有机-无机压电材料TMCM-MnCl3的研究

有机-无机压电材料是一种分子铁电体，具有柔性、结构灵活、易成膜、全液相合成及环保节能等优点，可满足新一代薄膜器件及可穿戴设备的需求。该文以三甲基卤代甲基铵(TMXM, X=F, Cl, Br)为有机部分，MnCl₂为无机部分，通过溶液蒸发法制备了具有钙钛矿分子结构的有机-无机压电材料三甲基氯三氯化锰(TMCM-MnCl₃)，并对其分子结构组成、压电、热学、声学及铁电性进行表征。结果表明，TMCM-MnCl₃的压电常数为106 pC/N，居里温度为130 ℃，声阻抗值约为16.5 MRayl，低于压电陶瓷PZT-4(大于33 MRayl)，具有广阔的应用前景。     

基于推理注意力机制的二阶段网络图像修复

现有的图像修复方法在处理大面积缺失或高度纹理化的图像时，通常会产生扭曲的结构或与周围区域不一致的模糊纹理，无法重建合理的图像结构。为此，提出了一种基于推理注意力机制的二阶段网络图像修复方法。首先通过边缘生成网络生成合理的幻觉边缘信息，然后在图像补全网络完成图像的重建工作。为了进一步生成视觉效果更逼真的图像，提高图像修复的精确度，在图像补全网络采用推理注意力机制，有效控制了生成特征的不一致性，从而生成更有效的信息。所提方法在多个数据集上进行了实验验证，结果表明该图像修复方法的结构相似性指数达到了88.9%，峰值信噪比达到了25.56 dB，与现有的图像修复方法相比，该方法具有更高的图像修复精确度，生成的图像更逼真。     

Effect of PyC interface phase on the cyclic ablation resistance and flexural properties of two-dimensional Cf/HfC composites

Composites based on hafnium carbide and reinforced with continuous naked carbon fiber with and without PyC interface were prepared at low temperature by precursor infiltration and pyrolysis and chemical vapor deposition method. The microstructure, mechanical property, cyclic ablation and fiber bundle push-in tests of the composites were investigated. The results show that after three times ablation cycles, the bending strength of samples without PyC interface decreased by 63.6 %; the bending strength of samples with PyC interface only decreased by 37.8 %. The force displacement curve of the samples with PyC interface presented a well pseudoplastic deformation state. The mechanical behavior difference of two kinds of composites was due to crucial function of PyC interface phase including protection of fiber and weakening of fiber/matrix interface.     

Recent advances during CH4 dry reforming for syngas production: A mini review

Given the continuing issues of environment and energy, methane dry reforming for syngas production have sparked interest among researchers, but struggled with the process immaturity owing to catalyst deactivation. This review summarizes the recent advances in the development of efficient and stable catalysts with strong resistance to coking and metal sintering, including the application of novel materials, the assessment of advanced characterizations and the compatibility to improved reaction system. One feasible option is the crystalline oxide catalysts (perovskite, pyrochlore, spinel and LDHs), which feature a fine metal dispersion and surface confinement effect via a metal exsolution strategy and exhibit superior reactivity and stability. Some new materials (h-BN, clays and MOFs) also extend the option because of their unique morphology and microstructure. It also is elaborated that progresses were achieved in advanced characterizations application, leading to success in the establishment of reaction mechanisms and attributions to the formed robust catalysts. In addition, the perspective described the upgrade of reaction system to a higher reaction efficiency and milder reaction conditions. The combination of efficient reaction systems and robust catalysts paves a way for a scaling-up application of the process.     

建筑工业化产品的系统论与装配式住宅设计

从建筑工业化产品的系统论出发,聚焦建筑设计方法与策略,结合装配式建筑系统集成特征,提出装配式建筑设计七个方面的设计策略,并分析其思路和相关手法.     

Effects of non-thermal plasma treating wheat kernel on the physicochemical properties of wheat flour and the quality of fresh wet noodles

The effects of non-thermal plasma (NTP) on the physicochemical properties of wheat flour and the quality of fresh wet noodles ( FWN) were investigated. The results showed that NTP effectively decreased the total plate count (TPC), yeast and mould count (YMC) and Bacillus spp. in wheat flour. Wet gluten contents and the stability time reached the maximum when treated for 20 s. The viscosity of starch increased significantly after treatment due to the increased of damaged starch. The contents of secondary structure were altered to some extent, which was because that the ordered network structure of gluten protein broken. Furthermore, compared with the control, texture properties of FWN were enhanced significantly at 20 s, and the darkening rate of FWN was greatly inhibited due to the low polyphenol oxidase (PPO) activity. Consequently, the most suitable treatment was 500 W for 20 s, providing a basis for the application of NTP in flour products.     

基于堆叠稀疏去噪自动编码网络与多隐层反向传播神经网络的铣刀磨损预测模型

刀具磨损状态是机械加工过程中需考虑的重要因素之一.针对铣刀磨损的在线预测问题,建立了一种基于深度学习的铣刀磨损预测模型.首先,将采集到的铣刀切削时的振动信号进行小波去噪后,利用快速傅里叶变换和小波包分解等技术提取时域、频域及时频域上的特征参数,并根据相关性分析从中筛选出合格的特征参数合并为特征向量,以此作为堆叠稀疏去噪自动编码网络(SSDAE)的含噪样本.其次,利用特征后处理的方式对已经筛选出的特征参数进行单调不递减及平滑处理,并将其作为SSDAE的无噪样本来训练该网络.然后,将经过SSDAE降维后的特征向量作为多隐层反向传播神经网络(BPNN)的输入,以这些特征对应的实际铣刀的磨损量作为标签对该网络进行拟合训练.最后,对训练好的模型进行实验验证,通过测试数据集和人为加入噪声的测试数据集的对比,结果显示所提模型不仅具有较高的预测精度,还具有较高的鲁棒性.     

Effects of Cu on the corrosion behavior and microstructure of Mg–Zn–Ca bulk metallic glass

For the purpose of developing biodegradable magnesium alloys with suitable properties for biomedical applications, Mg–Zn–Ca–Cu metallic glasses were prepared by copper mold injection methods. In the present work, the effect of Cu doping on mechanical properties, corrosion behavior, and glass-forming ability of Mg₆₆Zn₃₀Ca₄ alloy was studied. The experimental findings demonstrated that the incorporation of Cu decreases the corrosion resistance of alloys, but increases the microhardness and degradation rate slightly. However, the addition of a trace amount of Cu can make the samples have antibacterial properties. Therefore, Mg–Zn–Ca–Cu has great advantages in clinical implantation and is the potential implant material.