Soluble and conductive polypyrrole copolymers containing silicone tegomers

Soluble and processable conductive copolymers of silicone tegomers and pyrrole were developed. This was easily accomplished by the oxidative polymerization of pyrrole monomer by Ce(IV) salt in the presence of silicone tegomers with hydroxyl chain ends. The resulting copolymers were soluble in dimethylformamide. The products were characterized by Fourier transform infrared, ¹H‐NMR, and four‐point probe conductivity, and their surface properties were investigated with contact‐angle measurements. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2896–2901, 2003     

A Polynomial Time Solution to Minimum Forwarding Set Problem in Wireless Networks under Unit Disk Coverage Model

Network-wide broadcast (simply broadcast) is a frequently used operation in wireless ad hoc networks (WANETs). One promising practical approach for energy-efficient broadcast is to use localized algorithms to minimize the number of nodes involved in the propagation of the broadcast messages. In this context, the minimum forwarding set problem (MFSP) (also known as multipoint relay (MPR) problem) has received a considerable attention in the research community. Even though the general form of the problem is shown to be NP-complete, the complexity of the problem has not been known under the practical application context of ad hoc networks. In this paper, we present a polynomial time algorithm to solve the MFSP for wireless network under unit disk coverage model. We prove the existence of some geometrical properties for the problem and then propose a polynomial time algorithm to build an optimal solution based on these properties. To the best of our knowledge, our algorithm is the first polynomial time solution to the MFSP under the unit disk coverage model. We believe that the work presented in this paper will have an impact on the design and development of new algorithms for several wireless network applications including energy-efficient multicast, broadcast, and topology control protocols for WANETs and sensor networks.     

The ratio of crystallinity and thermodynamical interactions of polycaprolactone with some aliphatic esters and aromatic solvents by inverse gas chromatography

Summary The retention diagrams of benzene, toluene, ethyl benzene, chloro benzene, n-propyl benzene, isopropyl benzene, methyl acetate, ethyl acetate, n-propyl acetate, n-butyl acetate and isoamyl acetate on the polycaprolactone were plotted at temperatures between 70 and 140^oC by inverse gas chromatography technique. Percent crystallinity of polycaprolactone were obtained at temperatures below melting point from the retention diagrams of benzene, toluene and ethyl benzene. It was concluded that the data obtained by inverse gas chromatography were comparable those of obtained by differential scanning calorimetry. Specific retention volume, V_g^o, Flory-Huggins polymer-solvent interaction parameters, ₁₂, the weight fraction activity coefficients of the solvents at infinite dilution, ₁, effective exchange energy parameters, X_eff were determined. Later, the partial molar heat of sorption, H_1,sorp and the partial molar heat of mixing, H₁ were obtained from the slope of the logarithm of specific retention volume, Ln V_g^o versus 1/T plot and from the slope of the logarithm of the weight fraction activity coefficients, ₁versus 1/T plot, respectively.     

A Distributed Approach for Monitoring Multicast Service Availability

With the deployment of native multicast in commercial networks, multicast is getting closer to becoming a ubiquitous service in the Internet. The success of this deployment largely depends on the availability of good management tools and systems. One of the most important management tasks for multicast is to verify the availability of the service to its users. This task is usually referred to as reachability monitoring. Reachability monitoring requires a number of monitoring stations to work together to collect this information in a distributed manner in the interdomain scale. In this paper we present a general architecture for multicast reachability monitoring systems and focus on three critical functions: agent configuration, monitoring, and feedback collection. For each component, we provide a number of alternative approaches to implement the required functionality and discuss their advantages and disadvantages. Then, we focus on the feedback collection component. To a large extent, it determines the complexity and the overhead of a monitoring system. Using simulations, we compare a number of alternative approaches for feedback collection and make suggestions on when to use each. We believe our work provides insight into the issues and considerations in designing and developing multicast reachability monitoring systems.     

Characterization of nanocrystalline Ni–Cu thin films electrodeposited onto ITO coated glass substrates: effect of pretreatment current density

In this work, Ni–Cu films were grown onto indium tin oxide coated glass substrates without and with galvanostatic pretreatment process at different current densities. In all cases, Ni–Cu films were electrodeposited at a constant deposition potential of ?1,800 mV versus saturated calomel electrode. After that, the surface morphology and structural properties of electrodeposited Ni–Cu films in dependence of pretreatment current density were studied. X-ray diffraction analysis showed that all films have face-centered cubic structure and consist of segregated two Ni-rich and Cu-rich phases regardless of pretreatment current density. The compositional analysis carried out by energy dispersive X-ray spectroscopy revealed that all films contain almost 90 wt% Ni and 10 wt% Cu. The average crystallite size decreased with decreasing pretreatment current density towards more negative values without inducing significant changes in the composition of the films. It was found that the preferred orientation of all films is in the [111] direction regardless of pretreatment current density. The effect of galvanostatic pretreatment process on the surface morphology investigated using a scanning electron microscopy and an atomic force microcopy were also discussed by means of obtained results.     

Foliar Application of Silicon Enhances Growth,Flower Yield,Quality and Postharvest Life of Tuberose (Polianthes tuberosa L.) under Saline Conditions by Improving Antioxidant Defense Mechanism

Silicon - Tuberose is native to Mexico and then reached Europe and spread other parts of the world. In Pakistan, tuberose stalks come in the market during late summer and autumn when only few...     

Mechanical,chemical, thermal,and rheological properties of recycled PA6/ABS binary and PA6/PA66/ABS ternary blends

The effects of multiple injection molding cycles on the chemical and mechanical properties of PA6/ABS and PA6/PA66/ABS blends are investigated. The chemical structures of both PA6/ABS binary and PA6/PA66/ABS ternary blends do not alter after recycling process. For PA6/ABS binary blend, it is found that the tensile strength, strain at break, elastic modulus, impact strength, flexural strength, and modulus of recycled blend decrease by 6.49%, 15.19%, 21.00%, 9.41%, 7.09%, and 8.25%, respectively, while MFI increases by 23.59% as compared with the virgin blend. After five recycling process for PA6/PA66/ABS ternary blend, the tensile strength, strain at break, and impact strength of recycled blend decrease by 18.00%, 50.80%, and 87.27%, respectively. However, flexural strength and modulus of PA6/PA66/ABS blend increase slightly. For virgin PA6/PA66/ABS blend, MFI value was 7.7 g/10 min and with recycling this value showed an important increase to 31.56 g/10 min after five cycles. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40810.     

Nonuniform Sampling for Detection of Abrupt Changes

In this work, detection of abrupt changes in continuous-time linear stochastic systems and selection of the sampling interval to improve the detection performance are considered. Cost functions are proposed to optimize both uniform and nonuniform sampling intervals for the well-known cumulative sum algorithm. Some iterative techniques are presented to make online optimization computationally feasible. It is shown that considerable improvement in the detection performance can be obtained by using nonuniform sampling intervals.     

Microstructure Study at Different Thicknesses of Disc-Shaped YBa2Cu3O7?x Prepared by FQMG Method

The flame-quench-melt-growth (FQMG) method was used for the preparation of bulk YBa₂Cu₃O_7?x (Y123). Both the superconducting and nonsuperconducting regions changing with thickness of superconducting sample were determined by X-ray diffraction (XRD) patterns and also observed at micrographs taken by the polarized optical microscope. It was observed that superconducting forming ratio which was examined for different thicknesses of the sample ranging from 6.54 to 1.58 mm strongly enhanced. This means that a region near the top surface of the sample contains more superconducting phase than the other regions. These observations would be helpful in designing and manufacturing the practical applications of YBCO systems.