Structural,morphological, dielectric and magnetic properties of Zn-Zr co-doping yttrium iron garnet

In this study, yttrium iron garnet co-doped with Zn and Zr atoms with a chemical formula Y₃Zn_xZr_xFe_(5−2x)O₁₂ (x = 0.0-0.3) has been successfully prepared by the solid-state reaction method. The effects of doping concentration on the microstructure, crystal structure, magnetic properties, and dielectric properties of Y₃Zn_xZr_xFe_(5−2x)O₁₂ were investigated. The microstructure analysis indicates that co-doping of YIG with Zn and Zr can effectively reduce the grain size of the ceramic. The crystal structure results reveal that the doping concentration of Zn–Zr has substantial influence on the lattice parameters of YIG, such as, increases the lattice constant, crystal cell size, and interplanar spacing. However, the second phase of ZrO₂ appears once x ≥ 0.15. Additionally, the dielectric properties of YIG ferrite can be regulated using this Zn–Zr co-doping method. Zn–Zr co-doping can improve the dielectric stability and reduce the dielectric loss at high temperature. The magnetization measurement shows that the saturation magnetization is stabilized at x < 0.15, and the magnetic loss is decreased with the increase in the doping concentration. Overall, the findings show that the ceramic with x = 0.1 exhibits better properties included high saturation magnetization (24.607 emu/g), low magnetic loss (0.0025 @ 1 MHz), and relatively low dielectric loss (496 @ 400°C).     

基于振动参数的钻井井架安全承载力评定

通过井架结构振动理论、有限元分析和实验室简易模型的试验研究，提出了以振动频率为基准，载荷下降系数为依据诊断钻井井架结构安全承载能力的方法。根据井架的具体结构形式和受力特征，将井架简化成一根沿长度上质量均匀分布、刚度恒定的简支梁，用振动理论推导出了井架固有频率的平方与作用载荷之间存在着线性关系，并通过有限元分析对这一关系进行了验证；提出了通过测试井架在两种不同栽荷作用下的固有频率推算井架临界承载并以此评定井架安全承载能力的方法；在实验室内制作了与A型井架相类似的模型，进行了逐级载荷下的固有频率测试，分析总结出适用于井架现场评定的具体方法，最后应用此方法对现场在役井架进行了测试与安全承载能力评定。该评定方法为井架测试、安全评定提供了一个新的发展方向，对保证钻井安全将起到重要的作用。     

燃煤电厂污泥掺烧技术及其研究进展

随着我国城市化进程的加快,城市生活污水量急剧增加。污泥作为污水处理后的附属产品,对环境影响极大,因此污泥的无害化、减量化、资源化处理迫在眉睫。燃煤电厂污泥掺烧是实现最大体积减少污泥的处置方法之一。发达国家和地区中,污泥掺烧工艺已逐渐成熟,在燃煤电厂的应用更为广泛。综述了污泥掺烧技术的现状,分析了燃煤电厂掺烧污泥造成的影响,并讨论了燃煤电厂污泥掺烧技术的未来发展方向。     

钠离子电池健康状态预测

钠离子电池健康状态(SOH)预测对于电池优化管理有重要意义,但由于钠离子电池老化机理复杂,影响因素众多,精准SOH预测挑战巨大.为此,本研究从健康状态时序测量数据出发,提出了基于双指数模型的粒子滤波法(DEM-PF)和基于小波分析的高斯过程回归法(WA-GPR),以实现钠离子电池单步SOH和剩余可用寿命(RUL)预测.前者直接采用双指数函数构建时序SOH数据模型,并结合PF算法进行模型参数更新;后者采用小波分析实现时序SOH数据多尺度解耦,采用GPR构建各尺度数据模型并进行融合后实施预测.实验结果表明,相比DEM-PF方法,WA-GPR方法的单步SOH和RUL预测效果更好,单步SOH预测均方根误差为0.8％,RUL预测误差最小为3次循环,从而为钠离子电池管理提供有效支撑.     

考虑风险偏好的快速频率响应备用容量规划

增设快速频率响应备用容量,为威胁系统频率安全事件设立备用规划方案,是应对电力系统频率稳定新形势的重要手段.首先,考虑一次调频事故拦截的潜在收益,采用风险偏好成本收益分析模型作为小概率极端事件的风险价值评估依据;基于序贯蒙特卡洛方法建立常规机组、高压直流传输线路、风电机组的运行状态模型,并将故障集输入所提的系统频率仿真模型中,对功率扰动实现系统频率追踪及下降最低点捕捉,进而获得满足快速频率响应备用容量;兼顾可靠性收益与备用综合成本,定义快速频率响应备用成本收益模型,并提出相应的备用方案可行性校验方法.算例结果表明:所提快速频率响应备用容量规划方案能有效的避免小概率极端事件被同质化,且极端事件概率越小,备用需求越高.     

微波共沉淀法制备锂离子电池正极材料LiNi0.8Co0.2O2

采用微波共沉淀法合成了制备LiNi0.8Co0.2O2的前驱体球形α-Ni0.8Co0.2(OH)2，将其与LiOH·H2O混合，在氧气氛围下，用不同的烧结温度分别烧结10小时获得LiNi0.8Co0.2O2正极材料。用XRD、SEM对所制备的正极材料进行结构和形貌分析，用恒流充放电测试材料的电化学性能。结果表明，烧结温度对材料结构和电化学性能影响较大，所合成材料均具有α-NaFeO2的层状结构，烧结温度越高材料结晶越完善。900℃烧结的LiNi0.8Co0.2O2材料初级颗粒结晶最完善而且其二次团聚粒子的平均粒径最小，其表现出的电化学性能也最好，首次放电容量为189.1mA·h·g-1，首次循环放电效率达到92.5%。30循环后放电容量保持在148 mA·h·g-1，显示出较好的循环稳定性。     

水文监测在未来科技城海绵城市建设示范区中的作用

评价海绵城市建设效果的主要标准是径流系数考核.水文监测与服务是海绵城市建设的重要组成部分,通过雨量、水位及流量等数据的实时采集和径流系数的计算,为海绵城市建设提供完善的专业分析和预测预报服务,为海绵城市建设方案的制定、绩效评价与考核提供科学依据.     

吸波材料的研究现状与发展趋势

介绍了吸波材料的吸波原理，系统总结了目前各种类型吸波材料的研究和应用现状，指出了吸波材料的研究和发展趋势。     

Preparation and characterization of SO42-/TiO2 and S2O82-/TiO2 catalysts

Nanosized solid superacids SO₄ ²⁻/TiO₂ and S₂O₈ ²⁻/TiO₂, as well as MCM-41-supported SO₄ ²⁻/ZrO₂, were prepared. Their structures, acidities, and catalytic activities were investigated and compared using XRD, N₂ adsorption-desorption, and in situ FTIR-pyridine adsorption, as well as an evaluation reaction with pseudoionone cyclization. The results showed that SO₄ ²⁻/TiO₂ and S₂O₈ ²⁻/TiO₂ possess not only nanosized particles with diameters < 7.0 nm, a BET surface greater than 140 cm²/g and relatively regular mesostructures with pores around 4.0 nm, but also a pure anatase phase and strong acidity. Different from the Lewis acid nature of SO₄ ²⁻/ZrO₂/MCM-41, SO₄ ²⁻/TiO₂ and S₂O₈ ²⁻/TiO₂ exhibit mainly Bronsted acidities. The strongest Bronsted acid sites were produced on SO₄ ²⁻/TiO₂ promoted with H₂SO₄, while Lewis acid sites on S₂O₈ ²⁻/TiO₂ even stronger than those on SO₄ ²⁻/ZrO₂/MCM-41 were generated when persulfate solution was used as sulfating agent. Because of their distinct acid natures, SO₄ ²⁻/TiO₂ and S₂O₈ ²⁻/TiO₂ exhibited catalytic activities for the cyclization of pseudoionone that were much higher than that of SO₄ ²⁻/ZrO₂/MCM-41. It can be concluded that the existence of more Br?nsted acid sites was favorable for proton participation in the cyclization reaction. Translated from Journal of Chemical Engineering of Chinese Universities, 2006, 20(2): 239–244 [译自: 高校化学工程学报]     

Sensor Fault Diagnosis and Unknown Disturbances Estimation of High Switching Frequency Single-phase PWM Rectifier

International Journal of Control, Automation and Systems - The fault and disturbances estimation has an important role in the modern traction railway system. This paper proposes a unique method for...