Influence of Mg concentration on structural,morphological and optical properties of nanoceria

Nano crystalline pure and Mg doped ceriaparticles were synthesized by simple chemical co-precipitation method using cerium nitrate hexahydrate as a source material and magnesium nitrate as doping precursor at room temperature. The effect of doping were investigated by X-ray diffraction pattern(XRD), FT-Raman,fourier transform infrared spectroscopy(FTIR), Ultraviolet spectroscopy(UV), photoluminescence spectroscopy(PL), field emission scanning electron microscope(FESEM) and high resolution transmission electron microscopy with energy dispersive spectroscopy (HRTEM &EDS). The X-ray diffraction pattern and FT-Raman studies showed that the prepared samples were nano particulates with cubic fluorite structure. The XRD pattern analysis showed that the size of the particles ranged from 13 to 20?nm, however 4?wt% Mg doping results in reduction of particle size compared with other doping concentrations. The effects of Mg concentration on various structural parameters of the prepared samples were also determined. The slight blue shift observed upon doping in UV–Vis absorption region around 330–360nmrecorded for reduction in particle size. The FTIR unveils the presence of Metal oxygen bonds below 700?cm^?1in the prepared samples. All samples showed a broad emission band at 430?nm with linearly increasing intensity with respect to dopant concentrations. The Spherical morphology with weak agglomeration was identified through FESEM and HRTEM analysis. The elemental analysis of Ce, O and Mg were confirmed through EDS analysis.     

Simultaneous accommodation of Dy3+ at the lattice site of β-Ca3(PO4)2 and t-ZrO2 mixtures: Structural stability,mechanical, optical,and magnetic features

Structurally stable β-Ca₃(PO₄)₂/t-ZrO₂ composite mixtures with the aid of Dy³⁺ stabilizer were accomplished at 1500°C. The precursors comprising Ca²⁺, P⁵⁺, Zr⁴⁺, and Dy³⁺ have been varied to obtain five different combinations. The results revealed the fact that complete phase transformation of calcium-deficient apatite to β-Ca₃(PO₄)₂ occurred only at 1300°C, whereas the evidence of t-ZrO₂ crystallization is obvious at 900°C. The dual occupancy of Dy³⁺ at β-Ca₃(PO₄)₂ and t-ZrO₂ structures was evident; however, Dy³⁺ initially prefers to occupy β-Ca₃(PO₄)₂ lattice until its saturation limit and thereafter accommodates at the lattice site of ZrO₂. The typical absorption and emission behavior of Dy³⁺ were noticed in all the systems and, moreover, the surrounding symmetry of Dy³⁺ domains has been determined from the luminescence study. All the systems ensured paramagnetic response that is generally contributed by the presence of Dy³⁺. A gradual increment in the phase content of t-ZrO₂ in the composite mixtures ensured a significant improvement in the hardness and Young's modulus of the investigated compositions.     

Acoustic emission technique for leak detection in an end shield of a pressurised heavy water reactor

This paper discusses the successful application of the Acoustic Emission Technique (AET) for detection and location of leak paths present on the inaccessible side of an end shield of a Pressurised Heavy Water Reactor (PHWR). The methodology was based on the fact that air and water leak AE signals have different characteristic features. Baseline data was generated from a sound end-shield of a PHWR for characterizing the background noise. A mock up end-shield system with saw cut leak paths was used to verify the validity of the methodology. It was found that air leak signals under pressurisation (as low as 3 psi) could be detected by frequency domain analysis. Signals due to air leaks from various locations of a defective end-shield were acquired and analysed. It was possible to detect and locate leak paths. Presence of detected leak paths were further confirmed by alternate test.     

Role of Silicon Coupling Grafted Natural Fillers on Visco-Elastic,Tensile-Fatigue and Water Absorption Behavior of Epoxy Resin Composite

Silicon - This work investigates the influence of silicon based coupling agents on visco-elastic properties of natural filler dispersed epoxy resin composites. Also this work attempts to explore...     

Structural integrity assessment of the containment structure of a pressurised heavy water nuclear reactor using impact echo technique

The impact echo technique is based on the use of transient stress waves for non-destructive detection of flaws in concrete structures. Impact-echo testing has been carried out for assessment of the structural integrity of the ring beam of a pressurised heavy water nuclear reactor. In order to develop the test procedure for carrying out impact echo testing, mock up calibration blocks were made. The detectability of the impact echo system has also been established in terms of the depth and the lateral dimension of the detectable flaw for the ring beam under consideration. Based on the optimised test parameters identified with the help of the studies carried out on the mock up blocks, impact echo testing was carried out on the ring beam of the reactor containment structure, for assessing its structural integrity.     

Multiobjective optimization and analysis of copper–titanium diboride electrode in EDM of monel 400™ alloy

Electrical discharge machining (EDM) is one of the most accepted machining processes in the precision manufacturing industry. In EDM process, finding an alternative tool material is the demand in modern manufacturing industry. Therefore, an attempt had been made to fabricate copper–titanium diboride powder metallurgy electrode to test in EDM on monel 400? material. The experiments are planned using center composite second-order rotatable design and the model is developed by response surface methodology. The machining characteristics have analyzed using the developed model. In this study, four input parameters such as titanium diboride percentage, pulse current, pulse on time, and flushing pressure are selected to evaluate the material removal rate (MRR) and tool wear rate (TWR). The adequacy of the developed regression model has tested through analysis of variance test. The desirability-based multiobjective optimization is used to find the optimal process parameter which has given maximum MRR and minimum TWR. The optimum process parameters obtained were titanium diboride of 16%, pulse current of 6 A, flushing pressure of 1 Mpa, and pulse on time of 35?µs. The validity of the response surface model is further verified by conducting confirmation experiments.     

Hydriding characteristics of palladium and platinum alloyed FeTi

Effect of alloying on the hydriding characteristics of FeTi with noble metals such as platinum and palladium (5% by weight) has been investigated. It is observed that palladium has a favourable effect with respect to easy activation, decreased hysteresis and lower plateau pressures for hydrogen absorption and desorption process. For Pd/FeTi, a saturation composition of Pd/FeTiH_1.85 having the -phase, has been obtained. Unlike this, for Pt/FeTi, the total hydrogen absorption is decreased significantly and a saturation composition of Pt/FeTiH_1.5 having only ₂ phase, is observed.     

Magnetization study of Fe-doped ZnO co-doped with Cu: Synthesized by wet chemical method

Fe- and Cu-doped ZnO of nominal compositions Zn_0.95Fe_0.05O and Zn_0.94Fe_0.05Cu_0.01O were synthesized by a wet chemical route. X-ray diffraction analysis of the samples annealed at 575 K showed that they are single phase without any secondary phases. DC magnetization measurements of Cu co-doped samples (Zn_0.94Fe_0.05Cu_0.01O) as a function of field at room temperature showed ferromagnetic signature while the samples without Cu co-doping (Zn_0.95Fe_0.05O) are paramagnetic in nature. On increasing the temperature of annealing from 575 K to 1,075 K an impurity phase emerges in both the samples, which has been identified as a variant of ZnFe₂O₄. Both the samples heated at and above 1,075 K are found to be paramagnetic at room temperature. These observations, the absence of room temperature ferromagnetism in Zn_0.95Fe_0.05O and the disappearance of ferromagnetism in Zn_0.94Fe_0.05Cu_0.01O on raising the temperature of annealing clearly rules out the likelihood of room temperature ferromagnetism arising from the impurity phases like γ-Fe₂O₃ and/or ZnFe₂O₄ that might have been formed during the synthesis. Our results strongly suggest that room temperature ferromagnetism in Zn_0.94Fe_0.05Cu_0.01O can be attributed to the formation of a secondary phase of Cu-doped ZnFe₂O₄.     

Cryo-X-ray analysis-A novel tool to better understand the physicochemical reactions at the bioglass/biological fluid interface

The present study deals with the short-term physicochemical reactions at the interface between bioactive glass particles [55SiO(2)-20CaO-9P(2)O(5)-12Na(2)O-4MgO. mol%] and biological fluid (Dulbecco Modified Eagle's Medium (DMEM)). The physicochemical reactions within the interface are characterized by scanning transmission electron microscopy (TEM) (STEM) associated with Energy-dispersive X-ray spectroscopy (EDXS). Microanalysis of diffusible ions such as sodium, potassium, or oxygen requires a special care. In the present investigation the cryo-technique was adopted as a suitable tool for the specimen preparation and characterization. Cryosectioning is essential for preserving the native distribution of ions so that meaningful information about the local concentrations can be obtained by elemental microanalysis. The bioglass particles immersed in biological fluid for 24 h revealed five reaction stages: (i) dealkalization of the surface by cationic exchange (Na(+), Ca(2+) with H(+) or H(3)O(+)); (ii) loss of soluble silica in the form of Si(OH)(4) to the solution resulting from the breakdown of Si--O--Si bonds (iii); repolymerization of Si(OH)(4) leading to condensation of SiO(2)); (iv) migration of Ca(2+) and PO(4) (3-) to the surface through the SiO(2)-rich layer to form CaO-P(2)O(5) film; (v) crystallization of the amorphous CaO-P(2)O(5) by incorporating OH-- or CO(3) (2-) anions with the formation of three different surface layers on the bioactive glass periphery. The thickness of each layer is approximately 300 nm and from the inner part to the periphery they consist of Si--OH, which permits the diffusion of Ca(2+) and PO(4) (3-) ions and the formation of the middle Ca--P layer, and finally the outer layer composed of Na--O, which acts as an ion exchange layer between Na(+) ions and H(+) or H(3)O(+) from the solution.