One step method of structure engineering porous graphitic carbon nitride for efficient visible-light photocatalytic reduction of Cr(Ⅵ)

Porous g-C3N4 nanosheets (PCN) were prepared by the nickel-assisted one-step thermal polymerization method.Hydrogen (H2) which was produced by the reaction between nickel (Ni) foam and ammonia (NH3) defined the structure and properties of PCN.During the formation of PCN,the participation of H2 not only enhanced the spacing between layers but also boosted the specific surface area that more active sites were exposed.Additionally,H2 promoted pores formation in the nanosheets,which was beneficial to the transfer of photons through lamellar structure and improved the absorption efficiency of visible light.Remarkably,the obtained PCN possessed better Cr(Ⅵ) photocatalytic reduction efficiency than pure g-C3N4.The reaction rate constant (k) of PCN (0.013 min-1) was approximately twice that of bare g-C3N4 (0.007 min-1).Furthermore,the effects of original pH and concentration of Cr(Ⅵ)-containing solution on removal efficiency of Cr(Ⅵ) were explored.A possible photocatalytic mechanism was proposed based on the experiments of radical scavengers and photoelectrochemical characterizations.     

Technical advancements and significance of circumlunar return and reentry spacecraft

As one of the vital steps in the 3rd phase of China’s lunar exploration program(CLEP),the circumlunar return and reentry spacecraft,developed by China Academy of Space Technology(CAST),is used to demonstrate the key technologies of hyper-speed return and reentry spacecraft.The system configuration and flight process are presented in this paper,as well as the analysis of mission characteristics,the key technologies and the technical advancement during the RD progress.The significance of circumlunar return and reentry spacecraft is given at the end.     

苯乳酸抑制链格孢霉作用靶位的分析

以从自然腐败的樱桃上分离的链格孢霉（Alternaria sp.）LD3.0086为指示菌，研究苯乳酸对链格孢霉的主要抑制作用靶位。应用分光光度法测定苯乳酸对链格孢霉的最小抑菌浓度，通过卡尔科弗卢尔荧光增白剂染液（calcofluor white，CFW）染色观察苯乳酸对菌丝顶端生长的破坏作用，利用扫描电子显微镜和透射电子显微镜观察链格孢霉的超微结构变化，通过测定苯乳酸作用前后链格孢霉上清液中N-乙酰葡萄糖胺质量浓度变化研究苯乳酸对菌丝细胞壁的破坏作用，应用荧光双染色法观察苯乳酸对链格孢霉菌丝细胞膜的损伤作用。结果表明，12.5 mmol/L的苯乳酸能有效抑制链格孢霉的生长；与对照组（无菌水处理）相比，苯乳酸处理后链格孢霉顶端生长细胞无明显形变，经12.5 mmol/L苯乳酸处理的链格孢霉上清液中N-乙酰葡萄糖胺质量浓度基本不变；苯乳酸处理24 h，链格孢霉菌丝细胞壁表面无明显损伤，细胞内结构发生明显变化；苯乳酸短时间（4 h）处理链格孢霉，菌丝细胞膜仍较为完整，加入苯乳酸较长时间（8 h）后细胞膜发生破裂。综合分析可知，苯乳酸对链格孢霉的主要作用靶位应不是菌丝体的细胞壁和细胞膜，而是在菌丝体内部，通过破坏菌丝内部细胞器结构或引起细胞内的生化反应，从而抑制链格孢霉的生长和繁殖，发挥抑菌活性。     

高端轴承钢专利技术发展趋势

以高端轴承钢全球技术专利数据为基础,着重从专利申请基本趋势、主要技术产出地和目标市场、技术分布以及主要专利申请人等几个角度,宏观分析了目前全球范围内高端轴承钢的专利布局情况。重点研究了国内相对而言属于研究空白点的专利技术——航空航天领域高端轴承钢专利技术,并对其耐高温性能改善和韧性改善两方面的技术研究进行了详细地梳理和解读,以期从微观角度进一步分析目前全球高端轴承钢的专利布局情况。     

介质阻挡放电低温等离子体技术降解废水中污染物研究现状及进展

介质阻挡放电(DBD)因其产生的低温等离子体能量密度高且能量体积大,可在温和的反应条件下无选择性地降解废水中大分子污染物,且反应高效、彻底,而被广泛应用于印染、制药、化工、农业等行业废水中难降解物质的实验室研究中。综述了DBD特性以及低温等离子体技术处理废水中污染物的作用过程和机理,总结和分析了影响污染物降解效果的关键因素,提出了尚未解决的技术难点和未来发展方向,以期为此技术的深度优化起到借鉴指导作用。     

松香基阴离子表面活性剂的研究进展

松香是一种重要的天然化工原料,无毒、可再生,应用十分广泛。以松香为原料合成表面活性剂是其精深加工的主要途径之一,特别是松香基阴离子表活性剂,由于研究历史悠久、理化性质独特、应用前景广阔,吸引了众多研究者的目光。本论文总结了松香基阴离子表面活性剂的研究进展与应用,并对其研究前景进行了展望。     

湍流进流诱发的二维水翼振动噪声特性研究

为研究螺旋桨流噪声,以螺旋桨的基本构型单位二维翼型为研究对象,研究其在不同工况下的振动噪声规律。以Lighthill声类比理论为基础,应用计算流体力学软件CFX和声学仿真软件LMS Virtual Lab分别模拟在不同工况下翼型的流场和声场分布。取翼型非定常脉动力作为声源,然后采用边界元方法分别求解翼型流噪声和振动噪声。结果表明,噪声水平随速度和翼型攻角的变化呈现较为明显的规律;相比考虑翼型振动时的振动噪声,忽略翼型振动影响的情况下流噪声水平偏大。     

A computer aided design method for car form and its application based on shape parameters

In the early design stage, automotive modeling should both meet the requirements of aesthetics and engineering. Therefore, a vehicle CAD (computer aided design) model that can be easily adjusted by feedbacks is necessary. Based on CE-Bézier surface, this paper presents a set of algorithms for parametric segmentation and fairing surface generation in a car model. This model is defined by a simplified automotive template and relevant control points, shape parameters and segmentation parameters, which can be modified to alter the car form efficiently. With this model and the corresponding adjustment method, more than fifty various vehicle models are established in this research according to different parameters. And two methods for calculating similarity index between car models are constructed, which are suitable for brand design trend analysis and modelling design decisionmaking.     

矩阵式返向器与扁圆形返向器的动力学分析

详细介绍了五次抛物线型回珠曲线的设计计算方法,通过Creo 3.0建立了含矩阵式返向器和含扁圆形返向器的滚珠丝杠副模型;在ADAMS中对两种滚珠丝杠副模型进行了4种工况下的动力学仿真;借助于MATLAB对比分析了两种返向器在不同的工况条件下,滚珠对其碰撞力的大小及变化规律。研究表明:相同工况下矩阵式返向器受到的碰撞力更大,但含矩阵式返向器的滚珠丝杠副的结构更加紧凑,可为含矩阵式返向器的滚珠丝杠副应用和结构改进提供参考。