2.4?±?2.7 ml to 4.9?±?0.6 ml. For each glucose concentration, the linear recovery function and a slope that depends on stimulus concentration are consistent with a role for gastric emptying during the delay in intake recovery. In Exp 3, rats ingested 12.5% or 37.5% glucose to satiety in an initial test and received, after a variable delay, either the same or the other concentration as the probe stimulus. The same volumes were ingested at each delay whether the glucose concentration of the probe stimulus was the same or was switched from that presented in the initial test. This result shows that the taste and caloric properties of the probe stimulus played no role in determining how much of it would be ingested… (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Effect of melt spinning on the microstructure and mechanical properties of three Ni-base superalloys

A microstructural and mechanical analysis was performed on three rapidly solidified nickel base superalloys. Transmission and scanning electron microscopy along with tensile tests were performed on the ribbons in the as-cast and aged condition. This investigation permitted a correlation to be made between cooling rate, microstructure, and mechanical properties. It was found that melt spinning significantly altered the physical characteristics of the alloys studied. The rapid cooling rates (∼10⁷ K/s) produced ribbons with a low dislocation density and small (∼1 μm) low angle cells. The precipitation of γ′ was suppressed, producing alloys with a smaller volume fraction of precipitates and lower APBE than in the conventionally cast condition. Also, the matrix/precipitate lattice mismatch was higher in the melt spun foils. Tensile strengths were similar to those in the conventional form; however, no measurable ductility was present. Aging the ribbons resulted in increases in γ′ volume fraction, tensile strengths, APBE, and elongations compared to the as-cast ribbons. The results of this work suggest that many of the microstructural refinements produced by melt spinning are lost after a short aging time at moderate temperatures.     

Behavioral preferences in response to social injustice: The effects of group permeability and social identity salience.

Examined features of an intergroup context that can affect people's preferred responses to a situation of social injustice. 90 undergraduates were randomly assigned to 1 of 3 conditions of group permeability (open, token, or closed) and 1 of 2 conditions of social identity salience (not salient or salient). It was predicted on the basis of social identity theory that individualistic responses would be preferred to a collective response when group boundaries were more open but not when they were closed. It was also expected that under conditions of group impermeability, collective behavior would be preferred to a greater extent by individuals for whom social identity was salient than by individuals for whom it was not salient. The results, which generally supported these hypotheses, are discussed in terms of social psychological theories of intergroup relations and also with regard to their potential practical implications. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Magnetic resonance features of supravalvular aortic stenosis in William''s syndrome. Report of 2 cases

A wandering spleen and splenic cysts are uncommon conditions in children. A combination of both entities has only rarely been reported in the literature. Another case of this complex pathology in 12-year-old girl is presented. She was initially referred for evaluation of a large abdominal mass. Diagnostic studies raised the suspicion of a hematoma in an abnormally located spleen, but the definitive diagnosis was established at laparotomy. Successful surgical management consisted of total cystectomy and splenopexy.     

Low-cost, redundant proximity sensor system for spatial sensing andcolour perception

The authors describe their approach to the design of redundant proximity sensor systems that are capable of extracting geometrical information about the surrounding environment and perceiving other relevant features of the reflecting objects, e.g. colour. Potential applications of the proposed sensorial systems are in the field of robotics and autonomous mobility     

SPATIAL AND VISUAL REASONING: HUMANS VERSUS LOGIC

Glasgow's revival of the "imagery debate" in computational terms provides a renewed opportunity to review the role of logical reasoning in general problem solving. Of special interest is the long-standing distinction between analogical or depictive problem representations, and the more abstract linguistic forms typified by traditional formal logic syntax.
In our brief statement, we recall that logical reasoning rests on semantics not syntax, and that the concepts of soundness, completeness, and consistency are manifest in both depictive and linguistic representations. We emerge with two conclusions: (1) enduring confusion regarding computational aspects of the "imagery debate" arise from long-standing confusion regarding key logical concepts, and related notions such as epistemological versus heuristic adequacy, logical versus probabilistic independence, and direct versus indirect representations; (2) the desire for depictive reasoning methods is ultimately motivated by human needs, not computational needs.