类锂硅离子软X射线激光研究

在激光等离子体典型参数条件下，利用碰撞－辐模型计算了类锂硅离子５ｆ－３ｄ和４ｆ－３ｄ跃的粒子数反转比率和激光增益系数。讨论了不同热带条件和不同冷却速度下，激光增益系统数的变化。计算结果表明，高功率，短脉冲激光生产的高温等离子体在快速冷却条件下能产生软Ｘ射的线激光增益。     

Influence of relaxation effects on probabilities of the 2s2p35S2－2s22p2 3P1，2 intercombination transitions in NII

Transition probabilities of the 2s2p^3 {}^5S_2－2s^22p^2 {}^3P_{1,2} intercombination transitions in NII have been calculated by using a large-scale multiconfiguration Dirac－Fock method. In the calculation the most important effects of relativity, correlation, and relaxation are considered. From the calculated transition probabilities, the lifetime of the 2s2p^3 {}^5S_2 metastable state is derived. The result is in excellent agreement with the latest experimental result. In the meantime the influence of anomalously strong relaxation effects on probabilities of the 2s2p^3 {}^5S_2－2s^22p^2 {}^3P_{1,2} lines in NII have been found.     

超声波原油破乳脱水的声场参数实验研究

本文阐明了超声波原油破乳脱水基本原理,实验研究了超声场参数对脱水率的影响,其中,声强,辐照时间和频率和影响原油脱水率的主要因素,而间歇比,脉冲宽度为次要回素,对本实验系统而言,声场参数有一个最佳值或范围,声强0.65W/cm^2,频率20kHz,间歇比8,脉冲宽度9.7ms,辐照时间5－10min.     

NⅡ离子2p4f—2p3d辐射跃迁概率的理论研究

在全相对论理论框架下，利用多组态Dirac-Fock(MCDF)方法，系统计算了NⅡ离子2p4f—2p3d的辐射跃迁概率，得到的结果与已有实验值符合很好.具体计算中，详细分析了相对论效应、电子关联、弛豫效应、Breit相互作用和量子电动力学(QED)效应对能级精细结构及辐射跃迁概率的影响.结果表明：相对论效应、电子关联和弛豫效应对NⅡ 2p4f-2p3d辐射跃迁概率有很重要的影响,考虑了这些效应后计算值得到明显改善.     

电导法研究树脂与游离酸的相互作用

利用电导实验技术跟踪树脂吸附游离酸的行为 ,讨论了外加盐和乙醇等因素对吸附的影响 ,利用固 -液相互作用方程求取吸附剂 -吸附质相互作用能。实验结果表明 ,树脂吸附游离酸 ,其表观吸附速率常数随着外加盐离子浓度的增大而减少 ;表观吸附速率常数与吸附剂 -吸附质相互作用能存在线性关系。     

A1Ⅱ离子3snp^1p1序列能级辐射寿命的非单调变化

本文考虑了一价铝离子双激发干扰态３ｐ４ｓ＾１ｐ１＾０对ｓｎｐ＾１Ｐ１＾０Ｒｙｄｂｅｒｇ序列的强相互作用，多组态ＨＦＲ自洽场方法计算了Ａ１Ⅱ３ｓｎｐ＾１Ｐ１０（ｎ＝３－１０）序列能级的辐射寿命，与已有的实验和理论计算结果进行了比较，结果表明该序列能级寿命随主量子数ｎ呈现非单调变化。     

Transmission characteristics of an excited-state induced dispersion optical filter of rubidium at 775.9 nm

The operation of an ultra-narrow bandwidth optical filter based on the 5P3/2→5D3/2 excited-state transition in rubidium vapor is reported. The 5D3/2 state is excited by a circularly polarized pump beam at 780 nm from a diode laser. The filter displays a single 398-MHz bandwidth at a peak transmission of 9.0%, which is narrower than the Doppler bandwidth. The dependence of peak transmission on the pump intensity and cell temperature is also given.     

与闪电过程有关的NII离子能级寿命的理论计算

用相对论多组态DiracFock方法,系统地计算了与闪电过程有关的NII离子2p2,2s2p3,2p3s,2p3p,2p3d组态能级之间的辐射跃迁概率,并由此推算出这些组态的35个能级的寿命.计算中考虑了相对论效应、电子关联、延迟效应等重要贡献.与已有的理论计算比较,目前计算的结果更接近最新实验值.据此,进一步给出了2p3d3F能级寿命新的理论预言值     

毛细管气相色谱法测定食用油中15种反式脂肪酸的含量

提出了毛细管气相色谱法测定橄榄油、芝麻油和花生油中的15种反式脂肪酸。样品用异辛烷溶解,与2mol·L-1氢氧化钾的甲醇溶液进行酯化反应,生成的脂肪酸甲酯经强极性聚二氰丙基硅氧烷毛细管气相色谱柱SP-2560分离,用氢火焰离子化检测器检定。在优化的试验条件下,15种反式脂肪酸甲酯的质量浓度在一定范围内与其峰面积呈线性关系,方法的检出限(3S/N)和测定下限(10S/N)分别为0.012%(以脂肪计)和0.024%(以脂肪计)。对空白样品进行加标回收试验,回收率在86.6%~109%之间,测定值的相对标准偏差(n=10)在2.0%~4.2%之间。方法用于分析市售橄榄油、芝麻油和花生油中的15种反式脂肪酸,结果与标准方法的测定值相符。     

Electric-dipole allowed （El） and forbidden （E2, M1 and M2） transition probabilities of 4f for N＋

By applying systematically enlarged multi-configuration Dirac-Fock wavefunction, the transitions for electricdipole allowed （E1） and forbidden （E2, M1 and M2） lines are studied among 4f pair coupling and low-lying configurations for singly ionized nitrogen. Most important effects of relativity, electron correlation, the rearrangement of electron density, Breit interaction, and quantum electrodynamic effects are included in the computation. Then, allowed （E1） and forbidden （E2, M1 and M2） transition probabilities of 4f for N＋ are obtained and compared with experimental results. Good agreement with available experimental results is found and most of the data of 4f are presented for the first time.