Relative spectral response calibration using Ti plasma lines

This work introduces the branching ratio(BR) method for determining relative spectral responses,which are needed routinely in laser induced breakdown spectroscopy(LIBS). Neutral and singly ionized Ti lines in the 250–498 nm spectral range are investigated by measuring laser-induced micro plasma near a Ti plate and used to calculate the relative spectral response of an entire LIBS detection system. The results are compared with those of the conventional relative spectral response calibration method using a tungsten halogen lamp, and certain lines available for the BR method are selected. The study supports the common manner of using BRs to calibrate the detection system in LIBS setups.     

激光诱导等离子体光谱仪实验装置的构建

激光诱导等离子体光谱仪是一种具有实时在线、非接触、多元素同时探测等优点的分析仪器。它无需制备样品,是钢铁冶炼中在线元素快速检测的仪器之一。本文将线阵CCD放置于罗兰圆上,搭建了一台紫外波段的激光诱导等离子体光谱仪实验装置,光谱分辨率达0.1nm,覆盖的光谱波段为235～260nm,主要用于检测钢铁材料中的C元素。实验结果表明,该系统的搭建是成功的。     

多光谱成像技术辅助书画配色与修复

利用多光谱成像技术,讨论了一种对书画图像进行扫描和分析的系统修复方法,避免了传统化学、物理分析方法对书画造成不必要的损害.在计算机的辅助下对书画进行多光谱图像的采集、光谱反射率重建、光谱图像降维以及图像颜色重建等,实现了书画颜色的高保真再现,在颜色修复上提出了基于Kubelka-Munk理论的颜料重构方法,为书画的修复提供技术上的支持.采用该方法不仅可降低修复过程中书画损坏的风险,而且可提高修复质量.     

Impurity Emission Behavior in the Soft X-Ray and Extreme Ultraviolet Range on EAST

Spectroscopy in the soft X-ray and extreme ultraviolet(XEUV) region is very important in magnetic fusion research.Recently,two flat-field spectrometers that utilize a varied line spacing grating to image the spectra of 1-13 nm and 5-50 nm were installed on EAST for core impurity emission monitoring and impurity transport study.The instruments were proven to be capable of observing spectral lines from low-Z impurities(Li,C,O,N,Ar,etc.) and highly ionized medium- and high-Z impurities(Fe,Cr,Ni,Cu,Mo,etc.).For example,spectra in the wavelength intervals of 1-2 nm and 5-13 nm contained strong metal lines,especially molybdenum lines during H-mode phases.Argon and nitrogen lines were also observed,which were injected for diagnostic purposes.Impurity lines were identified and compared to measurements on other magnetic fusion research devices.Detailed measurements of radial emission profiles from various impurity line emissions were also presented.     

An efficient procedure in quantitative analysis using laser-induced breakdown spectroscopy

Laser-induced breakdown spectroscopy has become a general-purpose technique, and internal standard calibration is a common method for quantitative analysis. Calibration models should be reconstructed for different systems and application environments. This study presents an efficient procedure in the construction and selection of calibration models for LIBS analysis. The procedure concludes data preprocess, calibration model construction, and concentration calculation. These steps can be programmed without manual intervention. Results of the quantitative analysis of Ni-based alloys using the proposed procedure are presented in this study.Ten elements are calibrated, and most have an average relative standard error of less than 10%.The proposed procedure is an effective process for constructing and selecting calibration models.     

EAST全超导托卡马克高分辨率EUV光谱仪诊断系统

EAST全超导托卡马克装置上建立一套极紫外(EUV)光谱诊断系统,用于高温等离子体高电离态杂质线辐射研究.该系统利用1200 l/mm凹面变线距全息光栅作为分光元件,工作波段50-500(A),波长分辨率Δλ-0.16(A)(186.6?),时间分辨为20 ms,空间观测范围为0-450 mm,基本覆盖EAST全超导托...