Base alumina ceramics with dispersoids: mechanical behaviour and tissue response afterin vivo implantation

Base alumina ceramics with dispersoids (BAC) are a new class of ceramics with improved mechanical properties as compared to pure alumina. They are obtained by dispersion of powder within an alumina matrix. Of the three new ceramics studied here, A20Z possesses the best mechanical properties as well as tribological properties superior to those of pure alumina whether it is used in ceramic-ceramic or ceramic-polyethylene combination.Mechanical behaviour and tissue response afterin vivo implantation were studied. Small four-point flexion bars obtained by pressureless sintering were implanted subcutaneously in the rat. The mechanical properties were unmodified even after one year from implantation.The tissue response was studied up to one year on cylinders implanted in the paravertebral muscles of Wistar rats, and was evaluated by qualitative examination of the encapsulating membrane and measurement of its thickness in relation to pure alumina. The tissue responses were comparable for both alumina and the three tested ceramics.     

Preparation of Crystalline Aluminum Phosphate by the Reaction Using Boron Phosphate

The use of BPO₄ in the synthesis of crystalline AlPO⁴ has been investigated. The best results are obtained if BPO₄ and hydrated alumina are heated in molten KCl: at 1050°C the conversion degree of BPO₄ into AlPO⁴ is >90% (in 4 h). The product consists of the tridymite AlPO⁴ form.     

CAD based shape optimization for gas turbine component design

In order to improve product characteristics, engineering design makes increasing use of Robust Design and Multidisciplinary Design Optimisation. Common to both methodologies is the need to vary the object’s shape and to assess the resulting change in performance, both executed within an automatic loop. This shape change can be realised by modifying the parameter values of a suitably parameterised Computer Aided Design (CAD) model. This paper presents the adopted methodology and the achieved results when performing optimisation of a gas turbine disk. Our approach to hierarchical modelling employing design tables is presented, with methods to ensure satisfactory geometry variation by commercial CAD systems. The conducted studies included stochastic and probabilistic design optimisation. To solve the multi-objective optimisation problem, a Pareto optimum criterion was used. The results demonstrate that CAD centric approach enables significant progress towards automating the entire process while achieving a higher quality product with the reduced susceptibility to manufacturing imperfections.     

An investigation of the usability of image-based CAPTCHAs using PROMETHEE-GAIA method

Multimedia Tools and Applications - Today, it is difficult to find an adequate Web site with a registration form that is not protected with some automated human proof test. One of the oldest...     

Shear bond strength to dentine of dental adhesives containing hydroxyapatite nano-fillers

The aim of this study was to compare the effect of hydroxyapatite (HAP) nano-rods (HAP_rods) and HAP nano-sticks (HAP_sticks) added to commercial adhesives on the macro-shear bond strength (SBS) to dentine and morphology of the adhesive–dentine interface. HAP was added to Single Bond Universal (SBU, 3M ESPE) and Te-Econom Bond (TeE; Ivoclar Vivadent), in the form of water suspensions to avoid agglomeration of nano-particles and to achieve HAP concentrations of 0.5, 1.0 and 1.5 wt%. Following a ‘total-etch’ or a ‘self-etch’ protocol, the adhesives were applied to flat dentine surface of 162 intact human, third molars (N = 6/group). Composite (Z250, 3M ESPE) was built-up using a split stainless steel mould, 3 mm in diameter. SBS was tested using a universal testing machine at 1 mm/min until fracture. Data were statistically analysed using two-way and one-way analysis of variance with Tukey’s post-test (α = 0.05). HAP_rods had no significant effect on SBS of the tested adhesives while HAP_sticks improved bond strength to dentine only of adhesives applied following the ‘total-etch’ total-etch protocol. SBS values of SBU containing 1% HAP_sticks (15.10 ± 2.96 MPa) and TeE containing 0.5% HAP_sticks applied following the total-etch protocol (12.96 ± 4.48 MPa) were higher than those of their respective control groups (10.36 ± 2.68 and 7.97 ± 3.64 MPa). Samples with higher SBS showed more ‘mixed’ failures. HAP nano-fillers may improve bond strength of total-etch adhesives without an adverse effect on adhesive dispersion on dentine and its ability to infiltrate dentinal tubules.     

The dependence of the photocatalytic activity of TiO2/carbon nanotubes nanocomposites on the modification of the carbon nanotubes

Nanostructural TiO₂/modified multi-wall carbon nanotubes photocatalysts were prepared by hydrolysis of Ti(iso-OC₃H₇)₄ providing chemical bonding of anatase TiO₂ nanoparticles onto oxidized- or amino-functionalized multi-wall carbon nanotubes (MWCNT). The processes of functionalization of the MWCNT and the deposition of TiO₂ influence the photocatalytic activity of the synthesized nanocomposites. The phase composition, crystallite size, and the structural and surface properties of the obtained TiO₂/modified-MWCNT nanocomposite were analyzed from XRD, FEG-SEM, TEM/HRTEM and FTIR data, as well low temperature N₂ adsorption. In the photocatalytic study, the TiO₂/oxidized-MWCNT catalyst showed the highest and the TiO₂/amino functionalized-MWCNT catalysts somewhat lower degradation rates, indicating that the enhancement of photocatalysis was supported by the more effective electron transfer properties of the oxygen- than amino-containing functional groups, which support the efficient charge transportation and separation of the photogenerated electron-hole pairs.     

Windowing Design Method for Polynomial-Based Interpolation Filters

An efficient implementation for finding digitally the interpolated samples is the Farrow structure. It mimics digitally a hybrid system where a continuous-time (CT) signal is reconstructed using an analog reconstruction filter having a piecewise-polynomial impulse response. The interpolated samples are obtained by sampling reconstructed signal. This paper introduces a generalized design method for polynomial-based interpolation filters and Farrow structure. The proposed method also can be used to calculate the coefficients of Selva interpolator. In this approach, the ideal CT impulse response is truncated by using CT window functions. The obtained windowed impulse response is then approximated using the piecewise Taylor polynomial approximation. Length of the impulse response and degree of the approximating polynomial can be arbitrarily selected, and in this way the transition band width can be controlled. However, if CT fixed-window functions are used, the stopband attenuation is determined by window type and remains approximately constant with increase of length and order of the impulse response. The stopband attenuation can be controlled by using CT dynamic windows such as Kaiser window. The presented windowing design method is an effective tool for calculation of the Farrow structure coefficients, with filter performance that is comparable to the frequency domain design.     

Synthesis and characterization of monetite and hydroxyapatite whiskers obtained by a hydrothermal method

High temperature hydrothermal syntheses, using calcium nitrate tetrahydrate, sodium dihydrogen phosphate and urea as precursors, and characterization of hydroxyapatite (HAp) whiskers are reported herein. The morphology and chemical composition of the crystals from a monetite to a hydroxyapatite phase were controlled by varying the starting concentrations of the precursors and the solution pH through the amount of urea that is decomposed during heating. X-ray diffraction (XRD) analysis, infrared spectroscopy (IR), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM) and high-resolution TEM (HRTEM) were used to investigate the products of the syntheses in order to find the optimum reaction conditions for obtaining the desired morphology and phase composition. Different morphologies ranging from single crystals of monetite through rods and plates of hydroxyapatite with different size distribution to whisker-like single hydroxyapatite crystal were achieved by simply varying the starting concentration of urea. Structural refinement of the hydroxyapatite whiskers confirmed a strong preferential orientation along the c-axis direction of the hexagonal crystal structure, which was significantly different from the usually observed random crystal orientation. TEM and SEM analysis of the apatite whiskers confirmed single crystal structure with the a c-axis orientation parallel to the long axis of the whiskers, with sizes up to 150 μm in length, 10 μm in width and with a thickness of about 300 nm, that grew from the same centre of nucleation, forming flaky-like particles.     

Microflow-based control of near-wall fluctuations for large viscous drag reduction

The stabilizing effect of microgroove surface morphology on viscous drag reduction was studied experimentally in the inlet region of a plane channel flow. The stabilization is thought to be due to the ability of a microgrooved surface pattern to suppress the velocity fluctuations in the spanwise direction on a restricted portion of the wetted surface, which prevents vorticity development at the wall and consequently across the entire flow field. This smart microflow control strategy, which works successfully only under very particular circumstances, was implemented in a microgroove-modified channel flow in which the front part has a microgrooved surface topology. The results of pressure drop measurements indicate that microgrooved surfaces can effectively stabilize laminar boundary layer development, leading to a significant reduction in the viscous drag. In the rear flat part of the microgroove-modified channel test section, a maximum drag reduction of DR @ 35%{\rm DR\simeq 35\%} was measured. This corresponds to an overall drag reduction of DR @ 16%{\rm DR\simeq 16\%} at a length Reynolds number of Re_x @ 10⁶.Re_x\simeq 10^6. The drag reduction effect persisted in a narrow range of flow velocities and for the reported experimental conditions corresponds to microgroove dimensions between 1.5 and 2.5 viscous length-scales.     

Efficient CAD-based triangulation of unordered 3D data

Abstract. The paper proposes a new method for efficient triangulation of large, unordered sets of 3D points using a CAD model comprising NURBS entities. It is primarily aimed at engineering applications involving analysis and visualisation of measured data, such as inspection, where a model of the object in question is available. Registration of the data to the model is the necessary first step, enabling the triangulation to be efficiently performed in 2D, on the projections of the measured points onto the model entities. The derived connectivity is then applied to the original 3D data. Improvement of the generated 3D mesh is often necessary, involving mesh smoothing, constraint-based elimination of redundant triangles and merging of mesh patches. Examples involving random measurements on aerospace and automotive free-form components are presented. Received: 30 August 1999 / Accepted: 10 January 2000