Fabrication of direct Z-scheme FeIn2S4/Bi2WO6 hierarchical heterostructures with enhanced photocatalytic activity for tetracycline hydrochloride photodagradation

A series of direct Z-scheme FeIn₂S₄/Bi₂WO₆ hierarchical heterostructures with intimate interface contacts were synthesized by in-situ growth route and characterized by systematical analyses. All as-prepared FeIn₂S₄/Bi₂WO₆ nanocomposites showed significantly enhanced photocatalytic activity towards photodegradation for the removal of tetracycline hydrochloride (TCH) in comparison with individual FeIn₂S₄ and Bi₂WO₆. Meanwhile, the highest photocatalytic degradation activity can be achieved by modulating adding amount of FeIn₂S₄ in FeIn₂S₄/Bi₂WO₆ nanocomposites and the optimized component ratio of FeIn₂S₄ to Bi₂WO₆ is determined to be 10 wt%. The enhanced photocatalytic activity could be ascribed to efficient separation between photogenerated holes and electrons based on the construction of direct Z-scheme system. The high photocatalytic stability of resultant 10 wt% FeIn₂S₄/Bi₂WO₆ nanocomposites was revealed through six successive recycling reactions. The main intermediate generated during TCH photodegradation was explored by HPLC-MS. Besides, the direct Z-scheme photocatalytic mechanism was confirmed by band position analysis, electron spin resonance (ESR) and active species capture experiment.     

深孔薄壁件挤压模CAD系统

介绍了利用ActiveXAutomation技术，以VB为开发工具，并采用参数化绘图研究开发的深孔薄壁件挤压模CAD系统。     

Design consideration of photocatalytic oxidation reactors using TiO2-coated foam nickels for degrading indoor gaseous formaldehyde

In the design process of the photocatalytic oxidation (PCO) reactor using TiO₂-coated foam nickels, the optimum of catalyst film thickness, light intensity and flow velocity were considered. A model was developed to study the effect of catalyst film thickness on photocatalytic degradation of formaldehyde by a TiO₂-coated foam nickel at continuous flow mode. In this model, external mass transfer and internal molecule diffusion-reaction were considered. A first-order kinetics equation was used to account for the photocatalytic reaction. Two exponential equations were employed to describe the distribution of light intensities in foam nickels and catalyst films, respectively. Validated with experimental data, the model can be used to predict the optimal thickness of catalyst films. A method for determining appropriate light intensities was proposed and discussed. The appropriate light intensity can be obtained by giving a margin, regarded as an excess coefficient, to the light intensity calculated based on the assumption of complete use of excited electron–hole pairs. The excess coefficient needs to be determined experimentally. In addition, the optimal flow velocity of PCO reactors could be consistent with the required one by changing the windward area of foam nickels. Based on the theoretical analyses, a novel PCO reactor containing 15 parallel-connected cells was designed. Each reaction cell was composed of an UV lamp and a TiO₂-coated tubular foam nickel. The performance of the reactor was tested by degrading gaseous formaldehyde at an indoor concentration level. The results showed that the reactor had low pressure loss and good degradation capability.     

Kinetic analysis on spherulite growth rate of polypropylene catalloys

The kinetic analysis on melt-crystallization of polypropylene catalloys (PP-cats) was conducted through measuring their spherulite growth rates. A multiple melting behavior of PP-cats was found through differential scanning calorimetry (DSC) and the corresponding crystalline microstructures of PP-cats were studied by wide-angle X-ray diffraction (WAXD). The calculated T_m^o value of propylene homopolymer (PP) suggests an obvious melting point depression of PP-cats. Moreover, it is found that the existence of ethylene-propylene copolymer could result in the changes of crystalline microstructure of PP and the PP crystal is in favor of growing along (040) lattice plane of α-monoclinic crystal. The crystal growth rate of PP-cats decreases with the increase of ethylene-propylene copolymer content in PP-cats. A comparison of crystallization kinetics between PP-cats and virgin iPP through a modified Lauritzen-Hoffman model indicates that there appears a transition from regimes II to III in iPP and PP-cats containing low ethylene-propylene copolymer content. However, for the PP-cats containing high ethylene-propylene copolymer content, crystallization always processes in regime II. In addition, both calculated nucleation parameter (K_g) and the fold surface free energy (σ_e) for PP-cats increase with the increase of ethylene-propylene copolymer content, implying that the existence of ethylene-propylene copolymer is unfavorable for the surface nucleation of PP and regular folding of the molecule chain. It is believed that an increase in viscosity of the melts induced by different compositions could remarkably slow crystallization growth down, because under this condition surface nucleation dominates as compared with crystal growth.     

汽车NVH控制橡胶减震元件行业的现状与发展

汽车的NVH(Noise,Vibration and Harshness,即噪声、振动和不平顺性)特性是汽车的五大性能指标之一(另外四个性能指标为:安全性、经济性、环保性和可靠性)。汽车的NVH控制是通过控制汽车中有关     

TWC LOGD: A portal for linked open government data ecosystems

International open government initiatives are releasing an increasing volume of raw government datasets directly to citizens via the Web. The transparency resulting from these releases not only creates new application opportunities but also imposes new burdens inherent to large-scale distributed data integration, collaborative data manipulation and transparent data consumption. The Tetherless World Constellation (TWC) at Rensselaer Polytechnic Institute (RPI) has developed the Semantic Web-based TWC LOGD portal to support the deployment of linked open government data (LOGD). The portal is both an open source infrastructure supporting linked open government data production and consumption and a vibrant community portal that educates and serves the growing international open government community of developers, data curators and end users. This paper motivates and introduces the TWC LOGD Portal and highlights innovative aspects and lessons learned.     

Reprocessing the MODIS Leaf Area Index products for land surface and climate modelling

Land surface and climate modelling requires continuous and consistent Leaf Area Index (LAI). High spatiotemporal resolution and long-time record data are more in demand nowadays and will continue to be in the future. MODIS LAI products meet these requirements to some degree. However, due to the presence of cloud and seasonal snow cover, the instrument problems and the uncertainties of retrieval algorithm, the current MODIS LAI products are spatially and temporally discontinuous and inconsistent, which limits their application in land surface and climate modelling. To improve the MODIS LAI products on a global scale, we considered the characteristics of the MODIS LAI data and made the best use of quality control (QC) information, and developed an integrated two-step method to derive the improved MODIS LAI products effectively and efficiently on a global scale. First, we used the modified temporal spatial filter (mTSF) method taking advantage of background values and QC information at each pixel to do a simple data assimilation for relatively low quality data. Then we applied the post processing-TIMESAT (A software package to analyze time-series of satellite sensor data) Savitzky-Golay (SG) filter to get the final result. We implemented the method to 10 years of the MODIS Collection 5 LAI data. In comparison with the LAI reference maps and the MODIS LAI data, our results showed that the improved MODIS LAI data are closer to the LAI reference maps in magnitude and also more continuous and consistent in both time-series and spatial domains. In addition, simple statistics were used to evaluate the differences between the MODIS LAI and the improved MODIS LAI.     

智能优化策略的比较

智能优化是从诸多新兴学科衍生出来的前沿科学，本文研究了智能优化的策略，对计算智能策略进行了分析比较，并举出了在工程实践中用这些策略进行智能优化的实例，从中得出有意义的结论。     

Experimental study and simulation of a hydraulic engine mount with fully coupled fluid-structure interaction finite element analysis model

Non-linear properties of a generic hydraulic engine mount (HEM) are identified and characterized by experiment and simulation approaches. The experimental methods for obtaining static and dynamic performances of the HEM are presented. The characteristics of two configurations of the take-apart HEMs (one is with an inertia track and a free decoupler and the other one is only with an inertia track) and their rubber springs are studied. The relations between static stiffness of an HEM and its rubber springs in three orthogonal directions are investigated. The influences of preload, excitation amplitudes and frequencies on the dynamic stiffness of an HEM are verified. The effects of the free decoupler on dynamic characteristics of the HEM are studied by comparisons of the test results of the two HEMs. The dynamic fluid pressure and the temperature in the upper chamber of an HEM are measured under different excitation conditions. A fully coupled fluid-structure interaction (FSI) and finite element analysis (FEA) model for simulation of HEMs is developed in this paper, which can be used to simulate the static and dynamic performances of the HEMs with only stress versus strain relations of the rubber materials, the fluid physical parameters and the HEMs sizes. The simulated results of one HEM with the proposed model are given, and the results match well with the measured data, or in coincidence with the working mechanisms of HEMs.