纳米复合全固态聚膦腈电解质

为了进一步提高聚合物电解质的室温离子电导率和锂离子的迁移数,通过对纳米二氧化硅的表面修饰,并采用可聚合的带氧化乙烯-氧化丙烯共聚侧链取代的聚膦腈大单体制备了纳米复合的全固态电解质.通过X射线光电子能谱,扫描电镜,差热扫描分析对纳米复合电解质的性能和形貌进行了分析,并通过交流阻抗考察了电解质与电极间的界面稳定性,用循环伏安表征了电解质的电化学稳定窗口,考察了锂盐含量对电解质离子电导率的影响,测试了电解质的离子电导率随温度的关系,并对锂离子的迁移数进行了测定.研究结果表明,通过纳米复合的方法,提高了聚合物电解质的离子电导率,降低了界面电阻,提高了锂离子迁移率.     

Effect of Poly（Ether Urethane） Introduction on the Performance of Polymer Electrolyte for All-Solid-State Dye-Sensitized Solar Cells

The introduction of poly（ether urethane） （PEUR） into polymer electrolyte based on poly（ethylene oxide）, LiI and I2, has significantly increased the ionic conductivity by nearly two orders of magnitudes. An increment of I3- diffusion coefficient is also observed. All-solid-state dye-sensitized solar cells are constructed using the polymer electrolytes. It was found that PEUR incorporation has a beneficial effect on the enhancement of open circuit voltage VOC by shifting the band edge of TiO2 to a negative value. Scanning
electron microscope images indicate the perfect interfacial contact between the TiO2 electrode and the blend electrolyte.