制粉工艺对贮氢合金电化学性能的影响研究

研究了干法、湿法和湿法加添加剂三种制粉工艺对贮氢合金电化学性能的影响 ,结果表明 :制粉工艺对合金粉末的表面形貌、粒度分布、氧含量均存在很大的影响 ,并影响到其电化学性能。当采用湿法制粉工艺时 ,贮氢合金电极的活化性能较干法制粉明显改善 ,若加入一定量的添加剂 ,活化性能进一步提高 ,第一次放电容量即达到2 78mAh·g-1,第二次放电容量达到合金电极的稳定容量 32 2mAh·g-1。湿法制粉对贮氢合金电极的循环稳定性能有一定的负面影响 ,这可能与贮氢合金粉末表面的氧化和细粉相对含量较多有关 ,然而 ,当加入一定量的添加剂以后 ,贮氢合金电极的氧含量得到有效的控制 ,3C充放循环稳定寿命达到 5 0 0次 ,与干法制粉工艺接近。     

Charge-discharge process of MnO2 supercapacitor

Mechanochemical synthesis of α-MnO2 was carried out with KMnO4 and Mn（CH3COO）2 in 1：1 mole ratio. The electrochemical performance of MnO2 electrode was investigated by cyclic voltammograms and alternating current impedance. The charge-discharge process of MnO2 supercapacitor in 6 mol/L KOH was studied within 1.2 V at 200 mA/g, suggesting that it displays double-layer capacibility in low potential scope and pseudo-capacitance properties in high potential scope. It is found that Mn3O4, an electrochemical inert, mainly forms in the initial 40 charge-discharge cycles. During cycling, the pseudo-capacitance properties disappear and the discharge curves are close to ideal ones, indicating double-layer capability. The maximum capacitance of MnO2 electrode is as high as 416 F/g, and retains 240 F/g after 200 cycles. The equivalent series resistance increases from 17 to 41Ω.     

Performance of positive and negative electrodes in amorphous manganese oxide supercapacitor

Using potassium permanganate and acetic manganese as the reactants, amorphous manganese oxide was prepared with mechanochemical method. XRD was used for microstructure characterization, while cyclic voltammetry and constant current charge-discharge were used for electrochemical performance testing. The positive electrode （PE） and negative electrode （NE） were investigated respectively in amorphous manganese oxide supercapacitor, aiming to find their different performances in charging-discharging. The results show that the crystalline structure is destroyed in both the PE and NE material during charge-discharge process. Thereinto, the NE suffers a bit more seriously. When cycling, the PE potential scope diminishes while the NE potential scope enlarges. The increased inner resistance makes the NE curves almost bended to be a right angle, but not the PE curves. The cell＇s equivalent series resistance （ESR） is more dependent on the NE, and the capacitance is mainly determined by the rapid descent of the NE potential range. The capacitances of the NE are highly rate-dependent, decreasing from 121.3 to 53.1 F/g, by 56.2%, over the range of 5-25 mV/s. However, the PE appears to be weakly dependent and its capacitance is only dropped by 22.1%.     

20T锻造操作机钳杆虚拟样机的仿真研究

锻造操作机主要用来夹持锻件并对其进行送进、旋转、升降等操作,配合锻造主机完成锻造任务.本文对钳杆旋转结构进行研究,并建立了满足控制要求的钳杆旋转机械模型与电比例泵控液压控制系统的模型.最后对基于虚拟样机的锻造操作机钳杆机液系统进行联合仿真分析.     

相拥Internet——WebRamp M3试用印象

初识WebRamp M3是在一则广告上,诸如“最省钱、最省事”的宣传词让我们砰然心动。当时我们正在为《中国计算机用户》杂志社局域网如何通过Modem上Internet网苦苦寻觅方案。面对新的产品,我们当然不能错过。 由同天科技有限公司总代理的WebRamp M3产品是一个外形非常小巧的硬件设备,它允许局域网用户通过Modem使用个人帐号共同访问Internet。与目前市场上的代理服务器软件(如WinGate)相比,该产品颇具个性和特色。M3是适合小型公司、比较合理且行之有效的Internet上网方案。     

AlF3包覆锂离子电池正极材料Li1.2(Mn0.54Ni0.16Co0.08)O2的制备、表征及电化学性能（英文）

采用溶胶-凝胶法合成锂离子电池正极材料Li1.2(Mn0.54Ni0.16Co0.08)O2,并用Al F3对这种材料进行表面包覆改性。采用X射线衍射(XRD)、扫描电子显微镜(SEM)、高分辨率透射电子显微镜(HRTEM)等表征材料的结构和形貌。结果表明,合成的Li1.2(Mn0.54Ni0.16Co0.08)O2具有典型的层状α-Na Fe O2结构,AlF3均匀包覆在Li1.2(Mn0.54Ni0.16Co0.08)O2材料表面,包覆层厚度为5~7 nm。电化学测试表明,包覆Al F3后材料的电化学性能得到提高,在1C倍率下,包覆的AlF3材料的首次放电容量为208.2 m A·h/g,50次循环后容量保持率为72.4%,而未包覆AlF3的材料的首次放电容量和容量保持率分别为191.7 m A·h/g和51.6%。     

氨厂用甲醇弛放气作Co—Mo床加氢脱敢源

对合成近装置回收甲醇弛放气进行了分析和总结，提出氨装置回收甲醇弛放气不存在任何危害，并指出回收过程中应注意的问题。     

英国LH-1300H掘进机泵站及液压系统技术改造

针对英国LH 130 0H掘进机在使用过程中存在的问题进行分析、研究及核定 ,用国产配件替代进口配件 ,简化调整液压系统 ,提高配件自给率 ,以保证正常生产 ,节约外汇 ,提高经济效益     

成功“伴侣”之二——BusinessObjects4.1

数据无限,信息有限。如何从洁瀚无边的企业数据中获取有价值的信息?数据仓库及其决策支持工具为此提供了解决之道。继上期推出PLATINUM公司的决策支持工具之后,本刊技术评测部特向大家推荐:     

二氧化锰电容材料的制备及性能表征

采用机械化学法制备了高比容量MnO2电容材料,考察了高锰酸钾与乙酸锰配比对样品结构及电化学性能的影响。用XRD、BET等方法对材料的结构进行了表征;用循环伏安、交流阻抗、恒电流充放电等方法分别研究了MnO2电极和超级电容器在6mol／LKOH水系电解液中的电化学性能。结果表明,原料中高锰酸钾含量越多,产物比表面积越大,表现出弱结晶性;当原料物质的量配比为1：1时,所得样品为385m^2／g的无定型MnO2,其电极最大放电容量达到了536F／g。