Structural dependence of microwave dielectric properties of spinel structured Mg2(Ti1-xSnx)O4 solid solutions: Crystal structure refinement,Raman spectra study and complex chemical bond theory

Mg₂(Ti_1-xSn_x)O₄ (x?=?0–1) ceramics were prepared through conventional solid-state method. This paper focused on the dependence of microwave dielectric properties on crystal structural characteristics via crystal structure refinement, Raman spectra study and complex chemical bond theory. XRD spectrums delineated the phase information of a spinel structure, and structural characteristic of these compositions were achieved with the help of Rietveld refinements. Raman spectrums were used to depict the correlations between vibrational phonon modes and dielectric properties. The variation of permittivity is ascribed to the Mg₂(Ti_1-xSn_x)O₄ average bond covalency. The relationship among the B-site octahedral bond energy, tetrahedral bond energy and temperature coefficient are discussed by defining on the change rate of bond energy and the contribution rate of octahedral bond energy. The quality factor is affected by systematic total lattice energy, and the research of XPS patterns illustrated that oxygen vacancies can be effectively restrained in rich oxygen sintering process. Obviously, the microwave dielectric properties of Mg₂(Ti_1-xSn_x)O₄ compounds were obtained (${\epsilon }_r$= 12.18, $Q\times f$?=?170,130?GHz, ${\tau }_f$?=??53.1?ppm/°C, x?=?0.2).     

粮情智能测控系统的研制

本文介绍了作者研制开发、经过粮库试验的粮情智能测控系统的系统结构，并对系统中有特色的部分作了进一步的分析。     

铸造Al-5Cu合金准固态断裂行为的研究

采用SEM观察手段并结合EDX分析 ,在合金的准固态区 ,通过观察Al 5Cu Mn合金准固态拉伸和热裂应力测试试样的断口形貌 ,研究了Ti、Ce等合金元素及其交互作用对Al 5Cu Mn合金准固态断裂行为的影响及其影响机理。通过对试验合金准固态力学性能的测试和大量SEM断口的观察分析研究 ,结果表明 ,Al 5Cu Mn中添加Ti元素可明显提高合金抗热裂能力 ,主要是由于其良好的细化晶粒效果 ;适量Ce元素的加入 ,不仅可细化晶粒 ,而且其在晶间富集形成的化合物还可有效改善低熔点共晶反应在准固态区的力学行为 ,对减小热裂倾向非常有利 ;Ti和Ce的综合作用对合金抗热裂水平的提高比单一元素更有效 ;热裂的产生首先表现为枝晶枝臂的屈服 ,其后的扩展则表现为脆性断裂占优的穿晶、沿晶混合型特征     

冲击荷载作用下热处理花岗岩动态力学特性研究

为研究冲击速度和热处理温度对黑云母花岗岩动态力学特性的影响,利用改进的霍普金森压杆系统对25~800 ℃共9个温度等级的热处理试样分别进行3种弹速下的冲击压缩试验。试验结果表明：随着冲击速度的增加,25~700 ℃热处理试样的应力—应变曲线由“Ⅱ型”转变为“Ⅰ型”,而800 ℃热处理试样均表现出“Ⅰ型”应力—应变曲线特征。同一温度热处理下试块的峰值应力、应变和平均应变均随动荷载的升高而增大。相同的冲击速度下,300 ℃热处理试样的动力学性能有所改善,500 ℃后试样的动力学性能开始逐渐劣化。同一温度热处理试样的破碎程度随冲击速度的增加而增加;相同冲击速度下,热处理试样的破碎程度随温度的升高先减弱后增强。     

冲击荷载下的新浇混凝土损伤特性及强度试验研究

以新浇混凝土养护过程会受到各类工程振动的作用与影响为工程背景,结合静载试验与冲击动载试验,得出冲击荷载影响下新浇混凝土的强度随龄期的变化规律。通过基于Weibull分布的统计损伤模型得出混凝土关于龄期的动态损伤本构模型。采用SHPB压杆装置进行混凝土试件破坏试验,得出在混凝土不同龄期的冲击动载下,混凝土抗压强度与静载下抗压强度的比值均为2:1左右;随着龄期的增长,混凝土试件受冲击破坏的破碎程度越来越小。采用SHPB压杆装置对不同龄期的混凝土做加载损伤试验,得出了冲击荷载下混凝土最薄弱龄期区段及其强度降低率达到峰值的龄期。     

Research of quasi-solid fracture behavior of casting Al-4.5Cu alloys

The influencing mechanisms of elements Ti and Ce and their interactions on fracture behaviors of casting alloys Al-4.5Cu-0.6Mn were studied by observing tensile fracture behavior in quasi-solid zone under SEM and EDX instruments.The results indicate that the resistance stress against hot cracking can be improved obviously by addition of Ti, because of its grain refining function. It is also found that, when Ce is added into the alloys, besides its effect in refining crystalline, the mechanical behavior of lower melting point eutectic phase in quasi-solid zone can be improved efficiently by some compounds with Ce formed and deposited between dendrites. Therefore, a coiligating effect of Ti and Ce on improving resistance stress against hot cracking is more efficient than that only single alloy element is applied. When hot cracking occurs, grains yield at first, and then crack spreads. Both inter-grain and trans-grain fractures are observed, but the major fracture manner is brittleness.     

泡沫金属制备方法及其研究概况

回顾国内、外泡沫金属制备方法的发展概况 ,对各种制备方法加以概述并分析其优、缺点。从应用前景和工业化生产的可行性来看 ,铸造法制备方式最为经济和可行。泡沫金属制备的最新发展趋势是大规格板材及块材材料的制备和开发。应该加强泡沫金属制备技术的基础理论研究     

基于多因素、多层次评判的多灾种下城市安全韧性评价指标研究

近年来的城市安全韧性研究基于灾情演变和城市空间元素相互影响的视角,突破了传统防灾中仅专注于城市建筑工程和设施等硬件抵抗能力的局限,着眼于城市功能在灾害情境下的运维、保障需求,以提升城市应对多灾种威胁的综合应对能力和恢复能力为目标.本研究通过城市承灾体时空特征和防灾韧性要素解析,建立了城市安全韧性表征的关联逻辑.研究以台风、暴雨、地震、火灾四类灾害为例,从灾害易发性与危险性特征、建筑与基础设施、应急响应机制三方面人手,分析总结城市抵抗、适应和恢复各个阶段功能变化的主要影响参量,建立了多灾种下城市安全韧性评价的指标体系,为城市安全韧性的量化评价方法研究和城市安全提升对策提供了参考依据.     

基于开关电容的三端口DC-DC变换器

三端口直流变换器(TPC)应用于新能源供电系统与电动汽车供电系统,可将系统中原有的多个单向和双向直流变换器在电路结构上实现合并,具有结构简单、成本低、控制灵活等优点。根据TPC的分类和组成规则构建一族含有开关电容、自举电路、BUCK、BOOST电路的高压比三端口直流变换器。形成的新型三端口变换器具有压比高、结构灵活、调压范围广等特点,可以很好地应用在新能源发电应用系统中。最后对提出的新拓扑进行理论分析和实验验证。     

Infrared‐Transparent Y2O3–MgO Nanocomposites Fabricated by the Glucose Sol–Gel Combustion and Hot‐Pressing Technique

A glucose sol–gel combustion method has been developed to synthesize composite nanopowders with equal volume fractions of Y₂O₃ and MgO. The synthesis involves the generation of precursor foam containing Y³⁺ and Mg²⁺ cations via the chemical and thermal degradation of glucose molecules in aqueous solutions. Subsequent calcination of the foam gave the composite nanopowders uniform composition and surface areas of 44–62 m²/g depending on the relative amount of glucose. Then the nanopowder with an average particle size of 19 nm was consolidated by the hot‐pressing technique with different sintering temperatures. The fabricated nanocomposite is mid‐infrared transparent as the result of fine grains, narrow grain size distribution, and uniform phase domains. The transmittance increases with increase in the sintering temperature and reaches 83.5% at 3–5 μm mid‐infrared wave range once the temperature reaches 1350°C, which is close to the theoretical value of 85%. And it is noteworthy that the cutoff wavelength reaches 9.6 μm, which is superior to those of spinel, AlON, and sapphire. And the Vickers hardness of the sample reaches 10.0 ± 0.1 GPa, which is significantly higher than those of the coarse grained single‐phase MgO and Y₂O₃. The results indicate that the glucose sol–gel combustion and hot‐pressing technique is an effective method to fabricate infrared transparent Y₂O₃–MgO nanocomposites.