Maximum power density for an endoreversible carnot heat engine

An analysis using maximum power-density criteria has been carried out for an endoreversible Carnot heat engine. The results have been compared with known results on maximum power analysis. The design parameters at maximum power density lead to smaller and more efficient endoreversible Carnot heat engines than those working at maximum power output.     

Degradation of 4-chloro-2-methylphenol in aqueous solution by electro-Fenton and photoelectro-Fenton processes

Degradation of 4-chloro-2-methylphenol (PCOC), a refractory toxic chemical emitted to the environment from the industrial production of phenoxy herbicides was studied in aqueous solution. Electro-Fenton and photoelectro-Fenton processes were used as the degradation methods. H₂O₂, produced by the reduction of oxygen at carbon cathode reacted with dissolved metal ions to form hydroxyl radicals, which in turn reacted with PCOC sequentially to degrade the aromatic ring. The effects of using different [Fe²⁺]/[PCOC]₀ and the effect of replacing Fe²⁺ by Mn²⁺ ion have been examined. It was found that degradation rate was increased with increasing [Fe²⁺]/[PCOC]₀ ratio from 2 to 4. However, the total charge utilized during the treatment was also increased. The efficiency of PCOC degradation was observed to be higher when Mn²⁺ was used as the catalyst. The mineralization of aqueous solutions of PCOC, withdrawn from the reactor at certain time interval, has been followed by total organic carbon (TOC) decay and dechlorination. A fast and complete degradation of the aromatic ring was achieved in photoelectro-Fenton system. 41.7% TOC decay and complete dechlorination were observed by consuming only 141.4 C electrical charge during a 300 min photoelectron-Fenton treatment. In the case of electro-Fenton system, 280.7 C electrical charge was consumed during 450 min of electrolysis to attain a similar degradation of PCOC. 14.9% TOC removal and 89.3% dechlorination have been obtained in this system under the applied conditions.     

Antibody purification by concanavalin A affinity chromatography

Concanavalin A (Con A) immobilized poly(2‐hydroxyethyl methacrylate) (PHEMA) beads in a spherical form (100–150 μm in diameter) were used for the affinity chromatography purification of human immunoglobulin G (IgG) from aqueous solutions and human plasma. PHEMA adsorbents were prepared by suspension polymerization. Bioligand Con A was then immobilized by covalent binding onto PHEMA beads. The maximum IgG adsorption on the PHEMA/Con A beads was observed at pH 6.0. The nonspecific IgG adsorption onto the plain PHEMA adsorbents was very low (ca. 0.17 mg/g). Higher adsorption values (up to 54.3 mg/g) were obtained when the PHEMA/Con A beads were used from aqueous solutions. A higher adsorption capacity was observed for human plasma (up to 69.4 mg/g) with a purity of 82.5%. The adsorption capacities of other blood proteins were 2.0 mg/g for fibrinogen and 4.2 mg/g for albumin. The total protein adsorption was determined to be 76.0 mg/g. IgG molecules could be repeatedly adsorbed and desorbed with the PHEMA/Con A beads without noticeable loss in the IgG adsorption capacity. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 1202–1208, 2005     

Fuzzy FMEA application to improve purchasing process in a public hospital

Failure mode and effects analysis (FMEA) is one of the well-known techniques of quality management that is used for continuous improvements in product or process designs. While applying this technique, determining the risk priority numbers, which indicate the levels of risks associated with potential problems, is of prime importance for the success of application. These numbers are generally attained from past experience and engineering judgments, and this way of risk assessment sometimes leads to inaccuracies and inconsistencies during priority numbering. Fuzzy logic approach is preferable in order to remove these deficiencies in assigning the risk priority numbers. In this study, a fuzzy-based FMEA is to be applied first time to improve the purchasing process of a public hospital. Results indicate that the application of fuzzy FMEA method can solve the problems that have arisen from conventional FMEA, and can efficiently discover the potential failure modes and effects. It can also provide the stability of process assurance.     

Fair referee assignments for professional football leagues

Assignment of referees to football games is an important problem faced in professional football leagues. Despite its importance, the problem has received limited academic attention. This paper presents a model and analysis of the problem for fair referee assignments, and develops a constructive heuristic and a local search procedure for its solution. Results from an extensive computational study show that the methods are effective in solving the problem in a second of computation time and yielding an excellent solution quality.     

Throughput performance of automated storage/retrieval systems under stochastic demand

In this paper we are concerned with the throughput performance of an Automated Storage/Retrieval (AS/R) system under stochastic demand, i.e., the case where storage and retrieval requests arrive randomly. Although AS/R systems have been the subject of extensive research, their performance under stochastic demand remains relatively unexplored. In fact, with random storage and retrieval requests, the primary tool for AS/R system analysis has been simulation. Assuming a particular dwell point strategy for the storage/retrieval machine, in this paper we derive closed-form analytical results to evaluate the performance of an AS/R system under stochastic demand and determine whether or not it meets throughput. Although the results are derived for a given system, they can also be used in the design or evaluation of new/proposed systems.