Diporphyrin tweezer for multichannel spectroscopic analysis of enantiomeric excess

Chiral 1,1’-binaphthyl-linked diporphyrin ‘tweezers’ (R)-1/(S)-1 and the corresponding zinc(II) complexes (R)-2/(S)-2 were prepared as chiral host molecules, and their utility for chiral analyses (especially enantiomeric excess (ee) determinations) were evaluated. Tris(1-n-dodecyl)porphyrins were used for the first time as the interacting units. Host capabilities of the diporphyrin tweezers were investigated by titrations with (R,R)- and (S,S)-cyclohexane-1,2-diamine (CHDA). The host molecules could be used as multichannel probes of ee by using UV-vis, circular dichroism (CD), fluorescence emission and ¹H nuclear magnetic resonance (¹H-NMR) methods. Chiral configurations could also be differentiated using CD or ¹H-NMR spectroscopy. All three optical techniques give good resolution of ee with reasonable sensitivity considering the low concentrations used (ca. 10⁻⁶ mol·L⁻¹). The ee determination of CHDA enantiomers using NMR spectroscopy is also possible because of the reasonably well separated resonances in the case of (R,R)- and (S,S)-CHDA. Non-metallated (R)-1/(S)-1 hosts could not be used to detect chiral information in a strongly acidic chiral guest. This work demonstrates the utility of 1,1’-binapthyl-linked chiral hosts for chiral analysis of ditopically interacting enantiomers.     

Strain rate dependency and fragmentation pattern of expanding warheads

For the characterization of the behaviors of a metal material in events like expanding warheads, it is necessary to know its strength and ductility at high strain rates, around 104e105/s. The flyer plate impact testing produces the uniform stress and strain rates but the testing is expensive. The Taylor test is relatively inexpensive but produces non-uniform stress and strain fields, and the results are not so easily inferred for material modeling. In the split-Hopkinson bar(SHB), which may be used in compression, tension and torsion testing, the strain rates never exceeds 103/s. In the present work, we use the expanding ring test where the strain rate is 104e105/s. A streak camera is used to examine the expanding ring velocity, and a water tank is used to collect the fragments. The experimental results are compared with the numerical simulations using the hydrocodes AUTODYN, IMPETUS Afea and a regularized smooth particle(RSPH) software. The number of fragments increases with the increase in the expansion velocity of the rings. The number of fragments is similar to the experimental results. The RSPH software shows much the same results as the AUTODYN where the Lagrangian solver is used for the ring. The IMPETUS Afea solver shows a somewhat different fragmentation characteristic due to the node splitting algorithm that induces pronounced tensile splitting.     

Critical parameters near the ferromagnetic-paramagnetic phase transition in La0.67–xYxBa0.23Ca0.1MnO3 compounds（x=0.10 and x=0.15）

The critical properties of the mixed manganite La0.67–x Y x Ba0.23Ca0.1Mn O3 with x=0.10 and x=0.15 around the paramagnetic(PM)-ferromagnetic(FM) phase transition were investigated through various techniques. These involved modified Arrott plots, Kouvel-Fisher method and Widom scaling relation. Magnetic data, analyzed in the critical region, using the above methods, yielded the critical exponents for(x=0.10) La0.57Y0.10Ba0.23Ca0.1Mn O3(β=0.312±0.002 and γ=1.147±0.003 at T C=299.23±0.05 K). Moreover, the estimated critical exponents of(x=0.15) La0.52Y0.15Ba0.23Ca0.1Mn O3 were β=0.286±0.004 and γ=0.943±0.002 at T C=289.53±0.06 K. The critical exponents’ values were close to the theoretical values of 3D-Ising model and tricritical mean-field model. These results suggested that the present composition should be close to a tricritical point in the La0.67–x Y x Ba0.23Ca0.1Mn O3 phase diagram. Expressing the field dependence as ΔS M∝H n allowed us to establish a relationship between the exponent n and the critical exponents of the material and to propose a phenomenological universal curve for the field dependence of ΔS M.     

High Temperature Property Development of Bauxite Based Bricks

Physical properties and microstructural evolution on firing of 3 types of bauxite based refractory bricks were carried out using techniques such as porosimetry,XRD and SEM.The groups differed from each other by progressive refining of the matrix or bond phase.It is revealed that such a refinement of the matrix can improve the high temperature properties of the bricks made from poor grade materials.     

锡

回顾1987年,只能说锡工业解决了几个问题。锡危机引起的正在进行的法院诉讼事件被拖延着,没有取得任何的积极结果,这一年的锡价没有改善並在新的规定下恢复锡的出口限额。这一年是整个锡工业仔细地检验其经营,並使计划比以前更适应将来的要求。“合理化”是一个关键词,因为各公司竭力维持经营並使其有利可图。     

DIRECT RESONANCE OF TURBULENT BOUNDARY LAVER OVER COMPLIANT WALLS

１．　ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｍａｉｎｇｏａｌｏｆｔｈｉｓｐａｐｅｒｉｓｔｏｅｘｐｌｏｒｅｔｈｅｐｏｓｓｉｂｉｌｉｔｙｔｏｌｅａｒｎｍｏｒｅａｂｏｕｔｔｈｅｍｅｃｈａｎｉｓｍｏｆｔｕｒｂｕｌｅｎｔｂｏｕｎｄａｒｙｌａｙｅｒｆｌｏｗｉｎｔｅｒａｃｔｉｏｎｓａｎｄｉｔｓｅｆｆｅｃｔｓｏｎｃｏｍｐｌｉａｎｔｗａｌｌｐｅｒｆｏｒｍａｎｃｅ．Ｔｈｅｒｅａｒｅｃｅｒｔａｉｎｐｒｅｒｅｑｕｉｓｉｔｅｃｏｎｄｉｔｉｏｎｓｔｏｆｕｒｔｈｅｒｔｈｅｓｔｕｄｙｏｎｔｈｅｍｅｃｈａｎｉｓｍ，ｉ．ｅ．ｔｈｅｃｏ…     

摩托罗拉8位HC08微控制器系列

摩托罗拉微控制器(MCU)具有编程语言简单、外围设备齐全、存储器模型用户友好、选择广及供应多、性能价格比高等优点,被设计者评为最容易使用的产品之一。在全球顶级的原始设备制造厂商(OEM)的无数嵌入式系统和用户最终产品中都可找到摩托罗拉的MCU,包括键盘、传呼机、电子游戏机、洗衣机、安全系统及汽车等。     

在金(Ⅲ)-溴化物-罗丹明6G体系中高灵敏浮选分光光度法测定金

本文叙述了在金(Ⅲ)-溴化物-罗丹明6G(R6G)体系中高灵敏浮选分光光度法测定微量金。在溴存在下,形成R6G-Br二溴衍生物。金的化合物用二异丙醚浮选,用1M(mol/L)硫酸洗涤浮选物,并将其溶解在甲醇中。在545nm处测量溶液的吸光度。此浮选化合物被认为是一种加合物,其化学式为[(R6G-Br~+)(AuBr_4~-)]·12[(R6G-Br_3~+)(Br_3~-)]。表现摩尔吸光系数为11.4×10~51·mol~(-1)·cm~(-1)。严重干扰的元素有Pd,Ag,Hg(Ⅱ)和Tl(Ⅲ)。金从酸性溴化物介质中萃取到二异丙醚后,仅Tl(Ⅲ)严重干扰。本文提出的方法可应用于测定泡铜样品中的痕量金。结果表明,该法的精密度和准确度较好。     

亚洲电力改革:孰是孰非?

电力市场化是全球电力工业都在热烈讨论和积极探索的热点课题 ,在中国电力市场化改革的今天 ,尤其具有重要的理论和实践意义。 2 0 0 2年 5月 1 3日至 1 8日 ,由清华港大深圳电力系统研究所主办的“电力市场新进展高级研讨会”在深圳清华大学研究院举行。在研讨会上 ,与会专家分别就电力市场研究和实践中的若干问题发表了演讲。本刊将主要内容摘录、汇编成文 ,奉献给大家 ,以便广大读者对电力市场的研究动态有比较全面的了解。在此 ,衷心感谢参加“电力市场新进展研讨会”的各位专家给予的大力支持和帮助 ,特别感谢香港大学 /浙江大学文福拴博士、香港大学严正博士在本文的摘编过程中提供的技术指导和具体帮助。     

以蔗糖作可再生的化工原料

蔗糖化学工业的出现要从有机化工原料(石油和煤)的成本急升来考虑,能源价格飞涨而世界糖价却徘徊于不经济的基线与暂时的高价之间,跟着的是不可预见的产量不足。正如目前那样,如果糖能打进食品以外的市场,那么这一可供补充和有保证的需求将会刺激增加糖产量的投资,而且可以避免一定时期会出现的糖过剩引起的不景气后果。