LPNN-based approach for LASSO problem via a sequence of regularized minimizations

In compressive sampling theory, the least absolute shrinkage and selection operator (LASSO) is a representative problem. Nevertheless, the non-differentiable constraint impedes the use of Lagrange programming neural networks (LPNNs). We present in this article the -LPNN model, a novel algorithm that tackles the LASSO minimization together with the underlying theory support. First, we design a sequence of smooth constrained optimization problems, by introducing a convenient differentiable approximation to the non-differentiable -norm constraint. Next, we prove that the optimal solutions of the regularized intermediate problems converge to the optimal sparse signal for the LASSO. Then, for every regularized problem from the sequence, the -LPNN dynamic model is derived, and the asymptotic stability of its equilibrium state is established as well. Finally, numerical simulations are carried out to compare the performance of the proposed -LPNN algorithm with both the LASSO-LPNN model and a standard digital method.     

Purification,structural data and biological properties of polysaccharide from Prunus amygdalus gum

This work demonstrates the efficiency of almond gum polysaccharides (AGPs) as bioactive compounds. AGPs were first extracted using H₂O₂, in the presence of NaOH, at different times and temperatures. The optimal extraction conditions were 4% H₂O₂ and 2 N NaOH, for 7 h at 50 °C, leading to an extraction yield of 58.2% (w/w). After a purification step, the retained AGPs were characterised using high‐performance liquid chromatography showing a molecular weight of 99.3 kDa. The monosaccharide composition of AGPs were assessed using gas chromatography–mass spectrometry. AGPs were found to be a complex heteropolysaccharide with a repeating unit mainly composed of galactose, arabinose, xylose, mannose, rhamnose, and glucuronic acid with the respective ratios: 45:26:7:10:1:11. The acidic nature of the polysaccharide is due to the presence of glucuronic acid. Total antioxidant activity, free radical‐scavenging activity and reducing power assay of AGPs were investigated. The obtained results showed high antioxidant activities of AGPs. Furthermore, beyond 60 mg mL^?1, AGPs exhibited bacterial growth inhibition for five pathogenic strains: Escherichia coli, Staphylococcus aureus, Enterococcus feacalis, Pseudomonas aeruginosa and Salmonella typhimurium.     

Experimental characterization and performance study of an ammonia–water–hydrogen refrigerator

We present in this paper an experimental study of a commercial diffusion-absorption refrigeration machine (DAR) operating on the Platen and Munters cycle. The temperatures at the inlet and outlet of every component of the machine, as well as the cabinet and ambient temperature are measured continuously. The tests are repeated for various electric power inputs to the refrigerator. The global heat transfer coefficient of the cabinet (UA)_cab is determined using both theoretical and experimental methods. This coefficient is found equal to 0.2 W/°C. The global heat transfer coefficient of the evaporator (UA)_evap is deduced using dynamic and steady state methods. This global heat transfer coefficient (UA)_evap is found equal to 0.3 W/°C. Finally the cooling capacity of the unit and the coefficient of performance are evaluated. The heating power supply to the generator necessary to ensure the desired state of this machine is found to be in the range of 35 W–45 W.     

Effects of almond gum as texture and sensory quality improver in wheat bread

The aim of this work was to investigate the effect of almond gum as dietary fibre source in enhancing the wheat bread quality. Different amounts of almond gum (2%, 5% and 10% (w/w)) were used in bread formulation. The volume, texture, crust and crumb colour, as well as the sensorial properties, were evaluated and compared to control (without almond gum). The obtained results showed that almond gum addition enhanced significantly the volume of bread. The highest volume was obtained using 2% almond gum concentration with 23.6% increase, compared to control. Using almond gum in bread formulation improved considerably its texture with a notable decrease in hardness by 61.7% and 42.5% when using 2% and 5% almond gum, respectively. The sensory analysis scores showed that the better overall acceptability was found for breads supplemented with 2% almond gum, as compared to control and breads supplemented with 5% or 10% almond gum.     

PETROLEUM GENERATION IN THE UKRAINIAN EXTERNAL CARPATHIANS AND THE ADJACENT FORELAND

Major hydrocarbon accumulations are located in western Ukraine within the Mesozoic-Cenozoic flysch sequence in the frontal parts of the External Carpathians, and in the adjacent autochthonous foreland. The accumulations occur in three different structural settings: in the Carpathian flysch belt; in the pre-Neogene foreland autochthon; and in Miocene foredeep molasse. The petroleum potential of organic-rich rocks belonging to a number of different sedimentary cycles and tectonic units was studied by Rock-Eval pyrolysis.
Two significant organic-rich units, both with a basin-scale distribution, occur within the External Carpathians: (i) a unit comprising the Lower Cretaceous Shypot and Spas Formations; and (ii) the Oligocene-Lower Miocene Menilite Formation. The Menilite Formation includes the principal source rocks in this area, although Lower Cretaceous source rocks may also have generated hydrocarbons. Thermal maturation of the flysch and consequent petroleum generation resulted mainly from tectonic burial during Miocene overthrusting. In the external parts of the Carpathian Flysch Belt, oil generation in the Menilite Formation begins at a depth of around 4.2 km and ceases at around 6 km. In more internal tectonic units, a "frozen oil kitchen" occurs at shallower depths, indicating an increasing amount of tectonic uplift and erosion.
The autochthonous foreland is part of the SW margin of the East European Platform, and is partially overthrust by the Carpathian orogen. Rocks belonging to several different sedimentary cycles are present here. Pre-Mesozoic rocks in the foreland are overmature, at least within the central and SE parts of the study area. Petroleum accumulations are therefore most probably confined to the Mesozoic-Cenozoic sedimentary cover, within which the Middle Jurassic Kokhanivka Formation has the highest generation potential.     

Two La0.5Ag0.1Ca0.4MnO3 Manganite Nanoparticles Synthesized via Sol–Gel and Solid-State Methods–Structural,Magnetic, and Magnetocaloric Properties

Journal of Superconductivity and Novel Magnetism - La0.5Ag0.1Ca0.4MnO3 manganite nanoparticles are synthesized via two different ways, namely, a solid-state reaction (S1) and the sol–gel...     

Deflection Prediction of Steel and FRP-Reinforced Concrete-Filled FRP Tube Beams

This paper presents the results of experimental and theoretical investigations that study the flexural behavior of reinforced concrete-filled fiber-reinforced polymer (FRP) tubes (RCFFTs) beams. The experimental program consists of 10 circular beams [6 RCFFT and 4 control reinforced concrete (RC) beams] with a total length of 2,000?mm, tested under four-point bending load. The experimental results were used to review and verify the applicability of various North American code provisions and some available equations in the literature to predict deflection of RCFFT beams. The measured deflections and the experimental values of the effective moment of inertia were analyzed and compared with those predicted using available models. The results of the analysis indicated that the behavior of steel and FRP-RCFFT beams under the flexural load was significantly different than that of steel and FRP-RC members. This is attributed to the confining effect of the FRP tubes and their axial contribution. This confining behavior in turn enhanced the overall flexural behavior and improved the tension stiffening of RCFFT beams. For that, the predicted tension stiffening of steel and FRP-RCFFT beams using the conventional equations (steel or FRP-RC member) underestimates the flexural response; therefore, the predicted deflections are overestimated. Based on the analysis of the test results, the Branson’s equation for the effective moment of inertia of RC structures is modified, and new equations are developed to accurately predict the deflection of concrete-filled FRP tube (CFFT) beams reinforced with steel or FRP bars.     

Physicochemical characterization of low sulfonated polyether ether ketone/Smectite clay composite for proton exchange membrane fuel cells

Polyether ether ketone (PEEK) with a low sulfonation degree was blended using different proportions of sodium rich Smectite clay (3 and 6 wt%) to use as an electrolyte membrane for fuel cell application. The structural functionalities, surface morphologies, and the thermal stability of the resultant composite membranes were characterized using Fourier-transform infrared spectroscopy, X-ray diffraction (XRD), scanning electron microscopy, atom force microscopy, and thermo-gravimetric analysis. FT-IR showed that no chemical reactions take place between the sulfonated polyether ether ketone (SPEEK) and the clay with different ratios. XRD diffractograms illustrated a lower degree of crystallinity of the blended SPEEK than pristine SPEEK. The elaborated composite membranes proved to have a higher thermal stability than SPEEK. Furthermore, the SPEEK/clay composite membranes with 3 and 6 wt% in clay loading had higher water uptake and lower methanol uptake than those in pristine SPEEK It was also shown that, the incorporation of sodium ions rich Smectite clay layers between the clusters in SPEEK improved the conductivity to 2 × 10⁻² S/cm at 140°C (for 6 wt% in clay) without compromising the dimensional stability of the composite membranes. These results propose the composite membranes as a potential candidate for methanol fuel cells at temperatures above 120°C making SPEEK composite membrane competitive to that of Nafion membrane.     

Crystallographic Orientation in Pure and Aluminum-Doped Zinc Oxide Thin Films Prepared by Sol–Gel Technique

Novel sol–gel processes for the preparation of grain-oriented thin films of pure and aluminum-doped zinc oxide (AZO) are reported. Using various stabilizing ligands, oxide films with different degree of c -axis orientation could be prepared on amorphous substrates. The origin of orientation in sol–gel-derived ZnO and AZO films is investigated. The texture selection of ZnO films is independent of the heat-treatment schedule but sensitive to the precursor system. The electrical properties of the films do not depend significantly on the crystallographic orientation. The film visible transmittance remained higher than 90% even after vacuum annealing.     

Low-temperature processing and characterization of single-phase PZT powders by sol-gel method

A new sol-gel system using acetoin was developed and employed for the fabrication of PZT powders and films with compositions near the morphotropic phase boundary Pb(Zr_0.52Ti_0.48)O₃. Acetoin was used as chelating agent to replace the highly toxic methoxyethanol used in previous formulations. This route simplified the chemical processing of PZT-based solutions. Powders were completely crystallized by about 450 °C and contained the ferroelectric perovskite single phase. The firing temperature and time were to be the most important variables. Metallic lead formed only when excess Pb was incorporated. The precursor and the heat-treated powders have been characterized by using thermal analysis and X-ray diffractometry (XRD) studies. The average particle size, as measured from X-ray line broadening, was ∼35 nm.