Deacetylated Cellulose Acetate/Polyurethane Composite Nanofiber Membranes with Highly Efficient Oil/Water Separation and Excellent Mechanical Properties

Nowadays, oil pollution has become more serious, which causes great threats both to the ecological environment and human life. In this study, a novel type of multifunctional deacetylated cellulose acetate/polyurethane (d-M_CA:M_TPU) composite nanofiber membranes for oil/water separation are successfully fabricated by electrospinning, which show super-amphiphilicity in air, super-hydrophilicity in oil, and oleophobicity in water. All the d-M_CA:M_TPU composite nanofiber membranes with different mass ratios can be used as water-removing, oil-removing, and emulsion separation substance only by gravity driving force. The highest separation flux for water and oil reaches up to 37 000 and 74 000 L m⁻² h⁻¹, respectively, and all the separation efficiencies are more than 99%. They have outstanding comprehensive mechanics performance, which can be controlled by simply adjusting the mass ratios. They show excellent antifouling and self-cleaning ability, endowing powerful cyclic stability and reusability. Those results show that d-M_CA:M_TPU composite nanofiber membranes have great application prospects in oil/water separation.     

坐便器与水箱配件在标准中的配套性要求

详细介绍了坐便器与水箱配件在新标准中的配套性技术要求,分析了2种产品配套性指标和相关的检测方法。     

脉冲位置键控系统误比特性能分析

梳理基于等待门限判决的脉冲位置键控系统相关文献资料,发现文献给出的误比特率(BER)理论公式不能准确描述系统误比特率,尤其是在低信噪比情况下一些理论公式计算的误比特率已经高于0.5,超过了通信系统误比特率上限,不符合通信理论。分析了各文献资料误比特率理论公式推导过程中的问题所在,推导得到了一个新的误比特率理论公式。进行了数值仿真,结果表明,新的误比特率理论公式与仿真吻合良好,能够准确描述系统误比特率,并且在低噪比下计算的误比特率不高于0.5,符合通信理论。在新的误比特率理论公式基础上,分析了基于等待门限判决的脉冲位置键控系统能量效率,并与二进制相移键控(BPSK)系统进行了比较,表明基于等待门限判决的脉冲位置键控系统是一种具有较高能量效率的系统,在一定条件下甚至优于BPSK系统。     

基于双数据目录存储的网格元数据的资源发现

提出了基于全局命名的数据网格环境下元数据目录和资源信息目录双目录存储和访问的概念，研究了全局命名的规则，给出了在该命名情况下元数据的注册和存储以及利用这种注册存储如何快速发现远程数据资源。说明了在多网格结点下寻找“对照表”采取时间戳抑制多次重发和导致多次访问数据资源的方法，并指出了“对照表”应采取的热点数据优先、冷僻数据清除的策略。     

既有居住建筑附属地下换热站降噪研究

为了降低既有建筑附属用房产生的噪声对居民生活的影响、改善居住建筑声环境,对既有居住建筑附属用房地下换热站的噪声源以及噪声传播途径进行了分析;以既有居住建筑地下换热站室内噪声实测数据为基础,对室内环境的声学特征进行分析。在综合考虑居民的健康和舒适的基础上,提出了针对该附属用房的降噪处理改造设计方案。经过改造后的空间噪声明显降低,空间声环境指标达到标准要求,有效地改善了居住建筑的声环境。文中提出的改造设计方案为制定民用建筑附属用房声学设计标准提供了技术支撑。     

Dynamic viscoelasticity and molecular orientation in uniaxially drawn PC/PET blends

The dependence of dynamic viscoelasticity on molecular orientation of the hot-drawn polycarbonate (PC)/poly(ethylene terephthalate) blends was studied experimentally. The oriented states of samples were investigated by wide-angle X-ray diffraction and quantified by Hermans' factor. The viscoelasticity was probed by dynamic mechanical analysis. For the fitting curves of dynamic modulus versus orientation, the PC-rich blends with different compositions had an opposite concavity and convexity compared with the neat PC. The difference revealed the influence of molecular mobility on orientation and viscoelasticity. The assumption on the phase morphological change from sea-island to local sandwich-like structure in blends was proposed and used to interpret the variation of slope of fitting curves. The relationship between orientation and viscoelasticity was observed in PC-rich blends, which can help understand the mechanism of molecular orientation and develop the constitutive relations for simulation. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47514.     

溶剂蒸汽压对溶液法制备PVP绝缘膜的影响

利用溶剂蒸汽辅助旋涂和辅助退火(SVA)工艺制备了PVP栅绝缘膜,并研究了SVA过程中溶剂蒸汽压对PVP膜特性的影响。根据椭偏光谱的柯西模型和有效介质近似(EMA)模型,对椭偏谱参数拟合分析得到了PVP膜光学参数与其微结构的关系。拟合结果表明,随着蒸汽压的增大,PVP膜总厚度(均小于30nm)和粗糙层厚度均降低,膜致密性得到改善。由这种膜构成的MIS结构的J-V特性测试结果显示,当蒸汽压由0.21增加至0.82时,在电场为5 MV/cm的条件下,其漏电流密度由1.04×10-6 A/cm2降至1.42×10-7 A/cm2。而且在蒸汽压为0.82时可得到膜厚仅约为20nm、单位面积电容达到145nF/cm2的超薄PVP膜。     

The role of conductive pathways in the conductivity and rheological behavior of poly(methyl methacrylate)–graphite composites

Up to now, research on the dynamic process of conductive network formation has tended to focus on composite particles with one‐dimensional geometry, such as carbon black and carbon nanotubes. However, studies on this subject based on fillers with two‐dimensional structure, such as graphite, are rare in the literature. In this work, the dynamic percolation and rheological properties of poly(methyl methacrylate) (PMMA)–graphite composites under an electric field were investigated. The activation energies of conductive network formation and polymer matrix mobility were calculated from the temperature dependence of the percolation time and the zero‐shear viscosity. It was found that the activation energy calculated from the zero‐shear viscosity was not influenced by the electric field in the concentration range investigated, but the electric field had an effect on the activation energy calculated from the percolation time. This finding emphasizes that the electrical and rheological properties have different physical origins. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43810.     

轧制和退火态的Mg-Y-Zr-xNd合金的组织和力学性能

通过光学显微组织(OM),扫描电子显微镜(SEM),X射线衍射(XRD),电子背散射衍射(EBSD)和拉伸试验研究了不同热处理条件下Mg-5Y-0.6Zr-xNd (x = 0, 0.5和1wt.％) 合金的组织和力学性能。结果表明,随着Nd含量的增加,第二相Mg24Y5和Mg14Nd2Y (β)在基体中的含量增加。添加少量Nd可以降低α-Mg的堆垛层错能,促进热轧过程中的动态再结晶。随着Nd含量的增加,静态再结晶的体积分数明显增加。退火处理后Mg-5Y-0.6Zr-0Nd合金的平均晶粒尺寸可细化至3.73μm。轧制合金的抗拉强度随着Nd的增加而增加,而伸长率则表现出相反的变化趋势。含有1.01wt.％Nd的轧制合金具有优良的机械性能,其拉伸强度,屈服强度和伸长率分别为336MPa,278MPa和16.3％。在微观结构观察的基础上,讨论了力学性能的变化。