Chemical potentials of oxygen for three-phase assemblages of CaSiO3(s) + Ca3Si2O7(s) + {CaO + SiO2 + FexO} melt and Ca3Si2O7(s) + Ca2SiO4(s) + {CaO + SiO2 + FexO} melt

By employing an electrochemical technique involving stabilized zirconia as solid electrolyte and Mo + MoO₂ mixture as reference electrode, the equilibrium oxygen partial pressures for three-phase assemblages of CaSiO₃(s) + Ca₃Si₂O₇(s) + {CaO + SiO₂ + Fe_xO} melt and Ca₃Si₂O₇(s) + Ca₂SiO₄(s) + {CaO + SiO₂ + Fe_xO} melt were determined as: - log {P_O2 (CS + C₃S₂ + L)/bar} = - 3.22 13000/(T/K) ± 0.05 - log {P_O2 (C₃S₂ + C₂S + L)/bar} = - 0.92 16400/ (T/K) ± 0.04. respectively, where CS, C₃S₂ and C₂S indicate CaSiO₃(s), Ca₃Si₂O₇(s). and Ca₂SiO₄(s), respectively.     

0.25 μm gate length CMOS devices for cryogenic operation

Under cryogenic operation, a low V_th realizes a high speed performance at a greatly reduced power-supply voltage, which is the most attractive feature of Cryo-CMOS. It is very important in sub-0.25 μm Cryo-CMOS devices to reconcile the miniaturization and the low V_th. Double implanted MOSFET's technology was employed to achieve the low V_th while maintaining the short channel effects immunity. We have investigated both the DC characteristics and the speed performance of 0.25 μm gate length CMOS devices for cryogenic operation. The measured transconductances in the saturation region were 600 mS/mm for 0.2 μm gate length n-MOSFET's and 310 mS/mm for 0.25 μm gate length p-MOSFET's at 80 K. The propagation delay time in the fastest CMOS ring oscillator was 22.8 ps at V_dd=1 V at 80 K. The high speed performance at extremely low power-supply voltages has been experimentally demonstrated. The speed analysis suggests that the sub-l0 ps switching of Cryo-CMOS devices will be realized by reducing the parasitic capacitances and through further miniaturization down to 0.1 μm gate length or below     

K(ATP) channels contribute to the cardioprotection of preconditioning independent of anaesthetics in rabbit hearts

The contribution of ATP sensitive potassium (K(ATP)) channels to the infarct-size limiting effect of preconditioning is considered to be anaesthetic-dependent in the rabbit heart. It has previously been reported that ischaemic preconditioning prevents ischaemia-induced reductions in activities of sarcolemmal adenylate cyclase (AC) and Na+, K(+)-ATPase. Anaesthetic dependency of the role of K(ATP) channels in the preservation of these enzyme activities, induced by ischaemic preconditioning, as well as that induced by activation of A1-adenosine receptors, was examined in rabbits anaesthetized with either pentobarbital or ketamine-xylazine and subjected to 20 min of regional ischaemia. Adenylate cyclase and Na+, K(+)-ATPase activities were lower in the ischaemic than in the non-ischaemic region of the hearts in control rabbits, but not in animals subjected to ischaemic preconditioning, or those pretreated with the A1-adenosine receptor agonist R(-)-N6-(2-phenylisopropyl) adenosine. The protective effects of both ischaemic preconditioning and A1-adenosine receptor activation were prevented by 6 mg/kg, but not 3 mg/kg, of the K(ATP) channel blocker, glibenclamide, in rabbits anaesthetized with pentobarbital, while these effects were prevented by 3 mg/kg of the blocker in rabbits anaesthetized with ketamine-xylazine. Moreover, K(ATP) channel opener, cromakalim, prevented the ischaemia-induced decreases in enzymatic activities in rabbits subjected to either type of anaesthesia. Thus, although the antagonistic effect of glibenclamide is blunted under pentobarbital, compared to ketamine-xylazine anaesthesia, K(ATP) channels contribute to preservative actions independent of the type of anaesthesia in the rabbit heart.     

Activities of FexO in CaO + CaF2 + SiO2 + FexO quaternary slags by disposable electrochemical oxygen probes

The activities of Fe_xO in CaO + CaF₂ + SiO₂ + Fe_xO quaternary slags were measured by means of solid-oxide galvanic cell. The Fe_xO activities in the slags are influenced by CaF₂ as well as SiO₂. At constant Fe_xO mole fractions, e.g., , at low SiO₂ mole fractions i.e., , the substitution of CaF₂ for CaO has an effect of raising the Fe_xO activity. At higher SiO₂ mole fractions, e.g., , however, such an effect becomes insignificant.     

Feeding-stimulant activity of algal glycerolipids for marine herbivorous gastropods

Phagostimulant activity of glycerolipids such as digalactosyldiacylglycerol (DGDG), 6-sulfoquinovosyldiacylglycerol (SQDG), phosphatidylcholine (PC), phosphatidylethanolamine (PE), etc., have been examined using the Avicel plate method for three kinds of marine herbivorous gastropods, the abaloneHaliotis discus, the turban shellTurbo cornutus, and the topshellOmphalius pfeifferi. DGDG showed strong activity for all the test animals. SQDG was much less active than the other glycerolipids for abalone. The turban shell and the top shell responded more or less sensitively to all tested glycerolipids at doses of 10–20g/sample zone.Chemical Studies on Phagostimulants for Marine Gastropods. Part VIII. For Part VII, see Sakata et al. (1988a).     

Measurement of self-diffusion coefficients in Li ionic conductors by using the short-lived radiotracer of 8Li

For the effective use of short-lived radioactive beams, soon to be available at the Tokai Radioactive Ion Accelerator Complex, the authors have developed a radiotracer method for diffusion studies in solids. The experimental test was performed by the measurement of the diffusion coefficients of Li in a sample of the compound βLiAl using an α-emitting radiotracer of ⁸Li (T_1/2=0.84 s). It was found that the time-dependent yields of the α particles from the diffusing ⁸Li that was initially implanted in the sample could be used as a measure of the diffusivity of the tracer in a nondestructive way. The method was applied to measure the self-diffusion coefficients of Li in βLiGa, and for investigating how the Li diffusion in the Li ionic conductors is affected by the concentration of atomic defects (i.e., the existence of the atomic vacancies of Li and the defects in Ga sites that are replaced by Li).     

Structural and hydration properties of amorphous tricalcium silicate

Mechanical milling was carried out to synthesize amorphous tricalcium silicate (Ca₃SiO₅) sample, where Ca₃SiO₅ is the most principal component of Portland cement. The partial phase transformation from the crystalline to the amorphous state was observed by X-ray and neutron diffractions. Moreover, it was found that the structural distortion on the Ca-O correlation exists in the milled Ca₃SiO₅. The hydration of the milled Ca₃SiO₅ with D₂O proceeds as follows: the formation of hydration products such as Ca(OD)₂ rapidly occurs in the early hydration stage, and then proceeds slowly after about 15 h. The induction time for the hydration of the milled Ca₃SiO₅ is approximately one half shorter than that for the hydration of the unmilled one. This result means that the mechanical milling brings about the chemical activity of Ca₃SiO₅ for hydration, and may be particularly useful for increasing the reactivity in the early hydration stage.     

Ion-velocity dependence of high-density electronic excitation effects in oxide superconductors

Thin films of EuBa₂Cu₃O_y oxide superconductor have been irradiated with high energy heavy ions (80 MeV I, 125 MeV Br, 1.1 GeV Mo and 3.5 GeV Xe) having same electronic stopping power, S_e, in order to investigate the ion-velocity dependence of the electronic excitation effects under the constant electronic energy deposition. Although S_e is constant, a strong reduction in the irradiation effect on lattice parameter with increasing ion-velocity is observed in the low ion-velocity region around E  1 MeV/nucleon, while the ion-velocity dependence is hardly observed in the high ion-velocity region of E > 10 MeV/nucleon. If the observed velocity-dependence is assumed to be due to the change in the fraction of S_e contributing to defect creation, the fraction in the low velocity region (E  0.6 MeV/nucleon) is estimated to be about two times larger than that in the high velocity region (E > 10 MeV/nucleon).     

Activities of Phosphorus in Copper‐Iron Liquid Alloys Saturated with Copper‐Iron Solid Solutions

In order to determine the activities of phosphorus and iron in liquid {Cu‐Fe‐P} alloys, the two coexisting phases of liquid {Cu‐Fe‐P} alloys + <Cu‐Fe‐P> solid solutions were brought into equilibrium with a mixture of Al₂O₃ + AlPO₄ + Fe_xAl₂O₄ at temperatures of 1416K and 1526K. The oxygen partial pressures were measured with the aid of a solid‐oxide galvanic cell of the type: (+)Mo / Mo + MoO₂/ ZrO₂(MgO) / {Cu‐Fe‐P} + <Cu‐Fe‐P> + <Al₂O₃> + <AlPO₄> + <FeAl₂O₄> / Fe(‐) The equilibrium reactions underlying the experiments can be expressed by 2[P]_cu + (5/2) (O₂) + <Al₂O₃> = 2 <AlPO₄> and x[Fe]_Cu + (1/2) (O₂) + <Al₂O₃> = <Fe_xAl₂O₄> The Henrian activity coefficient referred to 1 wt pct solution in pure liquid copper could be well expressed by the formula log f_P° = (4.46±0.40) ‐ (8.67±0.59)/(T/K). The iron activities referred to pure solid iron could be formulated as log a_Fe =‐ (0.37 ± 0.12) + (500 ±200) /(T/K).