Mid-infrared generation based on a periodically poled LiNbO3 optical parametric oscillator

We report a nanosecond Nd:YVO_4-pumped optical parametric oscillator (OPO) based on periodically poled LiNbO_3 (PPLN). Tuning is achieved in this experiment by varying the temperature and period of the PPLN. The design of double-pass singly resonant oscillator (DSRO) and confocal cavity enables the OPO threshold to be lowered considerably, resulting in a simple, compact, all-solid-state configuration with the mid-infrared idler powers of up to 466mW at 3.41μm.     

Measurements of AIM for Visible Wavelength Based on Individual Eye Model

We measure and calculate the aerial image modulation （AIM） of human retina for visible wavelengths based on the individual eye model. By employing the optical design software ZEMAX, we obtain the modulation transfer function （MTF） of human eye in visible wavelengths. Using CSV-1000 and VAF-1000, the contrast sensitivity function （CSF） and the visual acuity （VA） for the same eye are measured. Then the AIM of human retina could be acquired by the relations between MTF and CSF and between MTF and VA. The AIM of human retina is independent of MTF, and the values of AIM for normal eyes （without retina disease） are similar, so the assembly average for large numbers of normal eyes can be a standard AIM curve, which is helpful for the diagnosis of diseases in the retina system.     

Mid—Infrared Optical Parametric Oscillator Based on All—Solid—State—Pumped Periodically Poled LiNbO

We report the tunable mid-infrared generation with a periodically poled LinbO3(PPLN).Using an all-solid-state pumped Nd:YVO4 laser as the pump source and a PPLN nonlinear crystal with grating periods of 28.2-30.8μm,we have achieved wavelength conversion in the 2.90-4.05μm spectral range by period tuning.The use of confocal cavity design has brought a compact,all-solid-state configuration with an average output powers of idler up to -200mW.The maximum power of 277mW was obtained at the wavelength of 3.35um.     

K系数—多波长最小一乘回归分光光度法同时测定三组分的研究

将双波长Ｋ系分光光度法和多波长线性回归分光光度法相结合，并采用最小一乘法准则计算回归系数，提出了一种同时测定三组分的新方法，即Ｋ系数－多波长最小一乘回归分光光度法。     

磺酸功能化介孔聚合物催化“一锅法”无溶剂合成3,4-二氢嘧啶-2(1H)-酮

通过软模剂合成方法合成了高度有序具有二维六方(p6mm)的FDU-15介孔聚合物材料.利用气固相磺化法制备得到新型磺酸基功能化介孔聚合物固体酸(FDU-SO3H).通过X-射线衍射(XRD)、扫描电镜(SEM)及元素分析等测试手段对FDU-SO3H介孔材料的物化性能进行了表征.在无溶剂条件下,FDU-SO3H能有效地催化以芳香醛、乙酰乙酸甲酯和尿素(或硫脲)的三组分一锅法的Biginelli反应.在优化实验的条件下,合成了一系列3,4-二氢嘧啶-2(1H)-酮衍生物.考察了加料顺序、溶剂及反应底物对Biginelli反应的影响.苯甲醛、乙酰乙酸甲酯和尿素在无溶剂,90℃加热1 h的条件下反应,3,4-二氢嘧啶-2(1H)-酮的产率为91%.探讨了Biginelli可能的反应机理.实验结果证明,FDU-SO3H不仅具有催化活性高、对环境友好及在空气中稳定等优点,而且重复使用后仍能保持优异的催化活性.     

碳酸二苯酯与1,4-丁二醇熔融酯交换法合成聚(对亚丁基)碳酸酯的研究

利用TiO2-SiO2(PVP)凝胶基催化剂(TSP),无溶剂条件下,以碳酸二苯酯与1,4-丁二醇为单体,采用常压预聚和真空缩聚两步熔融酯交换法合成了聚(对亚丁基)碳酸酯(PBC),考察了工艺条件,并对PBC的结构及物理性质进行了表征.实验结果表明,最佳工艺条件如下:预聚时间为2 h,预聚温度为220~230℃(N2保护),缩聚温度为220℃,缩聚压力300 Pa,催化剂用量为0.15 wt%.优化条件下,PBC的特性黏数为1.12dL/g,Mn为49000,Mw为101000,PDI为2.07,Tg为-32.32℃,端羟基含量为6.2×10-4mol/g,苯酚残留量为5.26 wt%.在此工艺条件下,通过控制副产物苯酚的蒸出速率及其量,可以实现产品聚合度的可控,且苯酚几乎能够完全回收.     

基于MPS方法的汽泡凝结数值模拟研究

采用移动粒子半隐式(MPS)方法对静止过冷水中单个汽泡的凝结现象进行了数值模拟,研究了不同初始压力和初始直径时饱和蒸汽汽泡凝结过程,获得了凝结过程中汽泡形状、当量直径和压力的变化规律;汽泡初始压力为0.1～0.5MPa,初始直径为2mm、3mm和5mm;过冷水压力为0.1MPa,温度为70℃。结果表明两相界面不存在压差时,凝结过程中汽泡始终保持球形,汽泡当量直径逐渐减小,压力近似不变;相界面存在压差时,凝结过程中汽泡从球形逐渐变为心形、半月形,汽泡当量直径和压力会出现周期性振荡,且初始压力越大振荡幅度越大。     

Low-Threshold Mid-Infrared Optical Parametric Oscillator Using Periodically Poled LiNbO33

We report the generation of tunable mid-infrared optical pulses using all-solid-state pumped optical parametri coscillator in a periodically poled lithium niobate. Several ways were used to lower the threshold, resulting in a mean threshold as low as 6.5mW and an achievement of wavelength conversion in the 2.77-4.04μm spectral range. Continuous tuning range from 2.97 to 3.25μm was achieved. The maximum idler output power of 466mW at the wavelength of 3.41μm was obtained, which represents an optical-to-optical conversion efficiency of 19% from incident pump power to the idler output.     

High－Power Blue Light Generation by External Frequency Doubling of an Optical Parametric Oscillator ＊

We report on an all-solid-state high-power quasi-continuous blue light source by the frequency doubling of asignal wave from an optical parametric oscillator (OPO). A 50-mm-long LiB305 (LBO) crystal is used for theOPO, which is pumped by a diode-pumped Nd:YAG green laser (1OkHz, 50ns). Tunable blue emission in a newnonlinear crystal BiB306 (BiBO) is obtained with a wavelength range from 450 to 495 nm. The average power ofthe signal output is as high as 9.3 W from 924 to 970nm. The maximum output of the blue laser with the secondharmonic walk-off compensation is 1.3W average power at 470nm for 6.2W of OPO signal light at 940nm.