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1.
Nur Lina Rashidah Mohd Rashid Abdullah Abdul Samat Abdul Azim Jais Mahendra Rao Somalu Andanastuti Muchtar Nurul Akidah Baharuddin Wan Nor Roslam Wan Isahak 《Ceramics International》2019,45(6):6605-6615
The performance of low-to-intermediate temperature (400–800?°C) solid oxide fuel cells (SOFCs) depends on the properties of electrolyte used. SOFC performance can be enhanced by replacing electrolyte materials from conventional oxide ion (O2-) conductors with proton (H+) conductors because H+ conductors have higher ionic conductivity and theoretical electrical efficiency than O2- conductors within the target temperature range. Electrolytes based on cerate and/or zirconate have been proposed as potential H+ conductors. Cerate-based electrolytes have the highest H+ conductivity, but they are chemically and thermally unstable during redox cycles, whereas zirconate-based electrolytes exhibit the opposite properties. Thus, tailoring the properties of cerate and/or zirconate electrolytes by doping with rare-earth metals has become a main concern for many researchers to further improve the ionic conductivity and stability of electrolytes. This article provides an overview on the properties of four types of cerate and/or zirconate electrolytes including cerate-based, zirconate-based, single-doped cerate–zirconate and hybrid-doped cerate–zirconate. The properties of the proton electrolytes such as ionic conductivity, chemical stability and sinterability are also systematically discussed. This review further provides a summary of the performance of SOFCs operated with cerate and/or zirconate proton conductors and the actual potential of these materials as alternative electrolytes for proton-conducting SOFC application. 相似文献
2.
Muhammad Sheeraz Mamoon Ur Rashid Asad Ali Fazli Akram Ho Jeong Lee Jin San Choi Jong-Seong Bae Yong Soo Kim Young-Han Shin Chang Won Ahn Tae Heon Kim 《Journal of the European Ceramic Society》2021,41(10):5155-5162
We demonstrate the structural evolution of polymorphic phases in Al2O3-inserted SrMnO3 ceramics synthesized by solid state reaction. While the 4H-hexagonal phase is predominant in pure SrMnO3 ceramics, a small amount of 6H-hexagonal polymorph is identified in addition to the primary 4H-hexagonal SrMnO3 and the secondary hexagonal SrAl2O4 phases in the as-sintered ceramics, evidenced by x-ray diffraction and subsequent Rietveld refinement analyses. The existence of the 6H-hexagonal SrMnO3 phase is corroborated using Raman spectroscopy. The chemical compositions and electronic structures of the Al2O3-inserted SrMnO3 compounds are also examined using energy dispersive spectroscopy and x-ray photoelectron spectroscopy, respectively. The first-principles calculations reveal that there is no clear difference between the total energies of 4H- and 6H-hexagonal polymorphs regardless of the presence/absence of Sr and oxygen vacancies. Possible origins are discussed with the estimation of actual strain based on the refined lattice parameter of 6H SrMnO3. 相似文献
3.
The dynamic response of highway bridges subjected to moving truckloads has been observed to be dependent on (1) dynamic characteristics of the bridge; (2) truck configuration, speed, and lane position on the bridge; and (3) road surface roughness profile of the bridge and its approach. Historically, truckloads were measured to determine the load spectra for girder bridges. However, truckload measurements are either made for a short period of time [for example, weigh-in-motion (WIM) data] or are statistically biased (for example, weigh stations) and cost prohibitive. The objective of this paper is to present results of a 3D computer-based model for the simulation of multiple trucks on girder bridges. The model is based on the grillage approach and is applied to four steel girder bridges tested under normal truck traffic. Actual truckload data collected using a discrete bridge WIM system are used in the model. The data include axle loads, truck gross weight, axle configuration, and statistical data on multiple presence (side by side or following). The results are presented as a function of the static and dynamic stresses in each girder and compared with code provisions for dynamic load factor. The study provides an alternate method for the development of live-load models for bridge design and evaluation. 相似文献
4.
This paper evaluates the behavior and performance of laminated circular elastomeric bearings and compares them to those of square and rectangular bearings. The study included an experimental evaluation and a nationwide survey of state Department of Transportations on the use and performance of circular bearings and bearings in general in their states. The experimental investigation studied the bearings' behavior in compression, compression and rotation, and compression and shear. Results from this limited study showed that the three bearings have similar stress-strain behavior in compression and they are in agreement with the AASHTO LRFD guide stress–strain curves. In compression and rotation, the AASHTO LRFD substructure moments are slightly less than the measured values for circular bearings and rectangular bearings rotated about their strong axis for a compressive stress of 10.3?MPa (1.5?ksi) and slightly higher than those of rectangular bearings rotated about their weak axis. In compression and shear, the shear stiffness of circular and square bearings is in agreement with theoretical values within the range of design displacements. Results from the survey showed that many states are using circular bearings and more states would consider using them, however no maintenance or monitoring data were available on their short-term and long-term performance. 相似文献
5.
Effect of the percentage carbon equivalent on the nodule characteristics,density and modulus of elasticity of ductile cast iron 总被引:1,自引:0,他引:1
Nabil Fatahalla Hani Abd Al Hakim Aly Abo-El-Ezz Moenes Mohamed 《Journal of Materials Science》1996,31(18):4933-4937
Successful melting and Mg treatment were conducted using a vortex unit which produced spheroidal graphite (SG) Fe ingots having a percentage carbon equivalent (%CE) ranging from 3.782 to 5.240. Microstructure examination revealed graphite nodules embedded in a white matrix (unetched condition). The variation of %CE proved to have a pronounced effect on the nodule characteristics. The nodule count showed a maximum value at %CE of 4.613. For metal-mould ingots it reached a value of 1584 nodules mm–2, while for sand-mould ingots it reached a value of 970 nodules mm–2. Nodule size was found to be inversely proportional to the nodule count for both sand- and metal-mould ingots. The nodularity of all ingots was, in general, higher than 95%. The density of SG Fe was found to decrease gradually (at %CE=3.782) from 7242 to 6969 kg m–3. The modulus of elasticity (E) showed a boat-like curve having minimum values of 189 and 192 GPa for the sand and metal moulds, respectively. 相似文献
6.
M. M. Rashid 《International journal for numerical methods in engineering》2002,55(4):431-450
A computational procedure for remapping material state information from one finite element mesh to another is described. The procedure is useful in connection with evolving meshes for inelastic problems, as for example occur in the context of fracture simulation and adaptive mesh refinement. The proposed method is based on weak enforcement of equality between corresponding fields on the two meshes, where piecewise‐constant fields on both meshes are generalized from the quadrature‐point values. The essential algorithmic problem is that of calculating the volume partition of an arbitrary convex region with respect to a covering set of disjoint convex regions. Instead of geometrically resolving the associated intersections, the problem is herein approximated by a constrained optimization problem, which may be readily and efficiently solved computationally. This formulation is a main contribution of the paper. Computational examples are given that illustrate the effectiveness of the proposed procedure. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
7.
Ahmed Helmy Khaled Sharaf Hani Ragai 《Analog Integrated Circuits and Signal Processing》2003,37(3):139-148
A noise analysis of bipolar harmonic mixers (BHM) used for direct-conversion receivers is presented in this paper. Analytical and simulated results for the transfer function of the mixer are presented. Simple analytical expressions describing noise contribution from all sources are derived. Estimation of flicker noise quite agrees with harmonic-balance simulation results. Based on the derived expressions, total time average noise power spectral density (PSD) at the output is compared with simulation results. For the recommended regions of operation, error is less than 20%. The overall BHM noise figure (NF) is calculated and optimized based on a simple extracted formula. Errors introduced by analysis remain within a 1.5-dB margin with respect to simulation results. The validity of analysis for high frequencies is justified. The effect of flicker noise coefficient on the overall mixer NF is compared for different available processes. 相似文献
8.
9.
Touqeer Haseeb Zaman Shakir Amin Rashid Hussain Mudassar Al-Turjman Fadi Bilal Muhammad 《The Journal of supercomputing》2021,77(12):14053-14089
The Journal of Supercomputing - The Internet of Things is a rapidly evolving technology in which interconnected computing devices and sensors share data over the network to decipher different... 相似文献
10.
Pavel L. Katsel Tamara M. Dmitrieva Rashid B. Valeyev Yuri P. Kozlov 《Journal of chemical ecology》1992,18(11):2003-2010
Three components of the male yellowfin Baikal sculpin pheromonal signal have been isolated from urine by diethyl ether extraction, thinayer chromatography (TLC), and high-performance liquid chromatography (HPLC). Using mass spectrometry, we have identified two of them as testosterone (T) and 11-hydroxytestosterone (11HT). These steroids are synthesized in testes during full spermatogenesis, and they are excreted in male urine with milt. The third component is not a steroid. It is more likely to be a polyene alcohol (farnesol). 2Z,6E-Farnesol possesses behavioral activity. 相似文献