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排序方式: 共有319条查询结果,搜索用时 125 毫秒
1.
Choon-Woo Nahm 《Journal of Materials Science》2006,41(20):6822-6829
The electrical properties and DC accelerated aging characteristics of ZnO–Pr6O11-based varistors were investigated with various Dy2O3 contents and sintering times. It was found that the Dy2O3 content and sintering time significantly affected electrical properties and their stability. The nonlinear exponent with
increasing Dy2O3 content varied with ∨-shaped, reaching maximum of 58.6 at 1.0 mol% Dy2O3 for varistors sintered for 1 h and with ∧-shaped, reaching maximum of 46.3 at 0.5 mol% Dy2O3 for 2 h. The leakage current was in the range of 0.1–1.1 μA for varistors sintered for 1 h and 0.3–2.4 μA for 2 h. The increase
of sintering time led to lowering of nonlinearity. The varistors with 0.5 mol% Dy2O3 sintered for 2 h exhibited the good stability, under DC stress of 0.95 V
1 mA/150 °C/24 h. 相似文献
2.
3.
K-S. Park S-H. Park Y-K. Sun K-S. Nahm Y-S. Lee M. Yoshio 《Journal of Applied Electrochemistry》2002,32(11):1229-1233
The structural and electrochemical properties of LiNiO2 powders were investigated as a function of the oxygen flow rate employed in the preparation of lithium nickel oxide. It was found that oxygen played an important role in the synthesis of highly crystallized LiNiO2(R3¯m). In the crystallization process of LiNiO2, a deficiency of oxygen in the calcination reactor induced the formation of impurities and cubic rock-salt structure (Fm3m) in LiNiO2 powders. For LiNiO2 prepared at higher oxygen flow rates, the electrode delivered high discharge capacities with relatively good retention rates. But very low electrode capacity was obtained from LiNiO2 prepared at lower oxygen flow rates. 相似文献
4.
Ki Soo ParkMyung Hun Cho Sang Ho ParkKee Suk Nahm Yang Kook SunYun Sung Lee Masaki Yoshio 《Electrochimica acta》2002,47(18):2937-2942
Layered Li0.7[M1/6Mn5/6]O2 (M=Li, Ni) was synthesized using a sol-gel method. P2-Na0.7[M1/6Mn5/6]O2 precursor was first synthesized by a sol-gel method, and then O2-Li0.7[M1/6Mn5/6]O2 was prepared by an ion exchange of Li for Na in P2-Na0.7[M1/6Mn5/6]O2 precursor. From charge/discharge curves, it was seen that Li0.7[Li1/6Mn5/6]O2 has two plateaus similar to those observed from a spinel structure, but Li0.7[Ni1/6Mn5/6]O2 holds a single plateau as observed from a typical layered structure. It was considered that Li0.7[Li1/6Mn5/6]O2 undergoes a phase transformation from layered to spinel structure during the charge/discharge cycle, but Li0.7[Ni1/6Mn5/6]O2 maintains O2-layered structure after the cycles. Li0.7[Ni1/6Mn5/6]O2 was higher in discharge capacity and retention rate than Li0.7[Li1/6Mn5/6]O2. 相似文献
5.
Synthesis of BaCu(B2 O5 ) Ceramics and their Effect on the Sintering Temperature and Microwave Dielectric Properties of Ba(Zn1/3 Nb2/3 )O3 Ceramics 总被引:1,自引:0,他引:1
Min-Han Kim Jong-Bong Lim Jae-Chul Kim Sahn Nahm Jong-Hoo Paik Jong-Hee Kim Kyeong-Soon Park 《Journal of the American Ceramic Society》2006,89(10):3124-3128
BaCu(B2 O5 ) ceramics were synthesized and their microwave dielectric properties were investigated. BaCu(B2 O5 ) phase was formed at 700°C and melted above 850°C. The BaCu(B2 O5 ) ceramic sintered at 810°C had a dielectric constant (ɛr ) of 7.4, a quality factor ( Q × f ) of 50 000 GHz and a temperature coefficient of resonance frequency (τf ) of −32 ppm/°C. As the BaCu(B2 O5 ) ceramic had a low melting temperature and good microwave dielectric properties, it can be used as a low-temperature sintering aid for microwave dielectric materials for low temperature co-fired ceramic application. When BaCu(B2 O5 ) was added to the Ba(Zn1/3 Nb2/3 )O3 (BZN) ceramic, BZN ceramics were well sintered even at 850°C. BaCu(B2 O5 ) existed as a liquid phase during the sintering and assisted the densification of the BZN ceramic. Good microwave dielectric properties of Q × f =16 000 GHz, ɛr =35, and τf =22.1 ppm/°C were obtained for the BZN+6.0 mol% BaCu(B2 O5 ) ceramic sintered at 875°C for 2 h. 相似文献
6.
Kyeong Bock Lee Choon Mahn Park Hyun Sik Noh Chul Koo Kim Kyun Nahm 《Journal of Materials Science》1993,28(24):6545-6548
Measurements of electrical resistivity. X-ray diffraction patterns, magnetic susceptibility and thermoelectric power of the Er1-x
Pr
x
Ba2Cu3O7- system have been made. The superconducting transition temperature was found to decrease monotonically with praseodymium concentration, x. From the susceptibility data, it was determined that the valence of praseodymium lies between +3 and +4. The thermoelectric power was found to increase with x, and the slopes of dS/dT were negative except for the case x= 0. The. tendency of the thermopower to change with increasing praseodymium concentration has been qualitatively explained using the theory for strongly correlated systems. 相似文献
7.
Choon-Woo Nahm 《Journal of Materials Science》2006,41(22):7272-7278
The microstructure, electrical properties, and stability against DC accelerated aging stress of the varistor ceramics, which are composed of ZnO–Pr6O11–CoO–Cr2O3–La2O3-based ceramics, were investigated for various La2O3 contents. The increase of La2O3 content led to more densified ceramics, whereas abruptly decreased the nonlinear properties by incorporating beyond 1.0 mol%. The highest nonlinearity was obtained from 0.5 mol% La2O3, in which the nonlinear exponent is 81.6 and the leakage current is 0.1 μA. As the La2O3 content increased, the donor concentration increased in from 0.64 × 1018 to 16.89 × 1018/cm3 and the barrier height greatly decreased with increasing La2O3 content, reaching a maximum (1.47 eV) in 0.5 mol% La2O3. The varistors doped with 0.5 mol% La2O3 exhibited high stability, in which the variation rates of varistor voltage, nonlinear exponent, and leakage current were −1.14%, −3.7%, and +100%, respectively, for stressing state of 0.95 V
1 mA/150 °C/24 h. 相似文献
8.
Hyunjo Jeong Seung-Hoon Nahm Kyung-Young Jhang Young-Hyun Nam 《Journal of Mechanical Science and Technology》2002,16(2):147-154
The objective of this paper is to develop a nondestructive method for estimating the fracture toughness (K IC) of CrMoV steels used as the rotor material of steam turbines in power plants. To achieve this objective, a number of CrMoV steel samples were heat-treated, and the fracture appearance transition temperature (FATT) was determined as a function of aging time. Nonlinear ultrasonics was employed as the theoretical basis to explain the harmonic generation in a damaged material, and the nonlinearity parameter of the second harmonic wave was the experimental measure used to be correlated to the fracture toughness of the rotor steel. The nondestructive procedure for estimating theK IC consists of two steps. First, the correlations between the nonlinearity parameter and the FATT are sought. The FATT values are then used to estimateK IC, using theK IC versus excess temperature (i.e.,T-FATT) correlation that is available in the literature for CrMoV rotor steel. 相似文献
9.
Choon-Woo Nahm 《中国稀土学报(英文版)》2013,31(3):276-280
The effect of Tb4O7 on electrical behavior of the ZnO-Pr6O11-based varistor ceramics was investigated.Microstructural analysis indicated that the addition of Tb4O7 decreased average grain size from 3.6 to 3.2 μm and increased the sintered density from 5.58 to 5.68 g/cm3.As the amount of Tb4O7 increased,the breakdown field increased from 9393 to 12437 V/cm and the nonlinear coefficient increased from 50 to 65.The varistor ceramics added with 0.5 mol.% in the amount of Tb4O7 exhibited an excellent stability by exhibiting-0.1% in the variation rate of the breakdown field,0% in the variation rate of the nonlinear coefficient,and 8.8% in the variation rate of the leakage current density for DC-accelerated aging stress of 0.85 E1 mA/115℃/24 h. 相似文献
10.
Woojin Lee Hoechang Kim Dae-Ryong Jung Jongmin Kim Changwoo Nahm Junhee Lee Suji Kang Byungho Lee Byungwoo Park 《Nanoscale research letters》2012,7(1):672
The effects of surface passivation on the photoluminescence (PL) properties of CdS nanoparticles oxidized by straightforward H2O2 injection were examined. Compared to pristine cadmium sulfide nanocrystals (quantum efficiency ≅ 0.1%), the surface-passivated CdS nanoparticles showed significantly enhanced luminescence properties (quantum efficiency ≅ 20%). The surface passivation by H2O2 injection was characterized using X-ray photoelectron spectroscopy, X-ray diffraction, and time-resolved PL. The photoluminescence enhancement is due to the two-order increase in the radiative recombination rate by the sulfate passivation layer. 相似文献