Synthesis and photopolymerization of novel,highly reactive phosphonated-urea-methacrylates for dental materials

An urea methacrylate (1) and two phosphonated methacrylates (2–3) were synthesized from 2-isocyanatoethyl methacrylate (IEM) and benzyl amine (1), diethyl aminomethylphosphonate (2) and diethyl amino(phenyl)methylphosphonate (3). Their photopolymerization rates are notably higher than commercial monomers, despite the presence of only one double bond. Their polymerization rates follow the order 1 ～ 2 > 3 ～ triethylene glycol dimethacrylate (TEGDMA) > 2-hydroxyethyl methacrylate (HEMA). A tendency toward high crosslinking density during thermal bulk polymerizations, low oxygen sensitivity and high conversions with benzophenone during photopolymerization indicated the importance of hydrogen abstraction/chain transfer reactions. It was found that the addition of the monomers to HEMA significantly increased its polymerization rate, proving their utility as replacements for TEGDMA as reactive diluents for 2,2-bis[4-(2-hydroxy-3-methacryloyloxy propyloxy) phenyl] propane (Bis-GMA). Copolymer systems containing 2 and 3 showed improved T_g values compared to Bis-GMA/TEGDMA systems.     

Inhomogeneous flow model of natural convection,entropy generation,and heatlines visualization in wavy I-shaped enclosure with rectangular heater

The present investigation is on examination of the natural convection and entropy generation considering the heatlines visualization of nanofluid I-shaped enclosure with two corrugated walls considering inner rectangular heater of three different heights. The influence of Brownian motion along with thermophoresis had been implemented using Inhomogeneous two-phase model of nanofluid. The governing equations were solved numerically using COMSOL software. Influence of Rayleigh number $$, Buoyancy ratio number $$, Lewis number $$, heater length $$. The results indicate that the influence of Lewis number on heat transfer bettering is stronger at high Rayleigh number $$ while its impact is negligible at a lower value of Rayleigh number (conduction mode). In addition, the total entropy generation gets its highest value at Lewis number $$. Bejan number, fluid flow strength and heat rate increase as the rectangular heater height increases. Also, higher heat transfer augmentation is taken when the heater height is $$ while increasing the heater height to $$ leads to more total entropy generation. The impact of heater height on total entropy generation is highly affected by Rayleigh number as increasing the heater height from $$ into $$, total entropy generation increases by $$ at $$ while it increases by $$ at $$.     

盐胁迫环境下腐植酸类物质对小麦生长及矿物营养吸收的影响

对在不同浓度的盐胁迫条件下,叶面喷施液态腐植酸和土壤施用腐植酸类物质对小麦作物生长和矿物营养吸收的影响进行了研究。通过添加不同量的NaCl得到不同的盐浓度环境。腐植酸类物质在作物种植前一个月施用,液态腐植酸在种苗发芽后20d和35d喷施于小麦叶面。腐植酸类物质的施用量为0、1g/kg、2g/kg,液态腐植酸的浓度为0、0.1%、0.2%。盐度对小麦生长具有负面影响,它会降低小麦对除Na、Mn以外的矿物营养的吸收,影响小麦干重。通过在土壤施用腐植酸类物质可以增加小麦对N的吸收,叶面施用腐植酸可增加其对P、K、Mg、Na、Cu和Zn的吸收。研究结果显示：在土壤中施用腐植酸类物质,不同盐浓度与施用量之间存在较好的相关性,但叶面喷施时盐度和喷施量之间相关性并不明显。在盐胁迫环境的影响下,叶面喷施腐植酸的初始浓度和土壤中施用的腐植酸类物质的初施量都增加了作物对营养元素的吸收。     

Experimental and numerical modelling of the three-dimensional incompressible flow behaviour in the near wake of circular cylinders

An experimental investigation was carried out to study the structure of the flow field around three-dimensional circular cylinders. The study of the flow field around an obstacle was performed in a wind tunnel using a particle image velocimetry (PIV) system. The flow of a fluid around an obstacle with a different velocity to the oncoming flow was examined. The results showed the dependence of the flow structure around the obstacle on its Reynolds number, and the spacing between a pair of obstacles. Detailed quantitative information of turbulence parameters in the vicinity of the obstacle was attained. Extensive wind tunnel experimental results are presented and compared with numerical simulation. A three-dimensional numerical model with Reynolds stress model (RSM) turbulence and a non-uniform grid system were used to examine the effects of a single cylinder and two cylinders in tandem on the flow. The principal objective was to analyse three-dimensional flow past a single cylinder and two circular cylinders placed in tandem by combining the application of a PIV experimental technique and an RSM turbulence model.For the case of two cylinders in tandem, the flow patterns are characterized in the gap region as a function of the distance between the cylinders. A good level of agreement was found between the experimental results of flow and numerical simulation.