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1.
The Environmental Protection Agency (EPA) introduced Reformulated Gasoline (RFG) requirements as a measure to reduce emissions from gasoline-powered vehicles in certain geographic areas. As part of this effort, the EPA developed empirical models for predicting emissions as a function of gasoline properties and established statutory baseline emissions from a representative set of gasolines. All reformulated gasoline requires certification via this model, known as the Complex Model, and all refiners and importers calculate emissions performance reductions from the statutory baseline gasoline. The current representation of the Complex Model is extremely difficult to implement within refinery operations models or to use in combination with models for designer gasoline. RFG and boutique fuels are key driving forces in the North American refining industry.The RFG models introduce increasingly complex constraints with the major limitation that they are implicitly defined through a series of complicated disjunctions assembled by the EPA in the form of spreadsheets. This implicit and cumbersome representation of the emissions predictive models renders rigorous optimization and sensitivity analysis very difficult to address directly. In this paper, we discuss how the federal government requirements for reformulated gasoline can be restated as a set of mixed-integer nonlinear programming (MINLP) constraints with the aid of disjunctive programming techniques. We illustrate the use of this model with two simple example fuel blending problems.  相似文献   
2.
Leszek Markowski 《Vacuum》2004,74(2):247-251
In the time-of-flight spectrum of positive ions produced by electron bombardment of NaCl surface a delayed signal of Na+ is detected. This observation is attributed to production of core-excited autoionizing metastable Na** atoms which have their characteristic lifetimes in the 100 ns range. Moreover, it is noticed that the populations of the various metastable Na** states depend on the NaCl layer thickness. The lifetimes of some quartet metastable Na** states have been determined as well.  相似文献   
3.
The development of biaxial segmental orientation and stress in a flexible-chain polymer fluid subjected to steady biaxial extensional flow is analyzed. Closed-formula model based on the Padè approximation of the inverse Langevin function in the non-Gaussian distribution of the chain end-to-end vectors is considered. The approach is free from the limitations related to finite chain extensibility and slow convergence of the series expansion formulations at higher chain deformations.Segmental orientation is characterized by the average orientation tensor, related axial orientation factors and global orientation anisotropy. Orientational behavior and corresponding stresses in the biaxial elongational potential flow are discussed in a wide range of elongation rates. Orientation characteristics calculated for the biaxial flow deformation are much higher than those predicted for the affine biaxial stretch deformation in polymer solids.  相似文献   
4.
The upper and lower limits of the electrostrictive constants, dielectric permittivities, spontaneous polarizations, and piezoelectric coefficients were calculated for ceramic PbTiO(3) from theoretical single-crystal constants. Experimental ceramic data fall between these upper and lower limits. The large piezoelectric anisotropy d(33)/d(31) of ceramic PbTiO(3 ) was shown to be related to the single-crystal PbTiO(3) electrostrictive anisotropies Q(11)/Q(12 ) and Q(44)/Q(12). The possibility of a change in sign of the ceramic d(31) coefficient due to a slight variation in the single-crystal electrostrictive anisotropies was discussed. The single-crystal and predicted ceramic hydrostatic electrostrictive constants were found to be equal. Using this result the ceramic hydrostatic g(h ) coefficient is always smaller than the single-crystal g (h), but the ceramic hydrostatic d(h) coefficient can be either larger or smaller than the single-crystal d(h) depending on the dielectric anisotropy (epsilon (11)/epsilon(33)) of the single-crystal.  相似文献   
5.
Protein solubility is based on the compatibility of the specific protein surface with the polar aquatic environment. The exposure of polar residues to the protein surface promotes the protein’s solubility in the polar environment. The aquatic environment also influences the folding process by favoring the centralization of hydrophobic residues with the simultaneous exposure to polar residues. The degree of compatibility of the residue distribution, with the model of the concentration of hydrophobic residues in the center of the molecule, with the simultaneous exposure of polar residues is determined by the sequence of amino acids in the chain. The fuzzy oil drop model enables the quantification of the degree of compatibility of the hydrophobicity distribution observed in the protein to a form fully consistent with the Gaussian 3D function, which expresses an idealized distribution that meets the preferences of the polar water environment. The varied degrees of compatibility of the distribution observed with the idealized one allow the prediction of preferences to interactions with molecules of different polarity, including water molecules in particular. This paper analyzes a set of proteins with different levels of hydrophobicity distribution in the context of the solubility of a given protein and the possibility of complex formation.  相似文献   
6.
Thermodynamic properties were determined for the system cobalt oxide-copper oxide by means of an electromotive force (EMF) measurement techniques using galvanic cells with calciastabilized zirconia (CSZ) as the solid electrolyte and with air as the reference electrode according to the following schemes: CuO, Cu2O | CSZ | air and CoO-CuO, Cu2O CSZ | air for composition variables y=XCu/(XCo+Xcu equal to 0.05, 0.15, 0.25, 0.35, 0.45, 0.667, and 0.8; and within the temperature interval 1200–1350 K. Thermodynamic properties calculated directly from EMF values were combined with the available literature data on phase equilibria, and thermodynamic properties of solid phases in the Co-Cu-O system were assessed. Both terminal solid solutions, (Co,Cu)O and (Cu,Co)O, were described by a sublattice model with Redlich-Kister excess term. The interaction parameters for both (Co,Cu)O and (Cu,Co)O solid solutions and the Gibbs energy of formation for the intermediate phase Cu2CoO3 were obtained. The Gibbs energies of fictive end-members: monoclinic “CoO” and “CuO” with rock salt structure were derived as well. The phase diagrams were calculated using the assessed thermodynamic parameters. The (T, y) phase diagram was calculated for existence under ambient air. The property diagrams log10P(O2) versus composition and activity of CuO versus composition were calculated at 1273 K. The results of our calculations were in a good agreement with available experimental data.  相似文献   
7.
Leaching and characterisation studies have been undertaken on two chromate-inhibited epoxy polyamide primers. Leaching was carried out in 5% (w/v) NaCl solutions at different pH values (1, 3, 5 and 7) and the amount of Cr released into solution was monitored over time. Cr release was initially high, but as the immersion time increased the leaching from the primers slowed. Prior to and after immersion, the primers were characterised by a number of techniques including electron microprobe analysis, X-ray microdiffraction, Raman spectroscopy, and positron annihilation lifetime spectroscopy. The unexposed primers were found to contain the inorganic phases SrCrO4, BaSO4 and TiO2 (anatase or rutile). Upon immersion, water uptake by the primers was observed, together with a decrease in the amount of SrCrO4 in the primers. These studies provide insights into the mechanism of chromate leaching from inhibited primers.  相似文献   
8.
Verification of identity based on the analysis of dynamic signatures is an important problem of biometrics. The effectiveness of the verification significantly increases when the dynamic characteristics of signature (e.g. velocity of the pen) are considered. These characteristics are individual for each user and difficult to imitate. The effectiveness of the verification can be further improved by using partitioning. In this paper we propose a new method which uses partitioning. In our method partitions represent areas of high and low speed of signature and high and low pen?s pressure. All selected partitions are used by our algorithm, but more important in the classification process are these partitions, in which the signatures of the user acquired during training phase are more stable. Moreover, final classification is interpretable. In this paper we present the simulation results of the proposed method for the two databases: SVC2004 and BioSecure Database.  相似文献   
9.
We study behavior of quantum discord, a kind of quantum correlation, in systems of dipole–dipole interacting spins in an external magnetic field in the whole temperature range ( \(-\infty ). It was shown that negative temperatures, which are introduced to describe inversions in the population in a finite level system, provide more favorable conditions for emergence of quantum correlations including entanglement. We show that at negative temperature, the correlations become more intense and discord exists between remote spins being in separated states.  相似文献   
10.
The article presents a new concept of combining the three dimensions (3D) of a person's manipulation space. The data concern information about the reach of the arms and biomechanical data about limiting the load of a disabled person sitting in a wheelchair. Measurement data were acquired empirically, on original measuring station. The data included, respectively, arms' reach (static and dynamic) or, alternatively, measurements of limiting forces. The obtained data were processed into virtual 3D surfaces of arms' reach and forces. These surfaces provide the required graphic model of anthropotechnical and biomechanical data. Developed model was utilized to perform a virtual analysis of the accessibility of a disabled person to technical means: in a market sale space and in the ergonomic analysis into the space of a personal car. The presented method of 3D graphic modeling of anthropometrical and biomechanical data can be universally applied in ergonomic designing of work stations not only for disabled persons. © 2011 Wiley Periodicals, Inc.  相似文献   
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