Thickening of molten white chocolates during storage

When white chocolates are kept molten in storage tanks, problems can arise due to uncontrolled thickening and solidifying of the chocolate mass. The thickening of molten white chocolate was simulated on a laboratory scale using a rotational rheometer under static conditions, interrupted by short shear periods to measure the increasing viscosity. Several chocolates having different dairy components and fat contents were investigated for their tendency to thicken. In addition, sorption isotherms for white chocolates were obtained using dynamic vapour sorption at different temperatures. The sorption isotherms showed the presence of amorphous lactose in all the chocolates that were manufactured from milk powders. Moisture that is released during the crystallization of amorphous lactose causes stickiness and agglomeration of the neighbouring particles and starts the thickening process. This process is highly temperature-dependent. On elevating the temperature the lactose crystallization occurs at lower relative humidities. In order to reduce the tendency of white chocolate to thicken, a high free-fat level should be maintained, based on a high total fat content and on the use of high free-fat milk powders, preferably roller-dried whole milk powders or the combination of skimmed milk powder and anhydrous milk fat.     

Numerical investigation of the oxy-fuel combustion in large scale boilers adopting the ECO-Scrub technology

The present paper presents a three-dimensional numerical investigation of a pulverized-fuel, tangentially-fired utility boiler located at Florina/Greece under air, partial and full oxy-fuel conditions. Heat and mass transfer and major species concentration, such as CO₂, CO and O₂ are calculated; whilst the results for the reference air case scenario studied are in good agreement with the corresponding operational data measured in the plant, both for combustion calculations and NO_x emissions. Results for the partial and full oxy-fuel operation scenarios are in line with similar experimental and numerical investigations found in the recent literature. This numerical investigation of oxy-fuel conditions scenarios prior to their implementation under real scale conditions demonstrates the utmost of its importance, since significant results regarding the operation of a boiler in terms of lignite particle trajectories and burning rates are attained. Furthermore, NO_x calculations have been performed for all the examined case studies.     

The Marine Polysaccharide Ulvan Confers Potent Osteoinductive Capacity to PCL-Based Scaffolds for Bone Tissue Engineering Applications

Hybrid composites of synthetic and natural polymers represent materials of choice for bone tissue engineering. Ulvan, a biologically active marine sulfated polysaccharide, is attracting great interest in the development of novel biomedical scaffolds due to recent reports on its osteoinductive properties. Herein, a series of hybrid polycaprolactone scaffolds containing ulvan either alone or in blends with κ-carrageenan and chondroitin sulfate was prepared and characterized. The impact of the preparation methodology and the polysaccharide composition on their morphology, as well as on their mechanical, thermal, water uptake and porosity properties was determined, while their osteoinductive potential was investigated through the evaluation of cell adhesion, viability, and osteogenic differentiation of seeded human adipose-derived mesenchymal stem cells. The results verified the osteoinductive ability of ulvan, showing that its incorporation into the polycaprolactone matrix efficiently promoted cell attachment and viability, thus confirming its potential in the development of biomedical scaffolds for bone tissue regeneration applications.     

Topological Based Scan Matching – Odometry Posterior Sampling in RBPF Under Kinematic Model Failures

Rao-Blackwellized Particle Filters (RBPF) have been utilized to provide a solution to the SLAM problem. One of the main factors that cause RBPF failure is the potential particle impoverishment. Another popular approach to the SLAM problem are Scan Matching methods, whose good results require environments with lots of information, however fail in the lack thereof. To face these issues, in the current work techniques are presented to combine Rao-Blackwellized particle filters with a scan matching algorithm (CRSM SLAM). The particle filter maintains the correct hypothesis in environments lacking features and CRSM is employed in feature-rich environments while simultaneously reduces the particle filter dispersion. Since CRSM’s good performance is based on its high iteration frequency, a multi-threaded combination is presented which allows CRSM to operate while RBPF updates its particles. Additionally, a novel method utilizing topological information is proposed, in order to reduce the number of particle filter resamplings. Finally, we present methods to address anomalous situations where scan matching can not be performed and the vehicle displays behaviors not modeled by the kinematic model, causing the whole method to collapse. Numerous experiments are conducted to support the aforementioned methods’ advantages.     

CMOS tuners for mobile TV

Digital video reception is emerging as the latest feature toward multimedia-enriched handheld devices. Mobile battery-operated devices require small-size tuners that consume low power and are amenable to single-chip integration with the baseband demodulator. Following an overview of the system and circuit-level implementation challenges of mobile TV standards such as DVB-H and T-DMB, this article presents a dual-band direct conversion tuner for DVB-H. Architecture and circuit trade-offs are discussed, and detailed measurements are presented. The tuner occupies 9.7 mm² and achieves a 4 dB NF at both UHF and L-band, eliminating the need for an external LNA. By using a fractional-TV synthesizer both 470-890 MHz and 1.4-1.8 GHz bands are supported, while achieving an integrated phase noise of less than -41 dBc. Sixth-order low-pass filters support channel bandwidths from 4 to 10 MHz     

Merging high doxorubicin loading with pronounced magnetic response and bio-repellent properties in hybrid drug nanocarriers

Hybrid magnetic drug nanocarriers are prepared via a self-assembly process of poly(methacrylic acid)-graft-poly(ethyleneglycol methacrylate) (p(MAA-g-EGMA)) on growing iron oxide nanocrystallites. The nanocarriers successfully merge together bio-repellent properties, pronounced magnetic response, and high loading capacity for the potent anticancer drug doxorubicin (adriamicin), in a manner not observed before in such hybrid colloids. High magnetic responses are accomplished by engineering the size of the magnetic nanocrystallites (～13.5 nm) following an aqueous single-ferrous precursor route, and through adjustment of the number of cores in each colloidal assembly. Complementing conventional magnetometry, the magnetic response of the nanocarriers is evaluated by magnetophoretic experiments providing insight into their internal organization and on their response to magnetic manipulation. The structural organization of the graft-copolymer, locked on the surface of the nanocrystallites, is further probed by small-angle neutron scattering on single-core colloids. Analysis showed that the MAA segments selectively populate the area around the magnetic nanocrystallites, while the poly(ethylene glycol)-grafted chains are arranged as protrusions, pointing towards the aqueous environment. These nanocarriers are screened at various pHs and in highly salted media by light scattering and electrokinetic measurements. According to the results, their stability is dramatically enhanced, as compared to uncoated nanocrystallites, owing to the presence of the external protective PEG canopy. The nanocarriers are also endowed with bio-repellent properties, as evidenced by stability assays using human blood plasma as the medium.     

Technical assessment of LNG based polygeneration systems for non-interconnected island cases using SOFC

Liquefied Natural Gas (LNG) is one of the most promising fuels with high calorific value and low specific GHG emissions that offers several advantages as an energy carrier for power generation. In this paper, a novel polygeneration concept based on LNG fired plant for power, cooling and drinking water production in island systems is presented. Two Solid Oxide Fuel Cell based energy systems (one simple SOFC and another hybrid concept of SOFC combined with GT) are modelled in Aspen Plus and compared with two conventional combustion based technologies (internal combustion engine and Gas Turbine Combined Cycle) in terms of overall efficiency. Furthermore, a Low Temperature Multi-Effect Distillation (LT-MED) plant was modelled and coupled with the energy systems to evaluate the waste heat recovery potential for desalinated water production. Moreover, three concepts for cold recovery from the LNG regasification plant were presented and modelled. Process simulations results revealed that the hybrid SOFC-GT plant is the best solution in terms of energy efficiency and the heat recovery of the exhaust gas in a LT-MED unit is a promising option for drinking water production with almost no energy cost. Last, from exergetic point of view, the cryogenic energy storage (CES) via the production of liquid air was evaluated as the best option for waste cold utilization during LNG regasification.