排序方式: 共有63条查询结果,搜索用时 15 毫秒
1.
Turyanskiy A. G. Vorob’ev N. S. Gizha S. S. Makushina V. A. Mikhal’kov Yu. M. Smirnov A. V. Pirshin I. V. Senkov V. M. Shashkov E. V. Fishman R. I. Ziyatdinova M. Z. Komel’kov A. S. 《JETP Letters》2020,112(11):734-738
JETP Letters - The possibility of stable generation of intense characteristic Cs radiation upon electronic excitation of a Mo anode target heat treated in Cs and O2 vapors is demonstrated. The... 相似文献
2.
G. K. Ziyatdinova A. I. Samigullin G. K. Budnikov 《Journal of Analytical Chemistry》2007,62(8):773-776
Isoquinoline derivatives (papaverine and drotaverine) are oxidized at a graphite electrode in a 0.1 M sulfuric acid solution to give voltammetric waves at 1.1 V for papaverine and at 1.05 and 1.28 V for drotaverine. Determination limits and linearity ranges of currents as functions of papaverine and drotaverine concentrations are estimated. Microgram amounts of papaverine and drotaverine are determined in model solutions (RSD = 1–4%). A procedure for the direct determination of papaverine and drotaverine in pharmaceuticals is proposed. 相似文献
3.
B. A. Salakhutdinov D. N. Dalimov T. F. Aripov I. I. Tukfatullina R. Kh. Ziyatdinova A. Zh. Dzhuraev F. G. Kamaev L. Yu. Izotova B. T. Ibragimov I. Mavridis P. Giastas 《Chemistry of Natural Compounds》2002,38(3):249-256
Derivatives of 3-O-acetyl-18-H-glycyrrhetic acid were synthesized. Their structures and membrane activities were studied. 相似文献
4.
I. F. Abdullin E. N. Turova G. K. Ziyatdinova G. K. Budnikov 《Journal of Analytical Chemistry》2002,57(4):353-355
It was found that an iodine-modified platinum electrode gives a linear potentiometric response to 1.0 × 10–5 to 1.0 × 10–3 M ascorbic acid in model solutions. Ascorbic acid in some preparations was determined by potentiometry. The contribution of ascorbic acid to the total antioxidant capacity of aqueous extracts of hips, hop cones, and lemon juice was estimated. 相似文献
5.
S. G. Abdullina I. K. Petrova O. A. Lira G. K. Ziyatdinova H. C. Budnikov 《Journal of Analytical Chemistry》2012,67(3):269-272
Arbidol is proved to easily and completely react with electrogenerated bromine in the ratio 2: 9; so procedures for the arbidol
quantification in the neat substance and drugs are developed, the RSD value does not exceed 2%. A procedure for the coulometric
determination of water in the arbidol substance using the Fisher method is proposed. 相似文献
6.
Stoichiometric coefficients in reactions of sterically hindered phenols and α-tocopherol with electrogenerated hexacyanoferrate(III) ions have been found. Schemes of oxidation reactions via hydroxyl groups in the molecular structure have been proposed. The relative standard deviation of the results of determination of the indicated compounds in model solutions is ≤5%. It has been shown that α-tocopherol and ionol are quantitatively extracted from vegetable oil by 15-min single extraction at the oil-to-acetonitrile ratio 1: 2.5. A procedure for the extraction-coulometric determination of α-tocopherol in vegetable oil has been developed. 相似文献
7.
G. K. Ziyatdinova A. A. Gainetdinova G. K. Budnikov 《Journal of Analytical Chemistry》2010,65(9):929-934
Synthetic phenolic compounds (pyrogallol, catechol, hydroquinone, and their derivatives bearing heterocyclic fragments) react
with electrogenerated titrants, halogens, and ferricyanide(III) ions. Stoichiometric coefficients of reactions are found.
It is shown that the use of ferricyanide(III) ions as a titrant and a one-electron oxidant for the determination of this class
of antioxidants offers advantages in comparison with titrants-halogens. The found amounts of pyrogallol, pyrocatechol, and
hydroquinone derivatives in model solutions with the RSD 1–5% are fractions of milligrams. It is found that, in the series
of the studied synthetic phenolic compounds, pyrocatechol derivatives possess the maximum antioxidant capacity (AOC). 相似文献
8.
G. K. Ziyatdinova G. K. Budnikov A. I. Samigullin G. T. Gabdullina A. V. Sofronov L. A. Al’metkina I. S. Nizamov R. A. Cherkasov 《Journal of Analytical Chemistry》2010,65(12):1273-1279
It has been found that bisdithiophosphonic acids with aryl substituents at the phosphorus atom quantitatively interact with
electrogenerated halogens under the conditions of galvanostatic coulometry. Stoichiometric coefficients of the reaction between
synthetic antioxidants and coulometric titrants-halogens have been determined. The corresponding reaction schemes have been
proposed. The total antioxidant capacity (TAC) of the analytes has been estimated by their reaction with electrogenerated bromine. It has been demonstrated that bisdithiophosphonic
acids bearing ionolic fragments demonstrate the highest TAC. It has been established that bisdithiophosphonic acids are irreversibly
oxidized on a glassy carbon electrode at a potential of 800 mV with 0.1 M NaClO4 in acetonitrile as the supporting electrolyte. The quantification limit and the analytical range of the analyte determination
have been found. 相似文献
9.
R. G. Tagasheva E. R. Shakirova S. V. Bukharov I. V. Galkina G. K. Ziyatdinova R. Z. Musin I. Kh. Rizvanov 《Russian Journal of General Chemistry》2018,88(1):68-72
New multifunctional antioxidants based on carboxy- and sulfobetaines with sterically hindered phenol fragments were synthesized. The antioxidant capacity of the compounds determined in the reactions of their oxidation by electrogenerated bromine is comparable to that of ascorbic acid and ionol. 相似文献
10.
Guzel Ziyatdinova Lidiya Grigor’eva Mikhail Morozov Albert Gilmutdinov Herman Budnikov 《Mikrochimica acta》2009,165(3-4):353-359
MWNT-modified electrodes are introduced for the voltammetric determination of sulfur-containing amino acids. The morphology of the electrode surface has been characterized by atomic force microscopy. The MWNT layer consists of deeply intertwined vermicular structures with the average diameter of 25 nm. Cysteine, glutathione and methionine are oxidized on the electrode while only cysteine gives signals on the glassy carbon (GC) electrode. The application of such electrodes leads to a decreased overpotential and increase of oxidation currents for cysteine in comparison with a bare GC electrode. The schemes of oxidation are proposed. A decrease of the lower limit of determination and an enlargement of the analytical range for antioxidants were obtained. A simple, fast and accurate procedure for the voltammetric determination of methionine in pharmaceuticals has been developed and can be recommended for quality control purposes. 相似文献