Speed Control of DC Motor with MRPID Controller in the Presence of Noise

Speed control of a DC motor has always been a challenge because of its variable torque. But it becomes more challenging when noise enters the system at its input. Therefore, there is a need of more advanced controllers. In this paper, a multi-resolution proportional integral derivative (MRPID) controller has been proposed to be utilized to control the speed of a DC motor. It works well even in the presence of noise as compared to the conventional PID controller. Also, performance of a PID controller deteriorates when nonlinearity or uncertainty arises in the system. This degraded performance can be improved by utilizing the multi-resolution property of wavelets, which decomposes the error signal into various frequency components. Further, wavelet coefficients of these decompositions are used to generate the control signal for controlling speed of a DC motor. In this paper, performances of a MRPID, a fractional order PID (FOPID) and a conventional PID controllers are compared in the presence of noise for speed control of a DC motor. The results obtained using a MRPID controller are observed to be better in terms of improved transient characteristics and disturbance rejection for a DC motor as compared to those obtained with PID and FOPID controllers.

     

Friedmann-Robertson-Walker metric in curvature coordinates and its applications

For the first time, we express the general Friedmann-Robertson-Walker (FRW) metric (k = +1, 0,?1) into explicit “Schwarzschild” or “Curvature” form, which is important from the viewpoint of cosmology. With this form of the FRW metric, we reconsider the old problem of embedding a Schwarzschild mass (SM) in a pre-existing FRW background from the viewpoints of both (1) the enigmatic McVittie metric, obtained in 1933 and (2) the Einstein-Straus approach (1945) of scooping out a spherical cavity in the same background. Since the exterior of the SM is, by definition, described in the Schwarzschild coordinates, for a definitive study of the Einstein-Straus approach we employ this form of the FRW metric. We find that a necessary condition for a SM to participate in the cosmic expansion is that the background fluid is dust.     

Revisiting the old problem of general-relativistic adiabatic collapse of a uniform-density self-gravitating sphere

The problem of general-relativistic adiabatic collapse of a uniform-density perfect sphere has been studied since Wyman (Phys. Rev. 70, 396, (1946)) [1]. Apparently, there could be bouncing and oscillating solutions in such a case, as claimed by numerous authors since then. Consequently, various authors invoked such models for explaining pulsations of compact objects. However, here, for this age-old problem, we prove that for an assumed nonstatic adiabatically evolving sphere, density homogeneity implies (isotropic) pressure homogeneity too. This proof is based on the simple fact that in general relativity (GR), given one time coordinate t, one can employ another time coordinate t → t* = f(t) without any loss of generality. Since this proof does not use any exterior boundary condition, it is valid in a cosmological scenario too. However, here we focus on the evolution of an isolated sphere having a boundary. And the proof obtained here shows that a uniform-density perfect fluid collapse can occur only if the (isotropic) pressure is p = 0, i.e., only when the problem is reduced to the one treated by Oppenheimer and Snyder. For such an isolated sphere, we offer a supporting proof. This result is important and nontrivial because in the past 65 years innumerable authors working on this problem failed to see that the collapse of a supposed homogeneous sphere is (actually) synonymous to the old Oppenheimer-Snyder problem.     

Computational fluid dynamics modeling of high temperature air combustion in an heat recovery steam generator boiler

This paper reports a numerical study on the possibility of using high temperature air combustion (HiTAC) technique in the heat recovery steam generator (HRSG) boiler of the Fajr Petrochemical Complex, Iran. For this purpose a theoretical fuel nozzle which operates in HiTAC mode of combustion has been installed and modeled using the computational fluid dynamics (CFD) technique. By aim of establishing an efficient heat transfer rate to the boiler’s tubes, the proper nozzle location and an optimum mass flow rate of fuel have been found. The results show that by using this modification it is possible to increase the steam temperature up to 37 percent.     

Molecular-scale structure of uranium(VI) immobilized with goethite and phosphate

The molecular-scale immobilization mechanisms of uranium uptake in the presence of phosphate and goethite were examined by extended X-ray absorption fine structure (EXAFS) spectroscopy. Wet chemistry data from U(VI)-equilibrated goethite suspensions at pH 4-7 in the presence of ~100 μM total phosphate indicated changes in U(VI) uptake mechanisms from adsorption to precipitation with increasing total uranium concentrations and with increasing pH. EXAFS analysis revealed that the precipitated U(VI) had a structure consistent with the meta-autunite group of solids. The adsorbed U(VI), in the absence of phosphate at pH 4-7, formed bidentate edge-sharing, ≡ Fe(OH)(2)UO(2), and bidentate corner-sharing, (≡ FeOH)(2)UO(2), surface complexes with respective U-Fe coordination distances of ~3.45 and ~4.3 ?. In the presence of phosphate and goethite, the relative amounts of precipitated and adsorbed U(VI) were quantified using linear combinations of the EXAFS spectra of precipitated U(VI) and phosphate-free adsorbed U(VI). A U(VI)-phosphate-Fe(III) oxide ternary surface complex is suggested as the dominant species at pH 4 and total U(VI) of 10 μM or less on the basis of the linear combination fitting, a P shell indicated by EXAFS, and the simultaneous enhancement of U(VI) and phosphate uptake on goethite. A structural model for the ternary surface complex was proposed that included a single phosphate shell at ~3.6 ? (U-P) and a single iron shell at ~4.3 ? (U-Fe). While the data can be explained by a U-bridging ternary surface complex, (≡ FeO)(2)UO(2)PO(4), it is not possible to statistically distinguish this scenario from one with P-bridging complexes also present.     

Dissolution of biogenic and synthetic UO2 under varied reducing conditions

The chemical stability of biogenic UO2, a nanoparticulate product of environmental bioremediation, may be impacted by the particles' surface free energy, structural defects, and compositional variability in analogy to abiotic UO(2+x) (0 < or = x < or = 0.25). This study quantifies and compares intrinsic solubility and dissolution rate constants of biogenic nano-UO2 and synthetic bulk UO2.00, taking molecular-scale structure into account. Rates were determined under anoxic conditions as a function of pH and dissolved inorganic carbon in continuous-flow experiments. The dissolution rates of biogenic and synthetic UO2 solids were lowest at near neutral pH and increased with decreasing pH. Similar surface area-normalized rates of biogenic and synthetic UO2 suggest comparable reactive surface site densities. This finding is consistent with the identified structural homology of biogenic UO2 and stoichiometric UO2.00 Compared to carbonate-free anoxic conditions, dissolved inorganic carbon accelerated the dissolution rate of biogenic UO2 by 3 orders of magnitude. This phenomenon suggests continuous surface oxidation of U(IV) to U(VI), with detachment of U(VI) as the rate-determining step in dissolution. Although reducing conditions were maintained throughout the experiments, the UO2 surface can be oxidized by water and radiogenic oxidants. Even in anoxic aquifers, UO2 dissolution may be controlled by surface U(VI) rather than U(IV) phases.     

Experimental,equilibrium modelling,and column design for the reactive separation of biomass-derived 2-furoic acid

Electrochemical conversion of biomass to value-added chemicals has gained impetus in recent years. Herein, we present a methodology for recovering biomass-derived 2-furoic acid from the dilute aqueous stream by reactive extraction. The reactive extraction was performed using a chemical extractant, trioctylamine (TOA), with diluents (octanol, chloroform, and diethyl ether). Equilibrium parameters influencing the recovery of 2-furoic acid were evaluated. Using TOA in various diluents, the 2-furoic acid was recovered with 85%–99% efficiency. A 1:1 complex of the 2-furoic acid—TOA was formed in the organic phase, and the experimental equilibrium complexation constant was compared with that obtained from the relative basicity and Langmuir models. The equilibrium parameters were used for column design to estimate the solvent to feed ratio (S/F) and the number of theoretical stages (NTS). The NTS required is 12 to attain 99% recovery of 2-furoic acid in counter-current extraction. The present study sheds light on the reactive extraction process adopted for process intensification with electrochemical conversion, paving the way for the commercialization of valuable products obtained from biomass.